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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Boldyrev K. N., Pisarev R. V., Bezmaternykh L. N., Popova M. N.
Заглавие : Antiferromagnetic dichroism in a complex multisublattice magnetoelectric CuB2O4
Коллективы : Russian Academy of Sciences under the Programs for Basic Research; Russian Federation [MK-3521.2015.2], Russian Foundation for Basic Research [15-32-20613, 15-02-04222], Ministry of Education and Science of the Russian Federation [14.B25.0031.25]
Место публикации : Phys. Rev. Lett.: American Physical Society, 2015. - Vol. 114, Is. 24. - Ст.247210. - ISSN 0031, DOI 10.1103/PhysRevLett.114.247210. - ISSN 10797114(eISSN)
Примечания : Cited References:40. - This study was supported by the Russian Academy of Sciences under the Programs for Basic Research, by the President of the Russian Federation (Grant No. MK-3521.2015.2, K. N. B.), by the Russian Foundation for Basic Research (Grants No. 15-32-20613, K. N. B., and No. 15-02-04222, R. V. P.), and by the Ministry of Education and Science of the Russian Federation (Grant No. 14.B25.0031.25, R. V. P.).
Предметные рубрики: MAGNETIC SOLITON LATTICE
COPPER METABORATE
GYROTROPIC BIREFRINGENCE
SPECTROSCOPY
EXCITATIONS
TRANSITIONS
CRYSTALS
Cr2O3
FIELD
Аннотация: Magnetic control of the crystal chirality was announced by Saito et al. [Phys. Rev. Lett. 101, (2008)] on the ground of experiments in CuB2O4. This claim has raised a sharp dispute in the literature because it seemed to contradict the fundamental symmetry principles. We settle this dispute on the basis of a high-resolution optical spectroscopy study of excitonic transitions in CuB2O4. We find that a large sublattice-sensitive antiferromagnetic linear dichroism (LD) emerges at the Néel temperature TN=21 K and show how it could simulate a “magnetic-field control of the crystal chirality.” We prove that the discovered LD is related microscopically to the magnetic Davydov splitting. This LD is highly sensitive to subtle changes in the spin subsystems, which allowed us to observe a splitting of the phase transition into an incommensurate magnetic phase into two transitions (T∗1=8.5 and T∗2=7.9 K) and to suggest elliptical spiral structures below T∗1, instead of a simple circular helix proposed earlier.О магнитном контроле кристаллической хиральности сообщил Сайто и др. [Phys. Rev. Lett. 101, 117402 (2008)] на основании экспериментов в CuB2O4. Это требование вызвало резкий спор в литературе, потому что это казалось, противоречат основным принципам симметрии. Мы урегулировать этот спор на основе исследования с помощью оптической спектроскопии высокого разрешения экситонных переходов в CuB2O4. Мы считаем, что большой подрешетко-чувствительный антиферромагнитный линейный дихроизм (LD) возникает при температуре Нееля TN= 21 Kи показываем, как это может имитировать "контроль магнитным полем кристаллической хиральности." Мы докажем, что обнаруженный LD связанс микроскопическим магнитным Давыдовским расщеплением. Этот Л.Д. весьма чувствителен к тонким изменениям в спиновых подсистем, которые позволили нам наблюдать расщепление фазового перехода в несоизмеримы магнитная фаза в двух переходов (T*1= 8,5 и Т*2 = 7,9 К) и предположить эллиптическую спиральную структуру ниже T*1, вместо простой круговой спирали предложенный ранее.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Fokina V. D., Bogdanov E. V., Pogorel'tsev E. I., Bondarev V. S., Flerov I. N., Laptash N. M.
Заглавие : Calorimetric and dielectric studies of the (NH4)(2)MoO2F4 oxyfluoride
Коллективы :
Разночтения заглавия :авие SCOPUS: Calorimetric and dielectric studies of the (NH4)2MoO2F4 oxyfluoride
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2010. - Vol. 52, Is. 1. - P158-166. - ISSN 1063-7834, DOI 10.1134/S1063783410010282
Примечания : Cited References: 22. - This study was supported by the Russian Foundation for Basic Research ( project no. 09-02-00062).
Предметные рубрики: PHASE-TRANSITIONS
(NH4)(2)WO2F4
DIFFRACTION
MECHANISM
CRYSTALS
Аннотация: The temperature dependences of the heat capacity, dielectric properties, and response to an external pressure and an electric field for the (NH4)(2)MoO2F4 oxyfluoride (space group Cmcm, Z = 4) have been studied. A comparative analysis of the data on the entropy of phase transitions, p-T phase diagrams, permittivity, and anomalous heat capacity in combination with the results of previous studies of the related compounds (NH4)(2)WO2F4 and (ND4)(2)WO2F4 has made it possible to establish that both [MO2F4](2-) anions and ammonium groups play a substantial role in the mechanism and nature of the structural transformations.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Flerov I. N., Gorev M. V., Ushakova T. V.
Заглавие : Calorimetric investigations of phase transitions in the cryolites (NH4)(3)Ga1-xScxF6 (x = 1.0, 0.1, 0)
Место публикации : Phys. Solid State: AMER INST PHYSICS, 1999. - Vol. 41, Is. 3. - P468-473. - ISSN 1063-7834, DOI 10.1134/1.1130805
Примечания : Cited References: 19
Предметные рубрики: FERROELASTICS
ELPASOLITES
CRYSTALS
PRESSURE
Аннотация: The specific heat of the cryolites (NH4)(3)Ga1-xScxF6 with x=1.0, 0.1, and 0 was measured. The thermodynamic parameters of the phase transitions were determined. A previously unknown phase transition was found in the scandium compound at T=243 K. (C) 1999 American Institute of Physics. [S1063-7834(99)03003-8].
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Levitin R. Z., Popova E. A., Chtsherbov R. M., Vasiliev A. N., Popova M. N., Chukalina E. P., Klimin S. A., van Loosdrecht PHM, Fausti D., Bezmaternykh L. N.
Заглавие : Cascade of phase transitions in GdFe3(BO3)(4)
Место публикации : JETP Letters. - 2004. - Vol. 79, Is. 9. - P.423-426. - ISSN 0021-3640, DOI 10.1134/1.1776236
Примечания : Cited References: 8
Предметные рубрики: CRYSTALS
ND
Аннотация: Cascade of phase transitions in GdFe3(BO3)(4) at 156, 37, and 9 K has been detected by specific heat measurements and further studied by Raman scattering and Nd3+ spectroscopic probe method. A weakly first-order structural phase transition at 156 K is followed by a second-order antiferromagnetic ordering phase transition at 37 K and a first-order spin-reorientational phase transition at 9 K. (C) 2004 MAIK "Nauka / Interperiodica".
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : ALEKSEEV K. N., ALEKSEEVA N. V.
Заглавие : CHAOTIC DYNAMICS IN LIGHT IMPURITY CENTER INTERACTION
Разночтения заглавия :us: Chaotic dynamics in light-impurity center interaction
Место публикации : Phys. Lett. A: ELSEVIER SCIENCE BV, 1992. - Vol. 162, Is. 1. - P82-85. - ISSN 0375-9601, DOI 10.1016/0375-9601(92)90965-O
Примечания : Cited References: 26
Предметные рубрики: QUANTUM OPTICS
CRYSTALS
Аннотация: Interaction of an impurity center in crystal with light and crystal lattice vibrations is considered. Conditions of the transition to Hamiltonian chaos have been obtained for the case of strong and resonant electron-phonon coupling.
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ignatchenko V. A., Polukhin D. S.
Заглавие : Crossing resonance of stochastically interacting wave fields
Место публикации : J. Exp. Theor. Phys.: MAIK Nauka-Interperiodica / Springer, 2013. - Vol. 116, Is. 2. - P.206-222. - ISSN 1063-7761, DOI 10.1134/S1063776113020118
Примечания : Cited References: 42. - We are grateful to V. V. Val'kov and A. F. Sadreev for useful discussions. This work was supported by the Presidium of the Russian Academy of Sciences (Program no. 24.29), the Dynasty Foundation (Program for Support of Young Scientists), the Federal Target Program (state contract no. 14.B37.21.0730), and the Special Program for Siberian Federal University of the Ministry of Education and Science of the Russian Federation.
Предметные рубрики: CRYSTALS
SYSTEMS
ALLOYS
MEDIA
Аннотация: The dynamic susceptibilities (Green's functions) of the system of two interacting wave fields of different physical natures with a stochastically inhomogeneous coupling parameter between them with zero mean value have been examined. The well-known self-consistent approximation taking into account all diagrams with noncrossing correlation/interaction lines has been generalized to the case of stochastically interacting wave fields. The analysis has been performed for spin and elastic waves. The results obtained taking into account the processes of multiple scattering of waves from inhomogeneities are significantly different from those obtained for this situation earlier in the Bourret approximation [R.C. Bourret, Nuovo Cimento 26, 1 (1962)]. Instead of frequencies degeneracy removal in the wave spectrum and the splitting of resonance peaks of dynamic susceptibilities, a wide single-mode resonance peak should be observed at the crossing point of the unperturbed dispersion curves. The fine structure appears at vertices of these wide peaks in the form of a narrow resonance on the Green's-function curve of one field and a narrow antiresonance on the vertex of the Green's-function curve of the other field.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bogdanov E. V., Vasil'ev A. D., Flerov I. N., Laptash N. M.
Заглавие : Effect of cation substitution in fluorine-oxygen molybdates (NH4)(2-x) A (x) MoO2F4
Разночтения заглавия :авие SCOPUS: Effect of cation substitution in fluorine-oxygen molybdates (NH4)2 - xAxMoO2F4
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2011. - Vol. 53, Is. 2. - P303-308. - ISSN 1063-7834, DOI 10.1134/S1063783411020065
Примечания : Cited References: 11. - This study was supported by the Russian Foundation for Basic Research (project no. 09-02-00062) and the Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools of the Russian Federation (project no. NSh-1011.2008.2).
Предметные рубрики: PHASE-TRANSITIONS
CRYSTALS
(NH4)(2)WO2F4
DIFFRACTION
OXYFLUORIDE
MECHANISM
DISORDER
Аннотация: Thermophysical and structural studies of (NH4)(2 - x) A (x) MoO2F4 (A = Cs, Rb, K) solid solutions of oxyfluorides have been performed. The character of the influence of cation substitutions on the stability of the initial phase (space group Cmcm) and on the mechanism of phase transitions has been elucidated.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ignatchenko V. A., Felk V. A.
Заглавие : Effects of long-wave inhomogeneities of the exchange and elastic force constants in the framework of the coherent potential approximation
Место публикации : Phys. Rev. B: AMERICAN PHYSICAL SOC, 2006. - Vol. 74, Is. 17. - Ст.174415. - ISSN 1098-0121, DOI 10.1103/PhysRevB.74.174415
Примечания : Cited References: 14
Предметные рубрики: CRYSTALS
MODEL
Аннотация: The formalism of averaged Green's functions in the continuum is developed for spin waves in ferromagnets with inhomogeneities of the exchange constant and elastic waves in media with inhomogeneities of the force constant. The integral self-consisted equation in the coherent potential approximation is developed for taking into account effects of inhomogeneities of these nonlocal characteristics of the material on the wave spectrum in it. The obtained general results are applied to the study of effects of one-dimensional inhomogeneities of the exchange constant on the wave spectrum in a ferromagnet.
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ushakov A. V., Karpov I. V., Lepeshev A. A., Petrov M. I.
Заглавие : Enhancing of magnetic flux pinning in YBa2Cu3O7-x/CuO granular composites
Коллективы : Ministry of Education and Science of the Russian Federation [11.370.2014/K]
Место публикации : J. Appl. Phys.: American Institute of Physics, 2015. - Vol. 118, Is. 2. - Ст.023907. - ISSN 0021-8979, DOI 10.1063/1.4926549
Примечания : Cited References: 27. - This work was supported in part by the Ministry of Education and Science of the Russian Federation (Project No. 11.370.2014/K).
Предметные рубрики: HIGH-TEMPERATURE SUPERCONDUCTORS
T-C SUPERCONDUCTORS
CRITICAL CURRENTS
GRAIN-BOUNDARIES
CRYSTALS
DEFECTS
Аннотация: This paper shows that the combination of self-assembled structures in the form of "whiskers" and nanoparticles, which appear as a result of the joint sintering powders YBa2Cu3O7-x and arc nanopowders CuO, leads to a significant increase in the current density and the appearance of the peak effect in strong magnetic fields range. Very high critical current density appears from a complex vortex pinning, where the defects in the form of "whiskers" provides more energy of pinning, and nanoparticles inhibit the flux creep. Regulation of the morphology of such structures can be achieved by simple change of the concentration of nanodispersed additives. It is shown that the optimal additive is CuO equal to 20 wt. %. © 2015 AIP Publishing LLC.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ignatchenko V. A., Felk V. A.
Заглавие : Exchange narrowing of magnetic resonance linewidths in inhomogeneous ferromagnets
Место публикации : Phys. Rev. B: AMERICAN PHYSICAL SOC, 2005. - Vol. 71, Is. 9. - Ст.94417. - ISSN 1098-0121, DOI 10.1103/PhysRevB.71.094417
Примечания : Cited References: 32
Предметные рубрики: AMORPHOUS FERROMAGNETS
RANDOM ANISOTROPY
NANOCRYSTALLINE
CRYSTALS
ALLOYS
Ключевые слова (''Своб.индексиров.''): ferromagnetic material--anisotropy--article--calculation--correlation analysis--crystal structure--magnetism--mathematical analysis--nanotechnology--nuclear magnetic resonance
Аннотация: The theory of exchange narrowing of ferromagnetic and spin-wave resonance linewidths in ferromagnets with the randomly inhomogeneous magnetic anisotropy is developed. The calculation is carried out by the method of averaged Green functions in the framework of the coherent potential approximation (CPA). One- and three-dimensional inhomogeneities with an arbitrary correlation wave number k(c) are considered (r(c)=k(c)(-1) is the correlation radius of the inhomogeneities). The method of the approximate solution of the CPA equation is proposed which has the quick convergence. Effects of exchange narrowing of the magnetic resonance lines and shifts of these lines are calculated in the whole region of the values of the correlation wave number k(c). The approximate analytical expressions for the linewidth of the FMR in the limiting cases of the small and large k(c) are obtained. Large narrowing of the FMR and spin-wave linewidths with the decrease of the correlation, radius of inhomogeneities is the substantiation. of the main advantage of nanocrystalline and amorphous materials over usual polycrystals when they are used at high frequency devices.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krylov A. S., Sofronova S. N., Kolesnikova E. M., Ivanov Y. N., Sukhovsky A. A., Goryainov S. V., Ivanenko A. A., Shestakov N. P., Kocharova A. G., Vtyurin A. N.
Заглавие : Experimental and theoretical methods to study structural phase transition mechanisms in K3WO3F3 oxyfluoride
Коллективы : Russian Foundation for Basic Research [4828.2012.2, 12-02-31205]; Federal Special Program "Scientific and scientific-pedagogical staff of innovative Russia" [8379]
Место публикации : J. Solid State Chem. - 2014. - Vol. 218. - P.32-37. - ISSN 0022-4596, DOI 10.1016/j.jssc.2014.05.028. - ISSN 1095-726X
Примечания : Cited References: 21. - The Authors are grateful to Prof. Zinenko V.I. for constructive discussion of the results. The work has been done with financial support of the Russian Foundation for Basic Research projects nos. 4828.2012.2, 12-02-31205; Federal Special Program "Scientific and scientific-pedagogical staff of innovative Russia" project no. 8379.
Предметные рубрики: LATTICE-DYNAMICS
RAMAN-SCATTERING
ELPASOLITE
(NH4)3WO3F3
SPECTROSCOPY
CRYSTALS
Ключевые слова (''Своб.индексиров.''): raman spectroscopy--ir spectroscopy--nmr spectroscopy--high hydrostatic pressure--oxyfluorides--lattice dynamics calculations
Аннотация: The results of structural phase transitions mechanisms study in K3WO3F3oxyfluoride are represented by different experimental and theoretical methods. The structural phase transition anomalies at T1=452 K and T2=414 K of Raman and IR spectra have been analyzed. Using vibrational spectroscopy methods, the NMR-experiment has been done to clarify the nature of found phase transitions: displacive types or order-disorder types. The model of “disordered” crystal was proposed, and the results of lattice dynamics calculation in frameworks of the generalized Gordon–Kim method of ordered (R3) and “disordered” crystals were compared. The high pressure phases were studied by the Raman technique too.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Pankin P. S., Sutormin V. S., Gunyakov V. A., Zelenov F. V., Tambasov I. A., Masyugin A. N., Volochaev M. N., Baron F. A., Chen K. P., Zyryanov V. Ya., Vetrov S. Ya., Timofeev I. V.
Заглавие : Experimental implementation of tunable hybrid Tamm-microcavity modes
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Government of Krasnoyarsk Territory; Krasnoyarsk Region Science and Technology Support Fund [19-42-240004]; Russian Foundation for Basic Research, TaiwanRussian Foundation for Basic Research (RFBR) [19-52-52006, MOST 108-2923-E-009-003-MY3]; Russian FederationRussian Federation [MK-4012.2021.1.2]; Krasnoyarsk Regional Center of Research Equipment of Federal Research Center KSC SB RAS
Место публикации : Appl. Phys. Lett. - 2021. - Vol. 119, Is. 16. - Ст.161107. - ISSN 0003-6951, DOI 10.1063/5.0067179. - ISSN 1077-3118(eISSN)
Примечания : Cited References: 60. - The authors are grateful to M. N. Krakhalev for helpful discussions. Electrical control of hybrid modes was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research, Project No. 19-42-240004. Temperature control of hybrid modes was funded by Russian Foundation for Basic Research, Project No. 19-52-52006 and No. MOST 108-2923-E-009-003-MY3, Taiwan. P. S. Pankin is grateful for the support of the President of the Russian Federation under Grant No. MK-4012.2021.1.2. This study was supported by the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center KSC SB RAS
Предметные рубрики: STATES
CRYSTALS
LAYER
Аннотация: Mode hybridization is a unique way to manipulate the mode inside a fixed cavity or at interface. For example, Tamm plasmon-polariton at solid interface can be spectrally shifted without tuning the interface. Experimental implementation of tunable hybrid Tamm-microcavity modes is reported. The hybrid modes are excited in a one-dimensional photonic crystal bounded with a gold layer by attaching a nematic liquid crystal microcavity. Coupling between Tamm plasmon-polariton and microcavity modes leads to repulsion of their dispersion curves controlled by the refractive index of a liquid crystal and the polarization of incident light. Effective tuning of hybrid modes through heating or applying an external electric field to the liquid crystal layer is demonstrated. The experimentally measured strength coupling value between Tamm and microcavity modes was 20.7 meV.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Flerov I. N., Gorev M. V., Aleksandrov K. S., Tressaud A., Fokina V. D.
Заглавие : Ferroelastic phase transitions in fluorides with cryolite and elpasolite structures
Место публикации : Crystallogr. Rep. - 2004. - Vol. 49, Is. 1. - P.100-107. - ISSN 1063-7745, DOI 10.1134/1.1643969
Примечания : Cited References: 43
Предметные рубрики: NUCLEAR MAGNETIC-RESONANCE
THERMODYNAMIC PROPERTIES
RB2KMIIIF6 ELPASOLITES
NEUTRON-DIFFRACTION
CRYSTALS
PEROVSKITES
DIAGRAM
SC
RB2KGAXSC1-XF6
SCATTERING
Аннотация: The ferroelastic phase transitions are investigated in several series of fluoride crystals belonging to the elpasolite and cryolite families (space group Fm (3) over barm) with the general formula A(2)BB'F-6. The influence of the size and shape of cations and anions on the entropy and the mechanism of structural distortions is discussed. (C) 2004 MAIK "Nauka/Interperiodica".
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Flerov I. N., Kartashev A. V., Grankina V. A.
Заглавие : Heat capacity and phase transitions in NH4LiSO4, Cs-x(NH4)(1-x) LiSO4, and RbLiSO4
Разночтения заглавия :авие SCOPUS: Heat capacity and phase transitions in NH4LiSO4, Csx(NH4)1-xLiSO4, and RbLiSO 4
Место публикации : Phys. Solid State: AMER INST PHYSICS, 2005. - Vol. 47, Is. 4. - P720-728. - ISSN 1063-7834, DOI 10.1134/1.1913987
Примечания : Cited References: 29
Предметные рубрики: ROOM-TEMPERATURE
MONTE-CARLO
LINH4SO4
SUBSTITUTION
CRYSTALS
SULFATE
CSLISO4
Аннотация: The heat capacity of NH4LiSO4, RbLiSO4, and Cs-x(NH4)(1 - x) LiSO4 crystals and its behavior over a broad temperature range including the phase transition regions were studied. The entropy changes corresponding to structural transformations in these crystals were found not to be characteristic of straightforward ordering of structural blocks. The results obtained are discussed in terms of phenomenological theory and model concepts. (C) 2005 Pleiades Publishing, Inc.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : MELERO J. J., BARTOLOME J., BURRIEL R., ALEKSANDROVA I. P., PRIMAK S.
Заглавие : HEAT-CAPACITY MEASUREMENT OF THE SUCCESSIVE PHASE-TRANSITIONS IN CS2ZNI4
Разночтения заглавия :us: Heat capacity measurement of the successive phase transitions in Cs2ZnI4
Место публикации : Solid State Commun.: PERGAMON-ELSEVIER SCIENCE LTD, 1995. - Vol. 95, Is. 4. - P201-206. - ISSN 0038-1098, DOI 10.1016/0038-1098(95)00261-8
Примечания : Cited References: 20
Предметные рубрики: INCOMMENSURATE PHASE
SEQUENCE
CRYSTALS
CS2CDI4
Ключевые слова (''Своб.индексиров.''): ferroelectrics--heat capacity--phase transitions--incommensurate phases
Аннотация: The heat capacity of a Cs2ZnI4 single crystal has been measured by means of AC calorimetry. Three anomalies have been detected corresponding to a normal to inconmensurate phase transition at T-I = 116.9+/-0.1 K, an incommensurate to commensurate lock-in transition at T-L = 107.58+/-0.05 K, and a structural transition from a commensurate orthorhombic to a monoclinic phase at T-C = 93.77+/-0.05 K with thermal hysteresis. The lock-in transition has the peculiarity of being discontinuous but not showing any measurable hysteresis. After comparison with the Landau model predictions for the heat capacity, derived for the k(Delta) = (1/2 + Delta)a* case, it is concluded that Cs2ZnI4 lies close to the Lifschitz point of coexistence of the normal, incommensurate and commensurate phases.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisov V. M., Denisova L. T., Irtyugo L. A., Patrin G. S., Volkov N. V., Chumilina L. G.
Заглавие : High-Temperature Heat Capacity of Y2.9Ho0.1Al5O12
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2013. - Vol. 55, Is. 4. - P.692-695. - ISSN 1063-7834, DOI 10.1134/S1063783413040082
Примечания : Cited References: 21
Предметные рубрики: CRYSTALS
GARNETS
Аннотация: This paper presents data on the heat capacity of Y2.9Ho0.1Al5O12 as a function of temperature (360-1020 K). The experimental data obtained are used to derive the thermodynamic functions of the oxide compound.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vtyurin A. N., Goryainov S. V., Zamkova N. G., Zinenko V. I., Krylov A. S., Krylova S. N., Shefer A. D.
Заглавие : Hydrostatic pressure-induced phase transitions in RbMnCl3: Raman spectra and lattice dynamics
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2004. - Vol. 46, Is. 7. - P1301-1310. - ISSN 1063-7834, DOI 10.1134/1.1778456
Примечания : Cited References: 16
Предметные рубрики: CRYSTALS
SPECTROSCOPY
Аннотация: Raman scattering spectra of RbMnCl3 are measured at room temperature under high hydrostatic pressure. The results are interpreted based on first principles lattice dynamics calculations. The experimental data obtained correlate with the calculations in the low frequency domain but disagree slightly in the region of high-frequency vibrations. The transition from the hexagonal to the cubic perovskite phase observed earlier (near 0.7 GPa) was confirmed, and new transitions to lower symmetry distorted phases were discovered (at 1.1 and 5 GPa). (C) 2004 MAIK "Nauka / Interperiodica".
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Stanislavchuk T. N., Chukalina E. P., Popova M. N., Bezmaternykh L. N., Gudim I. A.
Заглавие : Investigation of the iron borates DyFe3(BO3)(4) and HoFe3(BO3)(4) by the method of Er3+ spectroscopic probe
Разночтения заглавия :авие SCOPUS: Investigation of the iron borates DyFe3(BO3)4 and HoFe3(BO3)4 by the method of Er3+ spectroscopic probe
Место публикации : Phys. Lett. A: ELSEVIER SCIENCE BV, 2007. - Vol. 368, Is. 5. - P408-411. - ISSN 0375-9601, DOI 10.1016/j.physleta.2007.04.044
Примечания : Cited References: 16
Предметные рубрики: GDFE3(BO3)(4)
CRYSTALS
Ключевые слова (''Своб.индексиров.''): rare-earth iron borates--magnetic ordering--optical spectroscopy--magnetic ordering--optical spectroscopy--rare-earth iron borates
Аннотация: Temperature-dependent high-resolution optical spectra of the Er3+ probe ion in DyFe3(BO3)(4) and HoFe3(BO3)(4) are reported. The data provide the temperature of magnetic ordering and direction of the Fe3+ magnetic moments. Both compounds order magnetically at T-N = 39 +/- 1K. The magnetic structure of DyFe3(BO3)(4) is of the easy-axis type, while that of HoFe3(BO3)(4) is of the easy-plane type. The role of anisotropic interactions between the iron and the rare-earth subsystems is discussed. (c) 2007 Elsevier B.V. All rights reserved.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gorev M. V., Bogdanov E. V., Flerov I. N., Kocharova A. G., Laptash N. M.
Заглавие : Investigation of thermal expansion, phase diagrams, and barocaloric effect in the (NH4)(2)WO2F4 and (NH4)(2)MoO2F4 oxyfluorides
Коллективы :
Разночтения заглавия :авие SCOPUS: Investigation of thermal expansion, phase diagrams, and barocaloric effect in the (NH4)2WO2F4 and (NH4)2MoO2F4 oxyfluorides
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2010. - Vol. 52, Is. 1. - P167-175. - ISSN 1063-7834, DOI 10.1134/S1063783410010294
Примечания : Cited References: 27. - This study was performed within the framework of the Interdisciplinary Integration Project no. 34 of the Siberian Branch of the Russian Academy of Sciences and supported by the Krasnoyarsk Regional Science Foundation and the Russian Foundation for Basic Research within the framework of the project "Sibir'" ( grant no. 09-02-98001) and by the Council on Grants from the President of the Russian Federation for the Support of Leading Scientific Schools ( project no. NSh-1011.2008.2).
Предметные рубрики: TRANSITIONS
CRYSTALS
DIFFRACTION
MECHANISM
PRESSURE
Аннотация: The thermal expansion along the principal crystallographic axes of the (NH4)(2)WO2F4 and (NH4)(2)MoO2F4 oxyfluorides has been studied. The anomalous behavior of alpha (i) (T) due to the phase transitions has been revealed at T (1) = 271.4 K and T (2) a parts per thousand 180 K for the molybdate and at T (1) = 201.5 K and T (2) a parts per thousand 161 K for the tungstate. The quantities dT/dp and dT/d sigma (i) , which characterize the dependence of the phase transition temperatures on the hydrostatic and uniaxial pressures, have been determined from analyzing the results of studies of the thermal expansion and heat capacity with the use of the Pippard relations. The p-T and alpha (i) -T phase diagrams reflect different characters of the influence of the pressure on the stability of the initial and distorted phases of the oxyfluorides. The magnitudes of the extensive and intensive barocaloric effects determined in the vicinity of the structural phase transitions are as follows: Delta S (BCE) varies from approximately -10 to -17 J/mol K and Delta T (AD) a parts per thousand 8-17 K for the molybdate and Delta S (BCE) varies from approximately -10 to -17 J/mol K and Delta T (AD) a parts per thousand 8-13 K for the tungstate.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zinenko V. I., Zamkova N. G., Maksimov E. G., Sofronova S. N.
Заглавие : Lattice dynamics and ferroelectric instability in ordered and disordered PbSc1/2Ta1/2O3 and PbSc1/2Nb1/2O3 solid solutions
Разночтения заглавия :авие SCOPUS: Lattice dynamics and ferroelectric instability in ordered and disordered PbSc1/2Ta1/2O3 and PbSc1/2Nb 1/2O3 solid solutions
Место публикации : J. Exp. Theor. Phys.: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2007. - Vol. 105, Is. 3. - P617-625. - ISSN 1063-7761, DOI 10.1134/S1063776107090191
Примечания : Cited References: 23
Предметные рубрики: RELAXOR FERROELECTRICS
PHASE-TRANSITION
LOCAL-STRUCTURE
PB(SC1/2NB1/2)O-3
PEROVSKITE
CRYSTALS
Ключевые слова (''Своб.индексиров.''): dipole moment--lattice vibrations--negative ions--phonons--positive ions--solid solutions--dynamic born charges--ferroelectric instabilities--frequency spectra--gordon-kim models--oxygen anions--phonon spectra--ferroelectricity
Аннотация: The dynamic Born charges and the frequency spectra of lattice oscillations in the crystals of ordered and disordered PbSc1/2Ta1/2O3 (PST) and PbSc1/2Nb1/2O3 (PSN) solid solutions have been calculated within the framework of the generalized Gordon-Kim model with allowance for the dipole and quadrupole polarizabilities. The phonon spectra of both compounds contain ferroelectric soft modes. The influence of various interactions on the magnitude of dynamic charges and ferroelectric instability in PSN and PST solid solutions has been studied and it is shown that both these charges and the ferroelectric instability are determined by the competition between long-range dipole-dipole interactions and short-range dipole-charge interactions, the determining role played by the interaction of Nb (Ta) cations and oxygen anions in the Nb-O (Ta-O) bond direction.
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