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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Slabko V. V., Tsipotan A. S. , Aleksandrovsky A. S.
Заглавие : Self-organised aggregation of a pair of particles with different resonant frequencies and electric dipole moments of transitions, controlled by an external quasi-resonant field
Место публикации : Quantum Electron. . - 2013. - Vol. 43, no. 5. - P.458-462. - DOI 10.1070/QE2013v043n05ABEH015021
Аннотация: The influence of the oscillation phases of the dipole moments induced in metal nanoparticles and quantum dots by an external laser field on their interaction energy is considered. It is shown that a difference in resonant frequencies leads to the formation of additional minima and maxima, which are absent in the spectral dependence of the interaction energy of identical particles at similar orientations of the pair of particles with respect to the plane of polarisation of radiation. These features are due to the fact that the oscillation phase difference of the induced dipole moments of particles reaches values close to π.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Слабко, Виталий Васильевич, Ципотан, Алексей Сергеевич, Александровский, Александр Сергеевич
Заглавие : Управляемая внешним квазирезонансным полем самоорганизованная агрегация пары частиц с разными резонансными частотами и электродипольными моментами переходов
Место публикации : Квант. электроника. - 2013. - Т. 43, № 5. - С. 458-462
Ключевые слова (''Своб.индексиров.''): взаимодействие лазерного излучения с веществом--дипольное взаимодействие--наночастицы--наноструктуры
Аннотация: Рассмотрено влияние фаз колебаний наведенных внешним лазерным полем дипольных моментов наночастиц металла и квантовых точек на энергию их взаимодействия. Показано, что различие в резонансных частотах приводит к возникновению дополнительных минимумов и максимумов, отсутствующих в спектральной зависимости энергии взаимодействия идентичных частиц при аналогичных ориентациях пары частиц относительно плоскости поляризации излучения. Последнее связано с достижением разностью фаз колебаний наведенных дипольных моментов частиц величин, близких к π.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisova E. A., Chekanova L. A., Iskhakov R. S., Bondarenko G. N.
Заглавие : Microstructure and magnetic properties of C/Co-P and Al2O3/Co-P composite particles prepared by electroless plating
Место публикации : J. Appl. Phys. - 2013. - Vol. 113, Is. 17. - Ст.17A340. - P. - DOI 10.1063/1.4800037
Аннотация: The electroless plating is used to synthesize two types of composite powder, such as the activated carbon with pores filled by Co100-XPX particles and the Al2O3 microgranular coated by the shell which consists of Co100-XPX particles with 4 X 18. The magnetic and structural properties of the composite particles are characterized by scanning electron microscopy, X-ray diffraction, and vibrating sample magnetometer. It is found that the average Co(P) particle size in composite powders decreases from 300 nm to 120 nm with an increase in P- content from 4 to 18 at. %. It causes a reduction in coercivity from 300 to 80 Oe for Al2O3/Co(P) powders and from 680 to 150 Oe for C/Co(P) powders. The effects of two methods of immobilization of Co(P) particles on magnetic properties are studied.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Safronov A. P., Beketov I. V., Komogortsev S. V., Kurlyandskaya G. V., Medvedev A. I., Leiman D. V., Larranaga A., Bhagat S. M.
Заглавие : Spherical magnetic nanoparticles fabricated by laser target evaporation
Место публикации : AIP Adv.: American Institute of Physics, 2013. - Vol. 3, Is. 5. - Ст.052135. - P. - ISSN 2158-3226, DOI 10.1063/1.4808368
Примечания : Cited References: 47. - This work was supported by the RFBR 10-02-96015 and 12-02-31385 projects, UrFU 215, Spanish MEC MAT2011-27573-C04 grants, Universidad del Pais Vasco UPV/EHU under UFI11/53 action and Physics Department of the University of Maryland visiting grant. Selected measurements were performed at SGIker service of UPV-EHU. We thank O.M. Samatov, Dr. A.M. Murzakayev, Dr. I. Orue, and A.A. Svalova for special support.
Предметные рубрики: IRON-OXIDE NANOPOWDERS
CO2-LASER EVAPORATION
FE3O4 NANOPARTICLES
FINITE-SIZE
TEMPERATURE
FERROMAGNETS
FERROFLUIDS
DEPENDENCE
EXPLOSION
PARTICLES
Аннотация: Magnetic nanoparticles of iron oxide (MNPs) were prepared by the laser target evaporation technique (LTE). The main focus was on the fabrication of de-aggregated spherical maghemite MNPs with a narrow size distribution and enhanced effective magnetization. X-ray diffraction, transmission electron microscopy, magnetization and microwave absorption measurements were comparatively analyzed. The shape of the MNPs (mean diameter of 9 nm) was very close to being spherical. The lattice constant of the crystalline phase was substantially smaller than that of stoichiometric magnetite but larger than the lattice constant of maghemite. High value of M-s up to 300 K was established. The 300 K ferromagnetic resonance signal is a single line located at a field expected from spherical magnetic particles with negligible magnetic anisotropy. The maximum obtained concentration of water based ferrofluid was as high as 10g/l of magnetic material. In order to understand the temperature and field dependence of MNPs magnetization, we invoke the core-shell model. The nanoparticles is said to have a ferrimagnetic core (roughly 70 percent of the caliper size) while the shell consists of surface layers in which the spins are frozen having no long range magnetic order. The core-shell interactions were estimated in frame of random anisotropy model. The obtained assembly of de-aggregated nanoparticles is an example of magnetic nanofluid stable under ambient conditions even without an electrostatic stabilizer. (C) 2013 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution 3.0 Unported License.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Belousov O. V., Borisov R. V., Zharkov S. M., Parfenov V. A., Dorokhova L. I.
Заглавие : Redox potentials of gold-palladium powders in aqueous solutions of H2PdCl4
Место публикации : Russ. J. Phys. Chem. A: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 86, Is. 3. - P.484-488. - ISSN 0036-0244, DOI 10.1134/S0036024412020070
Примечания : Cited References: 26
Предметные рубрики: BIMETALLIC NANOPARTICLES
METALLIC PALLADIUM
COPPER
ELECTRODE
BLACK
Bimetallic particles
Bimetallic powders
Gold-palladium
Hydrochloric acid solution
Nernst equation
Redox potentials
Gold
Hydrochloric acid
Redox reactions
Secondary batteries
Transmission electron microscopy
X ray diffraction analysis
Ключевые слова (''Своб.индексиров.''): bimetallic powders--gold-palladium--redox potential
Аннотация: The redox potential of fine-dispersed and compact bimetallic powders of the palladium-gold system in hydrochloric acid solutions of H2PdCl4 at a temperature of 60A degrees C was studied. It was found that the redox potential increases with gold enrichment of the solid solution in accordance with the Nernst equation. The effect of gold-palladium particle size on this redox potential is shown. The morphology, sizes, and composition of bimetallic particles are determined via transmission electron microscopy and X-ray diffraction analysis.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Trofimova N. N., Veligzhanin A. A., Murzin V.Y, Chernyshov A. A., Khramov E. V., Zabluda V. N., Edel'man I. S., Slovokhotov Y. L., Zubavichus Y. V.
Заглавие : Structural diagnostics of functional nanomaterials with the use of X-ray synchrotron radiation
Место публикации : Nanotechnologies in Russia. - 2013. - Vol. 8, Is. 5-6. - P.396-401. - ISSN 1995-0780, DOI 10.1134/S1995078013030191
Ключевые слова (''Своб.индексиров.''): experimental facilities--functional nano materials--kurchatov synchrotron radiation--magnetic nano-particles--research capabilities--structural diagnostics--structural elements--x-ray synchrotron radiation--nanostructured materials--synchrotron radiation
Аннотация: An experimental facility for the complex X-ray diagnostics of functional nanomaterials (Structural Materials Science beamline) installed at the Kurchatov Synchrotron Radiation Center is presented. The key structural elements of the beamline are described. The research capabilities of the facility are demonstrated by the example of transparent magnets and glasses with magnetic nanoparticles, which are promising for the design of magneto-optical data storage and spintronics devices.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Komogortsev S. V., Iskhakov R. S., Zimin A. A., Korenev S. V., Filatov E. Yu., Shubin Yu. V., Chizhik N. A., Yurkin G.Yu., Eremin E. V.
Заглавие : Correlation of magnetic anisotropy energy and order parameter in nanostructured CoPt particles
Коллективы : Euro-Asian Symposium "Trends in MAGnetism": Nanomagnetism
Место публикации : V Euro-Asian simposium "Trend in MAGnetism": Nanomagnetism: abstracts. - Vladivostok: FEFU, 2013. - С. 70. - ISBN 978-5-7444-3124-2
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Denisova E. A., Komogortsev S. V., Li O. A., Chekanova L. A., Patrusheva T. N., Eremin E. V.
Заглавие : Magnetic particles in mesoporous silica MCM-41
Коллективы : Euro-Asian Symposium "Trends in MAGnetism": Nanomagnetism
Место публикации : V Euro-Asian simposium "Trend in MAGnetism": Nanomagnetism: abstracts. - Vladivostok: FEFU, 2013. - С. 176. - ISBN 978-5-7444-3124-2
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Komogortsev S. V., Iskhakov R. S., Zimin A. A., Filatov E. Yu. , Korenev S. V. , Shubin Yu. V. , Chizhik N. A. , Yurkin G.Yu., Eremin E. V.
Заглавие : Correlation of magnetic anisotropy energy and order parameter in nanostuctured CoPt particles
Коллективы : Euro-Asian Symposium "Trends in MAGnetism": Nanomagnetism
Место публикации : V Euro-Asian simposium "Trend in MAGnetism": Nanomagnetism: abstracts. - Vladivostok: FEFU, 2013. - С. 246. - ISBN 978-5-7444-3124-2
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Edelman I. S., Ivanova O. S., Ivantsov R. D., Velikanov D. A., Zabluda V. N., Zubavichus Y., Veligzhanin A. A., Zaikovskiy V. I., Stepanov S., Artemenko A., Curely J., Kliava J.
Заглавие : Magnetic nanoparticles formed in glasses co-doped with iron and larger radius elements
Место публикации : J. Appl. Phys.: American Institute of Physics, 2012. - Vol. 112, Is. 8. - Ст.84331. - P. - ISSN 0021-8979, DOI 10.1063/1.4759244
Примечания : Cited References: 65. - This work was partly supported by the Russian Foundation for Basic Research, Grant Nos. 07-02-92174 RFBR-CNRS and 11-02-00972, and President of Russia Federation Grant No NSh 1044.2012.2. A. Artemenko acknowledges financial support from the Marie Curie International Incoming Fellowship within the 7th European Community Framework Programme (EPREXINA, GA 255662). The synchrotron measurements were supported via the Russian federal Contract No. 16.552.11.7003. The authors thank K. P. Polyakova for the preparation of thin films.
Предметные рубрики: SUPERPARAMAGNETIC RESONANCE
FERROMAGNETIC-RESONANCE
TEMPERATURE-DEPENDENCE
FERRITE NANOPARTICLES
OXIDE NANOPARTICLES
FARADAY-ROTATION
CERAMICS
ANISOTROPY
PARTICLES
SPECTRA
Аннотация: A new type of nanoparticle-containing glasses based on borate glasses co-doped with low contents of iron and larger radius elements, Dy, Tb, Gd, Ho, Er, Y, and Bi, is studied. Heat treatment of these glasses results in formation of magnetic nanoparticles, radically changing their physical properties. Transmission electron microscopy and synchrotron radiation-based techniques: x-ray diffraction, extended x-ray absorption fine structure, x-ray absorption near-edge structure, and small-angle x-ray scattering, show a broad distribution of nanoparticle sizes with characteristics depending on the treatment regime; a crystalline structure of these nanoparticles is detected in heat treated samples. Magnetic circular dichroism (MCD) studies of samples subjected to heat treatment as well as of maghemite, magnetite, and iron garnet allow to unambiguously assign the nanoparticle structure to maghemite, independently of co-dopant nature and of heat treatment regime used. Different features observed in the MCD spectra are related to different electron transitions in Fe3+ ions gathered in the nanoparticles. The static magnetization in heat treated samples has non-linear dependence on the magnetizing field with hysteresis. Zero-field cooled magnetization curves show that at higher temperatures the nanoparticles occur in superparamagnetic state with blocking temperatures above 100 K. Below ca. 20 K, a considerable contribution to both zero field-cooled and field-cooled magnetizations occurs from diluted paramagnetic ions. Variable-temperature electron magnetic resonance (EMR) studies unambiguously show that in as-prepared glasses paramagnetic ions are in diluted state and confirm the formation of magnetic nanoparticles already at earlier stages of heat treatment. Computer simulations of the EMR spectra corroborate the broad distribution of nanoparticle sizes found by "direct" techniques as well as superparamagnetic nanoparticle behaviour demonstrated in the magnetization studies. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4759244]
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kagan M. Y., Efremov D. V., Mar'enko M. S., Val'kov V. V.
Заглавие : Superconductivity in repulsive fermi-systems at low density
Коллективы : RFBR [11-02-00741]
Место публикации : J. Supercond. Nov. Magn.: SPRINGER, 2013. - Vol. 26, Is. 9. - P.2809-2815. - ISSN 1557-1939, DOI 10.1007/s10948-013-2262-9
Примечания : Cited References: 57. - The authors acknowledge helpful discussions with A. V. Chubukov, A. S. Alexandrov, V. V. Kabanov, K. I. Kugel, Yu. V. Kopaev, N.M. Plakida, N.V. Prokof'ev, M. M. Korovushkin, M. A. Mitskan. M. Yu. K. work was supported by RFBR grant No. 11-02-00741.
Предметные рубрики: T-J MODEL
SUPERFLUID TRANSITION-TEMPERATURE
FRACTIONAL-STATISTICS
PHASE-SEPARATION
HUBBARD-MODEL
GAS
ENHANCEMENT
MECHANISM
EXCHANGE
PARTICLES
Ключевые слова (''Своб.индексиров.''): anomalous superconductivity--p-wave and d-wave pairings--kohn-luttinger mechanism--shubin-vonsovsky--hubbard and t-j models
Аннотация: In the large variety of models such as 3D and 2D Fermi-gas model with hard-core repulsion, 3D and 2D Hubbard model, and the Shubin-Vonsovsky model, we demonstrate the possibility of triplet p-wave pairing at low electron density. We show that the critical temperature of the p-wave pairing can be strongly increased in a spin-polarized case or in a two-band situation already at low density and reach experimentally feasible values of (1-5) K. We also discuss briefly d-wave pairing and high-T-C superconductivity with T-C similar to 100 K, which arises in the 2D t-J model in the range of parameters realistic for cuprates.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ershov A. E., Isaev I. L., Semina P. N., Markel V. A., Karpov S. V.
Заглавие : Effects of size polydispersity on the extinction spectra of colloidal nanoparticle aggregates
Место публикации : Phys. Rev. B: American Physical Society, 2012. - Vol. 85, Is. 4. - Ст.045421. - P. - ISSN 1098-0121, DOI 10.1103/PhysRevB.85.045421
Примечания : Cited References: 41. - This work was supported by grants from the following foundations of the Russian Federation: Presidium of RAS, OFN RAS, and SB RAS.
Предметные рубрики: METAL FRACTAL CLUSTERS
OPTICAL-PROPERTIES
ABSORPTION
NONLINEARITIES
COMPOSITES
SCATTERING
PARTICLES
SPHERES
GRAINS
Аннотация: We investigate the effect of particle polydispersity on the optical extinction spectra of colloidal aggregates of spherical metallic (silver) nanoparticles, taking into account the realistic interparticle gaps caused by layers of stabilizing polymer adsorbed on the metal surface (adlayers). The spectra of computer-generated aggregates are computed using two different methods. The coupled-multipole method is used in the quasistatic approximation and the coupled-dipole method beyond the quasistatics. The latter approach is applicable if the interparticle gaps are sufficiently wide relative to the particle radii. Simulations are performed for two different particle size distribution functions (bimodal and Gaussian), varying the number of particles per aggregate, and different distribution functions of the interparticle gap width. The strong influence of the latter factor on the spectra is demonstrated and investigated in detail.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Komogortsev S. V., Iskhakov R. S., Zimin A. A., Filatov E. Y., Korenev S. V., Shubin Y. V., Chizhik N. A., Yurkin G.Yu., Eremin E. V.
Заглавие : Magnetic anisotropy and order parameter in nanostructured CoPt particles
Коллективы : RFBR [11-03-00168-a, 12-02-00943-a]; Interdisciplinary integration of fundamental research of SB RAS [64]; Russian Federation [MK-1934.2013.3]
Место публикации : Appl. Phys. Lett.: American Institute of Physics, 2013. - Vol. 103, Is. 15. - Ст.152404. - P. - ISSN 0003-6951, DOI 10.1063/1.4824973
Примечания : Cited References: 36. - The authors are grateful to Dr. A. V. Zadesenets for synthesis of CoPt complex precursor and Dr. A. S. Bogomyakov for assistance in magnetic measurements. The work was supported by RFBR (Grant Nos. 11-03-00168-a and 12-02-00943-a), Interdisciplinary integration of fundamental research of SB RAS (2012-2014) project No. 64, and grant of the President of the Russian Federation (No. MK-1934.2013.3).
Предметные рубрики: FEPT THIN-FILMS
REMANENT MAGNETIZATION
UNIAXIAL ANISOTROPIES
FINE PARTICLES
NANOPARTICLES
FERROMAGNETS
PHASE
Аннотация: The correlation of magnetic anisotropy energy with order parameter in the crystallites of CoPt nanostructured particles prepared by thermal decomposition and further annealing has been studied by investigation of the approach magnetization to saturation curves and x-ray powder diffraction pattern profiles. It is shown that magnetic anisotropy energy value in partially ordered CoPt crystallite could be described as an intermediate case between two extremes, corresponding to either single or several c-domains of L1(0) phase in crystallite. (C) 2013 AIP Publishing LLC.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Dubrovskiy A. A., Shaykhutdinov K. A., Bayukov O. A., Yakushkin S. S., Bukhtiyarova G. A., Martyanov O. N.
Заглавие : Surface effects and magnetic ordering in few-nanometer-sized ε-Fe 2O3 particles
Место публикации : J. Appl. Phys. - 2013. - Vol. 114, Is. 16. - Ст.163911. - P. - ISSN 0021-8979, DOI 10.1063/1.4827839
Аннотация: The magnetic properties of ?-Fe2O3 nanoparticles with an average size of 3.4 nm in a silica gel matrix are investigated using Mossbauer technique, electron spin resonance, and magnetic measurements. Two magnetic subsystems reveal in magnetic measurements. Paramagnetic subsystem is formed by the Fe(III) ions in the smallest (<3.5 nm) particles' shell, while ferrimagnetic ordering in the "core" of the particles results in superparamagnetic behavior. The superparamagnetic behavior of the investigated samples is observed up to ?800 K. The magnetic moment of the particles is formed by both the ferrimagnetic ordering characteristic of ?-Fe 2O3 and the additional effect of uncompensated sublattices (planes). В© 2013 AIP Publishing LLC.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kolovsky A. R., Bulgakov E. N.
Заглавие : Wannier-Stark states and Bloch oscillations in the honeycomb lattice
Место публикации : Phys. Rev. B. - 2013. - Vol. 87, Is. 3. - Ст.033602. - P. - ISSN 1050-2947, DOI 10.1103/PhysRevA.87.033602
Ключевые слова (''Своб.индексиров.''): bloch oscillations--chaotic state--honeycomb lattices--localization length--localized state--quantum particles--static fields--tight-binding approximations--solid state physics--honeycomb structures
Аннотация: We study a quantum particle in a tilted honeycomb lattice in the tight-binding approximation. First we discuss the particle eigenstates, i.e., the stationary Wannier-Stark states. These states are proved to be extended states for the rational directions of the static field and localized states for the irrational directions. We find energy bands of the extended states and analyze the localized states. It is shown, in particular, that the localized honeycomb Wannier-Stark states are chaotic states with irregular dependence of the localization length on the static field magnitude. Second we discuss Bloch oscillations of the quantum particle. Irregular Bloch oscillations for irrational directions are observed. В© 2013 American Physical Society.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kolovsky A. R., Mantica G.
Заглавие : Cyclotron-Bloch dynamics of a quantum particle in a two-dimensional lattice
Место публикации : Physical Review E - Statistical, Nonlinear, and Soft Matter Physics. - 2011. - Vol. 83, Is. 4. - Ст.041123. - ISSN 1539-3755, DOI 10.1103/PhysRevE.83.041123
Ключевые слова (''Своб.индексиров.''): critical value--directed transport--drift velocities--electric and magnetic fields--electric field magnitude--electric field vectors--free space--initial conditions--lattice plane--quantum dynamics--quantum particles--quantum wave packets--two dimensional square lattice--two-dimensional lattices--electric fields--magnetic fields--quantum theory--vector spaces--two dimensional
Аннотация: This paper studies the quantum dynamics of a charged particle in a two-dimensional square lattice, under the influence of electric and magnetic fields, the former being aligned with one of the lattice axes and the latter perpendicular to the lattice plane. While in free space these dynamics consist of uniform motions in the direction orthogonal to the electric field vector, we find that, in a lattice, this directed drift takes place only for specific initial conditions and for electric field magnitudes smaller than a critical value. Otherwise, the quantum wave packet spreads ballistically in both directions orthogonal to the electric field. We quantify this ballistic spreading and identify the subspace of initial conditions ensuring directed transport with the drift velocity. We also describe the effect of disorder in the system. В© 2011 American Physical Society.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Korets A., Krylov A. S., Mironov E., Rabchevskii E.
Заглавие : Experimental study of the structure of milled diamond-containing particles obtained by the detonation method
Место публикации : EPJ Appl. Phys. - 2012. - Vol. 57, Is. 3. - Ст.30701. - ISSN 1286-0042, DOI 10.1051/epjap/2012110208
Примечания : Cited References: 15
Предметные рубрики: PURIFICATION
NANODIAMOND
Ключевые слова (''Своб.индексиров.''): chemical change--diamond grains--experimental spectra--experimental studies--ir spectrum--mechanical force--detonation--diamonds--x ray diffraction--agglomeration
Аннотация: A diamond-containing material (DCM) produced by detonation was mechanically milled using KM-1 and AGO-2S mills. Experimental spectra for infrared (IR) absorption, Raman scattering and X-ray diffraction patterns (XRD) were obtained for the treated DCM samples. We compared the Raman and IR spectra for the KM-1 milled samples and concluded that the surface of the DCM particles was not uniform. The mechanical force that resulted from milling with the AGO-2S destroyed the non-diamond part of the particles and initiated irreversible physical and chemical changes in them. The destruction of the diamond grains was the consequence of these irreversible changes. It follows from the experiments that the dipole momentum of the DCM particle was caused by the presence of polar fragments of molecules. The constant dipole momentum of the particles facilitated the aggregation. Based on this, we proposed a model of a structurally inhomogeneous DCM particle. В© 2012 EDP Sciences.
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18.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Kuzovnikova L. A., Денисова, Елена Александровна, Chekanova L. A.
Заглавие : Magnetic nanocomposite Al2O3/Co100-XPX particles: structure and magnetic properties
Коллективы : International Symposium on Metastable, Amorphous and Nanostructural Materials, Международный симпозиум по метастабильным, аморфным и наноструктурированным материалам , Национальный исследовательский технологический университет "МИСИС"
Место публикации : 19th International Symposium on Metastable, Amorphous and Nanostructural Materials (ISMANAM-2012): book of abstracts. - 2012. - P.149
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Karpov S. V., Semina P. N., Gavrilyuk A. P.
Заглавие : The role of the electron tunneling effect in the coagulation kinetics of polydisperse metal nanocolloids
Место публикации : Colloid J.: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 74, Is. 3. - P.305-312. - ISSN 1061-933X, DOI 10.1134/S1061933X12030052
Примечания : Cited References: 16. - Authors are thankful to G. A. Chiganova for discussions and helpful comments. Studies were carried out with the support of grants: the Presidium of RAS No 29 and No 31, OFN RAS III.9.5, IP SB RAS No 43, IP SB RAS (and SFU) No 101.
Предметные рубрики: PARTICLES
Аннотация: The energy of pair interactions between metal nanoparticles of different sizes is shown to be able to increase upon coagulation due to the additional electrostatic effect resulting from mutual heteropolar charging of the particles. The tunnel electron transfer occurring upon the collisions between particles of different sizes may be the reason for the charging. The transfer is caused by the dependence of the electron work function on the particle size. The electron transfer through the interparticle gap equalizes the Fermi levels in particles of different sizes and is associated with this dependence. Using the example of bimodal silver nanocolloids, it is shown that mutual heteropolar charging of particles with different sizes may accelerate the coagulation of polydisperse colloidal systems by an order of magnitude or more as compared with monodisperse systems, in which this effect is absent.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Atuchin V. V., Bekenev V. L., Chimitova O. D., Molokeev M. S., Bazarov B. G., Bazarova J. G., Khuzhum O. Y., Lim C. S.
Заглавие : Synthesis and electronic properties of β-RbNd(MoO4)2
Место публикации : Asian J. Chem. - 2014. - Vol. 26, No. 5. - P.1284-1286. - ISSN 0970-7077, DOI 10.14233/ajchem.2014.17209
Примечания : Cited References: 26. - This study is partly supported by by the Ministry of Education and Science of the Russian Federation.
Предметные рубрики: UP-CONVERSION PHOTOLUMINESCENCE
VIBRATIONAL PROPERTIES
CRYSTAL-STRUCTURE
PARTICLES
MOLYBDATE
SPECTROSCOPY
SYSTEM
ER3+
Ключевые слова (''Своб.индексиров.''): β-rbnd(moo4)2--electronic structure--ab initio calculations--x-ray photoelectron spectroscopy
Аннотация: The electronic structure of β-RbNd(MoO4)2 has been evaluated from experimental and theoretical points of view. For the molybdate, X-ray photoelectron valence-band spectra have been measured. The total and partial densities of states of the constituent atoms of β-RbNd(MoO4)2 have been calculated using the FP-LAPW method. The FP-LAPW data reveal that main contributors in the valence-band region of β-RbNd(MoO4)2 are the Rb 4p-, Nd 4f-, Mo 4d- and O 2p-like states.
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