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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kovaleva E. A., Kuzubov A. A., Avramov P. V., Kholtobina A. S., Kuklin A. V., Tomilin F. N., Sorokin P. B.
Заглавие : A key role of tensile strain and surface termination in formation and properties of La0.7Sr0.3MnO3 composites with carbon nanotubes
Место публикации : Comput. Mater. Sci.: Elsevier, 2017. - Vol. 139. - P.125-131. - ISSN 09270256 (ISSN), DOI 10.1016/j.commatsci.2017.07.021
Примечания : Cited References: 39. - This work was supported by National Research Foundation of Republic of Korea under Grant No. NRF-2017R1A2B4004440 and the government contract of the Ministry of Education and Science of the Russian Federation to Siberian Federal University (Grant No. 16.1455.2017/PCh). The authors would like to thank Joint Supercomputer Center of RAS, Moscow; Center of Equipment for Joint Use of Siberian Federal University, Krasnoyarsk; and Information Technology Centre, Novosibirsk State University for providing the access to their supercomputers. P.B.S gratefully acknowledges the financial supports of the Ministry of Education and Science of the Russian Federation in the framework of Increase Competitiveness Program of NUST «MISiS» (No. К2-2017-001) and RFBR, according to the research project No. 16-32-60138 mol_a_dk. E.A. Kovaleva would also like to acknowledge the program of the President of Russian Federation for Leading Scientific Schools Support (Grant No. 2016 NSh-7559.2016.2).
Ключевые слова (''Своб.индексиров.''): carbon nanotubes--lsmo--interface--spin polarization
Аннотация: Atomic and electronic structure of LSMO-based composites with carbon nanotubes were studied by means of density functional theory with respect to the termination of LSMO surface. The deformation of the tubes caused by the lattice mismatch with the substrate leads to a major change in their electronic structure. The surface terminated with Mn-O layer provides much stronger interaction with carbon nanotubes than Sr-O terminated one does. The interaction with transition metal atoms is essential for spin polarization of the nanotube while no spin injection was observed for Sr-O-supported tubes. © 2017 Elsevier B.V.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Berman G. P., Kolovsky A. R., Zaslavsky G. M.
Заглавие : A non-linear resonance in a system of surface-state electrons bound to the helium surface
Место публикации : Phys. Lett. A. - 1984. - Vol. 105, Is. 9. - P.483-486. - ISSN 0375-9601, DOI 10.1016/0375-9601(84)91042-9
Примечания : Cited References: 24
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Komarov S. A., Scherbinin V. V.
Заглавие : A Surface Wave Excitation by a Finite Phased Plane Waveguide Array with an Impedance Flange
Место публикации : 12th International Conference on Mathematical Methods in Electromagnetic Theory, 2008, Odesa, Ukraine, 2008. pp. 314-316
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mikhaleva N. S., Visotin M. A., Popov Z. I., Kuzubov A. A., Fedorov A. S.
Заглавие : Ab initio and empirical modeling of lithium atoms penetration into silicon
Место публикации : Comput. Mater. Sci.: Elsevier, 2015. - Vol. 109. - P.76-83. - ISSN 0927-0256, DOI 10.1016/j.commatsci.2015.06.024
Примечания : Cited References: 69. - The authors would like to thank the Institute of Computational Modeling SB RAS, Krasnoyarsk, Information Technology Centre Novosibirsk State University, for providing access to their computational resources. The reported study was supported by RFBR, research project No. 14-02-31071, 14-02-31309, 12-02-00640, by the Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools (project No. NSh-2886.2014.2), Increase Competitiveness Program of NUST "MISiS" (No. K2-2015-033). The authors also would like to thank Prof. Stephan Irle and L.R. Moskvina for fruitful discussions and helpful ideas.
Предметные рубрики: LONG CYCLE LIFE
CORE-LEVEL SPECTROSCOPY
CARBON-COATED SILICON
AUGMENTED-WAVE METHOD
ION BATTERIES
MOLECULAR-DYNAMICS
INTERATOMIC POTENTIALS
ELECTRONIC-STRUCTURE
CRYSTALLINE SILICON
SI(100)2X1 SURFACE
Ключевые слова (''Своб.индексиров.''): li-ion batteries--silicon--surface diffusion--li diffusion--density functional theory--molecular dynamics
Аннотация: A process of lithium atoms penetration into silicon (1 0 0) subsurface layers was investigated with the help of DFT method. It was shown that, while the concentration of lithium adatoms on reconstructed (1 0 0) silicon surface is low, the bonding energy of lithium atoms in the subsurface layers is smaller than the bonding energy on the surface, so lithium atoms are unlikely to migrate into the crystal. When the (1 0 0) silicon surface is covered by 2 layers of lithium, migration into the subsurface layer becomes favorable. In addition to this, the reconstruction of the surface changes to the form with symmetric dimers as the concentration increases. Thus, all possible lithium migration paths become energy-wise equal, so the rate of lithium atom transfer into silicon crystal rises. In addition to the ab initio calculations, an ad-hoc empirical interatomic potential was developed and the kinetics of lithium diffusion into silicon were studied. It was shown that lithium penetration proceeds in a layer-by-layer way with a sharp border between undoped and lithiated silicon. This is accounted for the fact that, once a tetrahedral interstice is occupied by a lithium atom, the migration barriers between the adjacent interstices become lower and the rate of diffusion increases. © 2015 Elsevier B.V. All rights reserved.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Fedorov A. S., Sorokin P. B., Kuzubov A. A.
Заглавие : Ab initio study of hydrogen chemical adsorption on platinum surface/carbon nanotube join system
Место публикации : Phys. Status Solidi B. - 2008. - Vol. 245, Is. 8. - P.1546-1551. - ISSN 0370-1972, DOI 10.1002/pssb.200844155
Примечания : Cited References: 31
Предметные рубрики: WALLED CARBON NANOTUBES
MOLECULAR-DYNAMICS
ROOM-TEMPERATURE
STORAGE
ENERGY
THERMODYNAMICS
GRAPHITE
DENSITY
POINTS
Аннотация: The process of hydrogen chemical adsorption on platinum cluster/single wall carbon nanotube (CNT) join surfaces is modelled at various temperatures and pressures. For that, the adsorption energy of hydrogen atoms on surfaces of both platinum (111) plate and CNT (5,5) or (8,8) types is calculated by density functional theory with the PBE approximation. At various temperatures the hydrogen atom hopping rate on both platinum and CNT surfaces is calculated by the transition state theory. Furthermore the hydrogen hopping rate from the platinum surface to the attached nanotube is obtained by calculation of the total energy profile. It is proved that hydrogen atoms can migrate easily at the platinum surface at all temperatures, but at the CNT surface they can migrate beginning at 400-500 K. By calculation of chemical potentials of hydrogen in gas or on CNT or platinum cluster surfaces the equilibrium density of adsorbed hydrogen was calculated at different temperatures and pressures. It is established that for all temperatures in the range 300-900 K and for all pressures less than 500 bar, the hydrogen is dissociated and chemically adsorbed on the platinum surface very effectively, but surface site occupation by hydrogen on attached CNT surface is rather small. But if CNT vacancies are present in the tube structure and the temperature is lower then 450 K, hydrogen atoms can be adsorbed effectively enough on these vacancies. (C) 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Fedorov A.S., Sorokin P.B., Kuzubov A. A.
Заглавие : Ab-initio study of hydrogen chemical adsorption on the platinum surface/carbon nanotube join system
Место публикации : Physica status solidi B - Basic Solid State Physics. - 2008. - Vol. 245, № 8. - С. 1546-1551
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanova O. S., Lin, Chun-Rong, Edelman I. S., Svetlitsky E. S., Sokolov A. Е., Zharkov S. M., Sukhachev A. L., Vorobyev S. A., Petrov D. A., Lin, En-Szu
Заглавие : Adsorption properties and catalytic activity of Fe3O4-Ag nanostructures
Колич.характеристики :12 с
Место публикации : Appl. Surf. Sci. - 2024. - Vol. 665. - Ст.160236. - ISSN 01694332 (ISSN), DOI 10.1016/j.apsusc.2024.160236. - ISSN 18735584 (eISSN)
Примечания : Cited References: 48. - The work is supported by the Russian Science Foundation (project no. 23-22-10025, https://rscf.ru/project/ 23-22-10025/) and by the Krasnoyarsk Regional Fund of Science and Technology Support. The electron microscopy and EDS investigations were conducted in the SFU Joint Scientific Center. Magnetic investigations were carried out in the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center "Krasnoyarsk Science Center SB RAS"
Аннотация: The morphology and magnetic properties as well as adsorption capacity and catalytic activity of Fe3O4-Ag nanoparticles synthesized by the solvothermal method were studied in dependence on the duration of the thermolysis process (3, 6, and 8 h). X-ray diffraction, transmission electron microscopy, and energy-dispersive spectroscopy measurements showed that the morphology of nanoparticles changed strongly as the duration of thermolysis increased. At 6 and 8 h duration, Fe3O4 nanocrystals grow and assemble into porous spherical globules with an Ag core (samples 2 and 3). These samples demonstrate high magnetization value and very low coercivity. The adsorption capacity of nanoparticles was studied with respect to two organic dyes: cationic methylene blue (MB) and anionic Congo red (CR). The particles showed preferential adsorption of the cationic dye. High catalytic activity towards four dyes: MB, methyl orange (MO), CR, and Rhodamine C (RhC) at the presence of NaBH4 is the remarkable property of these samples. The rate constant of the catalytic reaction was 1.4 min−1. Simultaneous exposure of CR and MO dyes to nanoparticles and NaBH4 caused their irreversible 100 % degradation while in the case of MB and RhC, a transition to their leuco form occurred.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gokhfeld D. M.
Заглавие : An extended critical state model: Asymmetric magnetization loops and field dependence of the critical current of superconductors
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2014. - Vol. 56, Is. 12. - P.2380-2386. - ISSN 1063-7834, DOI 10.1134/S1063783414120129. - ISSN 1090-6460
Примечания : Cited References: 37
Предметные рубрики: CRITICAL-CURRENT DENSITY
HIGH-TEMPERATURE SUPERCONDUCTORS
II SUPERCONDUCTORS
SURFACE-BARRIER
MGB2
TRANSPORT
MOTION
J(C)
PEAK
Аннотация: An extended critical state model has been developed. The model has considered the equilibrium magnetization of a surface layer and the magnetization of the central region of a superconducting sample. The magnetic flux distributions in the sample have been calculated. An analytical dependence of the critical current density on the magnetic field with different behaviors in strong and weak fields has been proposed. A relation of the asymmetry of the magnetization loops and the critical current density to the sample size has been established. The model is applicable to the parameterization of magnetization loops of single-crystal and polycrystalline superconductors.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Fedorov A. S., Serzhantova M. V., Kuzubov A. A.
Заглавие : Analysis of hydrogen adsorption in the bulk and on the surface of magnesium nanoparticles
Коллективы :
Место публикации : J. Exp. Theor. Phys.: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2008. - Vol. 107, Is. 1. - P126-132. - ISSN 1063-7761, DOI 10.1134/S1063776108070121
Примечания : Cited References: 15. - This study was supported financially by the Russian Foundation for Basic Research ( project no. 06-02-16132). The authors are also grateful to the Institute of Computer Modeling of the Siberian Branch of the Russian Academy of Science for providing a cluster computer on which all quantum-chemistry calculations were performed.
Предметные рубрики: MOLECULAR-DYNAMICS
TRANSITION
METALS
Ключевые слова (''Своб.индексиров.''): adsorption--gas adsorption--hydrogen--light metals--magnesium--nonmetals--hydrogen adsorption--magnesium hydrides--magnesium printing plates
Аннотация: The stability of magnesium hydride (MgH (x) ) nanoparticles (x = 0.5,...,2) is investigated using ab initio calculations. It is shown that for a nanoparticle diameter of D similar to 5 nm, the internal pressure becomes lower than 3 kbar; for this reason, the structure of hydride nanoparticles coincides with the structure of this hydride in crystalline form. It is found that the phase of partly saturated MgH (x) hydrides (x 2) must decompose into the phase of pure hcp magnesium and the alpha phase of MgH(2). The frequencies of jumps of hydrogen atoms within the hcp phase of magnesium and in the alpha phase of MgH(2) are calculated; it is shown that slow diffusion of hydrogen in magnesium is due to the large height of potential barriers for motion of hydrogen within MgH(2). To attain high diffusion rates, the structures of Mg(53)Sc and Mg(53)Ti crystals and their hydrides are calculated. It is found that the frequency of jumps of H atoms in Mg(53)ScH(108) near the Sc atoms does not noticeably change as compared to the frequency of jumps in the alpha phase of MgH(2), while the frequency of jumps in Mg(53)TiH(108) near Ti atoms is higher by approximately a factor of 2.5 x 10(6). This means that diffusion in manganese hydride with small admixtures of titanium atoms must be considerably eased. Chemical dissociation of hydrogen molecules on the (0001) surface of hcp magnesium, on the given surface with adjoined individual Ti atoms, and on the surface of a one-layer titanium cluster on the given surface of magnesium is investigated. It is found that dissociation of hydrogen at solitary titanium atoms, as well as on the surface of a Ti cluster, is facilitated to a considerable extent as compared to pure magnesium. This should also sharply increase the hydrogen adsorption rate in magnesium nanoparticles.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Platunov M. S., Varnakov S. N., Zharkov S. M., Bondarenko G. V., Weschke E., Schierle E., Ovchinnikov S. G.
Заглавие : Analysis of the structure and magnetic properties of an interface in multilayered (Fe/Si) N nanostructures with the surface-sensitive XMCD method
Коллективы : Russian Foundation for Basic Research [13-02-01265a, 14-02-31051mol-a]; Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools [NSh- 2886.2014.2]; Presidium of the Russian Academy of Sciences [24.34]; Ministry of Education and Science of the Russian Federation [02.G25.31.0043]
Место публикации : JETP Letters. - 2014. - Vol. 99, Is. 12. - P.706-711. - ISSN 0021-3640, DOI 10.1134/S002136401412011X. - ISSN 1090-6487
Примечания : Cited References: 26. - We are grateful to S.V. Komogortsev for stimulating discussions and to the management of BESSY II, Helmholtz-Zentrum Berlin, for the opportunity of performing experiments at the UE46-PGM1 beamline. This work was supported by the Russian Foundation for Basic Research (project nos. 13-02-01265a and 14-02-31051mol-a), by the Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools (project no. NSh- 2886.2014.2), by the Presidium of the Russian Academy of Sciences (program no. 24.34), and by the Ministry of Education and Science of the Russian Federation (state contract no. 02.G25.31.0043 and state task for research at Siberian Federal University in 2014).
Предметные рубрики: RAY CIRCULAR-DICHROISM
YIELD
SPECTRA
Fe
Аннотация: The structural and magnetic properties of (Fe/Si) N nanostructures obtained by successive deposition on the SiO2/Si(100) surface at a temperature of the substrate of 300 K have been studied. The thicknesses of all Fe and Si layers have been determined by transmission electron microscopy measurements. The magnetic properties have been studied by the X-ray magnetic circular dichroism (XMCD) method near the Fe L 3, 2 absorption edges. The orbital (m l ) and spin (m S ) contributions to the total magnetic moment of iron have been separated. The thicknesses of magnetic and nonmagnetic iron silicide on the Si/Fe and Fe/Si interfaces have been determined with the surface sensitivity of the XMCD method and the model of the interface between the nonmagnetic and weakened magnetic phases.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krakhalev M. N., Sutormin V. S., Prishchepa O. O., Kuz'menok N. M., Mikhalyonok S. G., Bezborodov V. S., Zyryanov V. Ya.
Заглавие : Anionic-cationic surfactant mixture providing the electrically controlled homeotropic surface anchoring of liquid crystals
Коллективы : International conference on Hole Burning, Single Molecule, and Related Spectroscopies: Science and Applications - 2018 , Belarusian Republican Foundation for Fundamental Research [X16P-110]; Russian Foundation for Basic Research (RFBR) [16-53-00073]; RFBR, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science [18-42-243006]
Место публикации : J. Mol. Liq. - 2019. - Vol. 282: Suzdal Conference (2018, Suzdal, RUSSIA). - P.57-62. - ISSN 0167-7322, DOI 10.1016/j.molliq.2019.02.132. - ISSN 1873-3166(eISSN)
Примечания : Cited References: 30. - The reported study was supported by the Belarusian Republican Foundation for Fundamental Research (project No X16P-110) and Russian Foundation for Basic Research (RFBR) (project No 16-53-00073). Mikhail N. Krakhalev and Vitaly S. Sutormin acknowledge financial support from RFBR, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science (project No 18-42-243006).
Предметные рубрики: IONIC MODIFICATION
TRANSITION
DROPLETS
CONFIGURATION
LAYER
Аннотация: In search of a substance able to function as an anionic surfactant applied for the electrically-induced anchoring transitions in liquid crystals, the compound 4-heptyloxybenzoate benzyl dodecyldimethylammonium (HOBBDDA) has been synthesized. Its orienting influence on nematic liquid crystal 4-pentyl-4'-cyanobiphenyl (5CB) has been tested. HOBBDDA dissolved up to 1.4%in 50 droplets dispersed in polymer film does not change the tangential surface anchoring inherent to polyvinyl alcohol matrix used. Homeotropic surface anchoring is realized if the HOBBDDA content exceeds 1.7%. The molecules of the surfactant in 5CB dissociate into anions and cations. The anions modify the surface anchoring under the action of DC electric field both in the normal and inverse mode. The mixture of HOBBDDA and cetyltrimethylammonium bromide can function as a binary ionic cationic surfactant which significantly expands the prospects for using the ionic-surfactant method to control liquid crystal materials. (C) 2019 Elsevier B.V. All rights reserved.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Turchin, Pavel P., Burkov, S. I., Turchin, Vladimir, I, Pletnev, Oleg N., Chulkova, Marina Yu, Nechepuryshina, Anastasia G.
Заглавие : Anisotropy of the electromechanical characteristics of SH-waves and Lamb waves in yttrium aluminum borate single crystals
Коллективы : Ministry of Science and Higher Education of the Russian Federation [FSRZ-2020-0011]
Место публикации : J. Sib. Fed. Univ. Math. Phys. - 2022. - Vol. 15, Is. 1. - P.80-87. - ISSN 1997-1397, DOI 10.17516/1997-1397-2022-15-1-80-87; Журн. СФУ. Матем. и физика. - ISSN 2313-6022(eISSN)
Примечания : Cited References: 24. - The study was carried out within the framework of the state assignment of the Ministry of Science and Higher Education of the Russian Federation (research project code FSRZ-2020-0011)
Аннотация: The anisotropy of the electromechanical properties of SH-waves and Lamb waves in yttrium aluminum borates, which are nonmagnetic representatives of the RMe3(BO3)4 single crystals family (where R=Y, La-Lu; M=Fe, Al, Cr, Ga, Sc) with unique properties of magnetoelectrics and multiferroics, has been studied. In the process of the numerical simulation of the acoustic waves characteristics, the values of linear electromechanical constants of YAl3(BO3)4 single crystals, previously measured by ultrasonic pulse echo and quasi-static methods, have been used.Исследована анизотропия электромеханичеких характеристик SH-волн и волн Лэмба в иттриевых алюмоборатах, которые являются немагнитным представителем семейства монокри- сталлов RMe3(BO3)4 (где R=Y, La-Lu; M=Fe, Al, Cr, Ga, Sc) с уникальными свойствами магнитоэлектриков и мультиферроиков. При численном моделировании характеристик акустических волн использованы значения линейных электромеханических постоянных монокристаллов YAl3(BO3)4, измеренных ранее ультразвуковым эхо-импульсным и квазистатическим методами.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Muzalevskiy K. V., Zeyliger, Anatoly
Заглавие : Application of Sentinel-1B polarimetric observations to soil moisture retrieval using neural networks: Case study for bare Siberian chernozem soil
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [19-29-05261 mk]; Ministry of Science and Higher Education of the Russian Federation [0287-2021-0034]
Место публикации : Remote Sens. - 2021. - Vol. 13, Is. 17. - Ст.3480. - ISSN 2072-4292(eISSN), DOI 10.3390/rs13173480
Примечания : Cited References: 21. - This work was supported by the Russian Foundation for Basic Research (grant No. 19-29-05261 mk). The field experiment and EC-5 Decagon sensor calibration in laboratory conditions were carried out with the support of Ministry of Science and Higher Education of the Russian Federation, project No. 0287-2021-0034 (basic state assignment)
Предметные рубрики: SURFACE
MODEL
PARAMETERS
ROUGHNESS
INVERSION
DUBOIS
IEM
OH
Аннотация: Sentinel-1 is currently the only synthetic-aperture radar, which radar measurements of the earth’s surface to be carried out, regardless of weather conditions, with high resolution up to 5–40 m and high periodicity from several to 12 days. Sentinel-1 creates a technological platform for the development of new globally remote sensing algorithms of soil moisture, not only for hydrological and climatic model applications, but also on a single field scale for individual farms in precision farming systems used. In this paper, the potential of soil moisture remote sensing using polarimetric Sentinel-1B backscattering observations was studied. As a test site, the fallow agricultural field with bare soil near the Minino village (56.0865°N, 92.6772°E), Krasnoyarsk region, the Russian Federation, was chosen. The relationship between the cross-polarized ratio, reflectivity, and the soil surface roughness established Oh used as a basis for developing the algorithm of soil moisture retrieval with neural networks (NNs) computational model. Two NNs is used as a universal regression technique to establish the relationship between scattering anisotropy, entropy and backscattering coefficients measured by the Sentinel-1B on the one hand and reflectivity on the other. Finally, the soil moisture was found from the soil reflectivity in solving the inverse problem using the Mironov dielectric model. During the field campaign from 21 May to 25 August 2020, it was shown that the proposed approach allows us to predict soil moisture values in the layer thickness of 0.00–0.05 m with the root-mean-square error and determination coefficient not worse than 3% and 0.726, respectively. The validity of the proposed approach needs additional verification on a wider dataset using soils of different textures, a wide range of variations in soil surface roughness, and moisture.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Tarasov A. S., Tarasov I. A., Yakovlev I. A., Rautskii M. V., Bondarev I. A., Lukyanenko A. V., Platunov M. S., Volochaev M. N., Efimov, Dmitriy D., Goikhman, Aleksandr Yu., Belyaev B. A., Baron F. A., Shanidze, Lev V., Farle M., Varnakov S. N., Ovchinnikov S. G., Volkov N. V.
Заглавие : Asymmetric interfaces in epitaxial off-stoichiometric Fe3+xSi1-x/Ge/Fe3+xSi1-x hybrid structures: Effect on magnetic and electric transport properties
Коллективы : RFBRRussian Foundation for Basic Research (RFBR); Krasnoyarsk Regional Fund of Science [20-42-243007, 20-42-240012]; Government of the Russian Federation [075-15-2019-1886]; Ministry of Science and Higher Education of the Russian Federation [FZWN-2020-0008]
Место публикации : Nanomaterials. - 2022. - Vol. 12, Is. 1. - Ст.131. - ISSN 2079-4991(eISSN), DOI 10.3390/nano12010131
Примечания : Cited References: 61. - The research was funded by RFBR, Krasnoyarsk Territory, and Krasnoyarsk Regional Fund of Science, project number 20-42-243007, and by the Government of the Russian Federation, Mega Grant for the Creation of Competitive World-Class Laboratories (Agreement no. 075-15-2019-1886). I.A.T. and S.N.V. thank RFBR, Krasnoyarsk Territory, and Krasnoyarsk Regional Fund of Science, project number 20-42-240012, for partial work related to the development of the simulation model of the pore autocorrelated radial distribution function coupled with the near coincidence site model, the Fe3+xSi1-x lattice distortion analysis, and processing Rutherford backscattering spectroscopy data. The Rutherford backscattering spectroscopy measurements were supported by the Ministry of Science and Higher Education of the Russian Federation (project FZWN-2020-0008)
Предметные рубрики: FILMS
ANISOTROPY
SI(001)
DEVICES
SURFACE
GROWTH
Аннотация: Three-layer iron-rich Fe3+xSi1-x/Ge/Fe3+xSi1-x (0.2 x 0.64) heterostructures on a Si(111) surface with Ge thicknesses of 4 nm and 7 nm were grown by molecular beam epitaxy. Systematic studies of the structural and morphological properties of the synthesized samples have shown that an increase in the Ge thickness causes a prolonged atomic diffusion through the interfaces, which significantly increases the lattice misfits in the Ge/Fe3+xSi1-x heterosystem due to the incorporation of Ge atoms into the Fe3+xSi1-x bottom layer. The resultant lowering of the total free energy caused by the development of the surface roughness results in a transition from an epitaxial to a polycrystalline growth of the upper Fe3+xSi1-x. The average lattice distortion and residual stress of the upper Fe3+xSi1-x were determined by electron diffraction and theoretical calculations to be equivalent to 0.2 GPa for the upper epitaxial layer with a volume misfit of -0.63% compared with a undistorted counterpart. The volume misfit follows the resultant interatomic misfit of |0.42|% with the bottom Ge layer, independently determined by atomic force microscopy. The variation in structural order and morphology significantly changes the magnetic properties of the upper Fe3+xSi1-x layer and leads to a subtle effect on the transport properties of the Ge layer. Both hysteresis loops and FMR spectra differ for the structures with 4 nm and 7 nm Ge layers. The FMR spectra exhibit two distinct absorption lines corresponding to two layers of ferromagnetic Fe3+xSi1-x films. At the same time, a third FMR line appears in the sample with the thicker Ge. The angular dependences of the resonance field of the FMR spectra measured in the plane of the film have a pronounced easy-axis type anisotropy, as well as an anisotropy corresponding to the cubic crystal symmetry of Fe3+xSi1-x, which implies the epitaxial orientation relationship of Fe3+xSi1-x (111)[0-11] || Ge(111)[1-10] || Fe3+xSi1-x (111)[0-11] || Si(111)[1-10]. Calculated from ferromagnetic resonance (FMR) data saturation magnetization exceeds 1000 kA/m. The temperature dependence of the electrical resistivity of a Ge layer with thicknesses of 4 nm and 7 nm is of semiconducting type, which is, however, determined by different transport mechanisms.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Andryushchenko T. A., Lyashchenko S. A., Lukyanenko A. V., Varnakov S. N., Ovchinnikov S. G.
Заглавие : Auger electron spectroscopy of the air-exposed (Cr0.5Mn0.5)2GaC MAX film surface
Колич.характеристики :6 с
Место публикации : Tech. Phys. Lett. - 2023. - Vol. 49, Is. 7. - P.59-64. - ISSN 10637850 (ISSN), DOI 10.61011/TPL.2023.07.56448.19430. - ISSN 10906533 (eISSN)
Примечания : Cited References: 16. - This study was supported by a grant from the Russian Science Foundation, project № 21-12-00226 (http://rscf.ru/project/21-12-00226/)
Аннотация: We have analyzed chemical bonding of atmospheric oxygen with chromium and manganese on the epitaxial MAX-phase (Cr0.5Mn0.5)2GaC surface using Auger electron spectroscopy combined with ion etching. It was found that the system has a specific anisotropic oxidation where oxygen atoms bind to chromium and manganese ones more actively at the faces of layered MAX phase crystallites in contrast to the (0001) basal plane. At the same time, the dominance of the Mn–O chemical bonding over Cr–O is observed on the latter.
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16.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Andryushchenko T. A., Lyashchenko S. A., Varnakov S. N., Wiedwald U., Farle M.
Заглавие : Auger electron spectroscopy of the Cr-Mn base max-phase surface
Коллективы : Российская академия наук, Физико-технический институт им. Е.К. Завойского ФИЦ Казанского научного центра РАН, Казанский (Приволжский) федеральный университет, Euro-Asian Symposium "Trends in MAGnetism", "Trends in MAGnetism", Euro-Asian Symposium
Место публикации : VIII Euro-Asian symposium "Trends in magnetism" (EASTMAG-2022): Book of abstracts/ program com. S. G. Ovchinnikov [et al.]. - 2022. - Vol. 2, Sect. O: MAX materials. - Ст.O.P1. - P.482-483. - ISBN 978-5-94469-051-7
Примечания : Cited References: 4. - Sample synthesis was supported by the government of the Russian Federation (agreement No.075-15-2019-1886). Measurements and analysis of samples were supported by the Russian ScienceFoundation (grant #21-12-00226, http://rscf.ru/project/21-12-00226/)
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Korshunov M. M., Togushova Yu.N.
Заглавие : Band structure modification due to the spin-orbit coupling in the three-orbital model for iron pnictides
Коллективы : Russian Foundation for Basic Research [16-02-00098]; BASIS Foundation for Development of Theoretical Physics and Mathematics
Место публикации : J. Sib. Fed. Univ. Math. Phys. - 2018. - Vol. 11, Is. 4. - P.430-437. - ISSN 1997-1397, DOI 10.17516/1997-1397-2018-11-4-430-437; Журн. СФУ. Сер. "Математика и физика". - ISSN 2313-6022(eISSN)
Примечания : Cited References: 14. - This work was supported in part by the Russian Foundation for Basic Research (grant 16-02-00098) and BASIS Foundation for Development of Theoretical Physics and Mathematics.
Предметные рубрики: SUPERCONDUCTING STATE
Ключевые слова (''Своб.индексиров.''): fe-based superconductors--spin-orbit coupling--band structure--fermi surface--сверхпроводники на основе железа--спин-орбитальное взаимодействие--зонная структура--поверхность ферми
Аннотация: We study the effect of the spin-orbit coupling on the band structure and the Fermi surface of the three-orbital model within the two-iron Brillouin zone. Due to the presence of two irons in the crystallographically correct unit cell, the spin-orbit coupling can be divided into the intra- and intercell parts with respect to the one-iron unit cell. We show that the intercell part produces the reconstruction of the Fermi surface in the form of the pronounced splitting between the previously degenerate electron (π, π)-pockets along the (0, π) - (π, π) direction. Intracell part shifts the bands around (0, 0) point and removes degeneracy there. There are also some other band shifts but they should not affect the low-energy physics because they occur at energy scales of about 1 eV below the Fermi level.Исследовано влияние спин-орбитального взаимодействия на зонную сруктуру и поверхность Ферми трехорбитальной модели в зоне Бриллюэна двух атомов железа на ячейку. Из-за присутствия двух атомов железа в кристаллографической элементарной ячейке спин-орбитальное взаимодействие можно разделить на внутри- и межъячеечную части по отношению к элементарной ячейке решетки железа. Показано, что межъячеечная часть приводит к реконструкции поверхности Ферми в виде выраженного расщепления между ранее вырожденными электронными карманами в точке (π ;π ) вдоль направления (0; π) − (π; π). Внутриячеечная часть приводит к сдвигу зон вблизи точки (0; 0) и снимает там вырождение. Также имеют место другие сдвиги зон, но они не должны влиять на низкоэнергетическую физику, поскольку возникают на энергиях порядка 1 eV ниже уровня Ферми.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gitelzon I. I., Filimonov V. S., Musonov V. M.
Заглавие : Bioluminescent glow of surface-water layer of the Central Arctic in spring
Место публикации : Doklady Akademii Nauk. - 1981. - Vol. 256, Is. 3. - P.723-726. - ISSN 0002-3264
Примечания : Cited References: 7
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zhila N. O., Sapozhnikova K. Y., Kiselev E. G., Nemtsev I. V., Lukyanenko A. V., Shishatskaya E. I., Volova T. G.
Заглавие : Biosynthesis and properties of a P(3HB-co-3HV-co-4HV) produced by Cupriavidus necator B-10646
Место публикации : Polymers. - 2022. - Vol. 14, Is. 19. - Ст.4226. - ISSN 20734360 (ISSN), DOI 10.3390/polym14194226
Примечания : Cited References: 77. - The study was funded by State Assignment of the Ministry of Science and Higher Education of the Russian Federation (project No. 0287-2021-0025)
Аннотация: Synthesis of P(3HB-co-3HV-co-4HV) copolymers by the wild-type strain Cupriavidus necator B-10646 on fructose or sodium butyrate as the main C-substrate with the addition of γ-valerolactone as a precursor of 3HV and 4HV monomers was studied. Bacterial cells were cultivated in the modes that enabled production of a series of copolymers with molar fractions of 3HV (from 7.3 to 23.4 mol.%) and 4HV (from 1.9 to 4.7 mol.%) with bacterial biomass concentration (8.2 ± 0.2 g/L) and PHA content (80 ± 2%). Using HPLC, DTA, DSC, X-Ray, SEM, and AFM, the physicochemical properties of copolymers and films prepared from them have been investigated as dependent on proportions of monomers. Copolymers are characterized by a reduced degree of crystallinity (Cx 38–49%) molecular weight characteristics Mn (45–87 kDa), and Mw (201–248 kDa) compared with P(3HB). The properties of the films surface of various composition including the porosity and surface roughness were studied. Most of the samples showed a decrease in the average pore area and an increase in their number with a total increase in 3HV and 4HV monomers. The results allow scaling up the productive synthesis of P(3HB-co-3HV-co-4HV) copolymers using Cupriavidus necator B-10646.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krakhalev M. N., Gardymova A. P., Prishchepa O. O., Rudyak V. Yu., Emelyanenko A. V., Liu J. -H., Zyryanov V. Ya.
Заглавие : Bipolar configuration with twisted loop defect in chiral nematic droplets under homeotropic surface anchoring
Место публикации : Sci. Rep. - 2017. - Vol. 7, Is. 1. - Ст.14582. - ISSN 20452322 (ISSN), DOI 10.1038/s41598-017-15049-6
Примечания : Cited References: 45. - We are grateful to Dr. Timofeev Ivan Vladimirovich for valuable comments and discussions. This work was supported by the Russian Foundation for Basic Research (RFBR) under Grants Nos 15-02-06924, 16-53-00073, and Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research project No. 16-42-240704, and by the Siberian Branch of the Russian Academy of Sciences under Complex Program II.2P 0358-2015-0010. The work of V.Y.R. and À.V.Å. on the simulation of droplet structure and texture was supported by the Russian Science Foundation (project No. 16-43-03010). The work of J.H.L. was supported by the Ministry of Science and Technology of Taiwan (contract No. MOST105-2923-E-006-007).
Аннотация: Optical textures and appropriate orientational structures have been studied within droplets of chiral nematic dispersed in polymer assigning the homeotropic anchoring. The helix axis of the chiral structure inside droplets forms the bipolar configuration. The optical droplet textures were analysed in the unpolarised light, analyser switching-off scheme and in crossed polarisers. The twisted loop defect reveals itself convincingly in all schemes. Its appearance at the optical patterns of the chiral nematic droplets has been examined depending on their size and the aspect direction. The existence of the defect has been verified by the structural and optical calculations. The effect of an electric field on both the defect line shape and the orientational structure of chiral nematic has been studied.
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