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1.
Orlov, Y. S.
Construction of a Multielectron Basis for Mott Insulators with Strong Electron Correlations, Spin-Orbit Interaction, and Covalence / Y. S. Orlov, S. G. Ovchinnikov> // J. Exp. Theor. Phys. - 2009. -
Vol. 109
,
Is. 2
. - P. 322-338,
DOI
10.1134/S1063776109080196. - Cited References: 35 . - ISSN 1063-7761
РУБ
Physics, Multidisciplinary
Рубрики:
NARROW ENERGY BANDS
MAGNETIC ANISOTROPY ENERGY
ORIGIN
TRANSITION
PHYSICS
MANGANITES
OXIDES
CHARGE
Аннотация:
We propose that the apparatus of quantum mechanics of a free atom (in particular, the theory of nj symbols and Rakah-Wigner genealogic coefficients generalized to the case of point groups and widely used in crystal field theory) be used for constructing multielectron bases with allowance for covalence and spin-orbit interaction. This allows us to take into account the electron-electron interaction for 3d ions the most comprehensively. The basis constructed in this way can be used in the generalized strong coupling method for the multiband p-d model in describing the structure of the quasiparticle energy spectrum and physical properties of systems with strong electron correlations. The procedure of construction and computation is demonstrated for the (5)T(2g) term in the d(6) configuration of the transition metal atom in an octahedral field. The mechanism for the emergence of magnetic anisotropy in S ions (Fe(3+) and Mn(2+)) due to covalent mixing of d(6) (L) under bar configurations with a nonzero orbital angular momentum ((L) under bar is a hole in ligands) is demonstrated
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Публикация на русском языке
Орлов, Юрий Сергеевич. Построение многоэлектронного базиса для моттовских диэлектриков с учетом сильных электронных корреляций, спин-орбитального взаимодействия и ковалентности [Текст] / Ю. С. Орлов, С. Г. Овчинников // Журн. эксперим. и теор. физ. - 2009. - Т. 136 Вып. 2. - С. 377-392
Держатели документа:
[Orlov, Yu S.
Ovchinnikov, S. G.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Ovchinnikov, S. G.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
ИФ СО РАН
Доп.точки доступа:
Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич
}
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2.
Contribution of Co3+
ions to the high-temperature magnetic and electrical properties of GdCoO3 / V. A. Dudnikov [et al.]> // J. Exp. Theor. Phys. - 2012. -
Vol. 114
,
Is. 5
. - P. 841-849,
DOI
10.1134/S106377611203003X. - Cited References: 28. - This work was supported by the Ural Branch of the Russian Academy of Sciences and Siberian Branch of the Russian Academy of Sciences (project no. 40), the Russian Foundation for Basic Research (project nos. 09-02-00171-a, 10-02-00251), program 2.3 of the Department of Physical Sciences of Russian Academy of Sciences, and Nonprofit Dinastiya Foundation. . - ISSN 1063-7761
РУБ
Physics, Multidisciplinary
Рубрики:
SPIN-STATE
RCOO3 R
TRANSITIONS
COBALTITES
LACOO3
OXIDES
SM
EU
ND
Аннотация:
The temperature dependence of the static magnetization of polycrystalline rare-earth cobaltite GdCoO3 is measured in the temperature range 2-800 K. The magnetic behaviors of GdCoO3 and Gd3+ are found to be different at temperatures above room temperature, which is caused by the appearance of a contribution from Co3+ ions at high temperatures. The temperature dependence of the magnetic susceptibility of GdCoO3 is determined by the magnetization of rare-earth gadolinium ions and the additional paramagnetic contribution induced by the thermally excited magnetic terms of Co3+ ions. The LDA + GTB method is used to calculate the electronic structure of GdCoO3 in the temperature range 0-300 K with allowance for strong electron correlations. The energy spectrum of GdCoO3 is found to have intragap states that decrease the dielectric gap width with increasing temperature.
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Публикация на русском языке
Вклад ионов Co3+ в высокотемпературные магнитные и электрические свойства GdCoO3 [Текст] / В. А. Дудников [и др.] // Ж. эксперим. и теор. физ. : Наука, 2012. - Т. 141 Вып. 5. - С. 966-975
Держатели документа:
[Dudnikov, V. A.
Ovchinnikov, S. G.
Orlov, Yu S.
Kazak, N. V.
Patrin, G. S.
Yurkin, G. Yu] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Dudnikov, V. A.] Reshetnev Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
[Ovchinnikov, S. G.
Patrin, G. S.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
[Michel, C. R.] Univ Guadalajara, Guadalajara 44430, Jalisco, Mexico
Доп.точки доступа:
Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Orlov, Yu.S.; Орлов, Юрий Сергеевич; Kazak, N. V.; Казак, Наталья Валерьевна; Michel, C. R.; Patrin, G. S.; Патрин, Геннадий Семёнович; Yurkin, G.Yu.; Юркин, Глеб Юрьевич
}
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3.
Borisov, A. A.
Doping dependence of the band structure and chemical potential in cuprates by the generalized tight-binding method / A. A. Borisov, V. A. Gavrichkov, S. G. Ovchinnikov> //
Mod. Phys. Lett. B. - 2003. -
Vol. 17
,
Is. 10-12
. - P. 479-486,
DOI
10.1142/S0217984903005500. - Cited References: 12 . - ISSN 0217-9849
РУБ
Physics, Applied + Physics, Condensed Matter + Physics, Mathematical
Рубрики:
CORRELATED ELECTRONS
SUPERCONDUCTIVITY
OXIDES
Аннотация:
Quasiparticle band structure in hole doped CuO2 layer is calculated with account for strong electron correlations in the framework of multiband p-d model. For undoped layer we obtain the charge-transfer antiferromagnetic insulator. With doping unusual impurity-like quasiparticle appears at the top of the valence band with spectral weight proportional to doping concentration. In the overdoped regime the band structure in the paramagnetic phase results in the doping dependent Fermi surface in agreement to ARPES data.
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Держатели документа:
LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Krasnoyarsk State Univ, Theoret Phys Chair, Krasnoyarsk 660041, Russia
ИФ СО РАН
Доп.точки доступа:
Gavrichkov, V. A.; Гавричков, Владимир Александрович; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; International Conference on Modern Problems in Superconductivity(3 ; 2002 ; Sept. ; 9-14 ; Yalta, Ukrain)
}
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4.
Ovchinnikov, S. G.
Effective Hamiltonian for HTSC cuprates taking into account electron-phonon interaction in the strong-correlation regime / S. G. Ovchinnikov, E. I. Shneider> // J. Exp. Theor. Phys. - 2005. -
Vol. 101
,
Is. 5
. - P. 844-855,
DOI
10.1134/1.2149064. - Cited References: 38. - This work was supported by the Russian Foundation for Basic Research (project no. 03-02-16124), the program “Quantum Macrophysics” of the Presidium of the Russian Academy of Sciences, the Foundation in Support for Russian Science, the Foundation of Noncommercial . - ISSN 1063-7761
РУБ
Physics, Multidisciplinary
Рубрики:
HIGH-TEMPERATURE SUPERCONDUCTORS
D-WAVE SUPERCONDUCTIVITY
T-C
DISPERSION
SCATTERING
OXIDES
STATE
MODEL
Кл.слова (ненормированные):
Electron beams
--
Electronic structure
--
Optimization
--
Phonons
--
Electron correlations
--
Hubbard X operators
--
Spin-photon interaction
--
Hamiltonians
Аннотация:
Electron-phonon interaction is sequentially derived from a realistic p-d multiband model for the cuprates under conditions of strong electron correlations. The electronic structure is described using the representation of the Hubbard X operators in a generalized tight-binding method. Dependences of the diagonal and off-diagonal (on lattice sites) matrix elements of electron-phonon interaction on the wavevectors are found for three phonon modes, namely, breathing, apical breathing, and bending modes. The interactions of the breathing and bending modes with electrons are shown to contribute to the formation of kinks in the (0; 0)-(pi; pi) and (0; 0)-(pi; 0) directions, respectively. A low-energy t-J* model with phonons is developed; apart from electron-phonon interaction, it also includes spin-phonon interaction. The elimination of phonons gives an effective electron-electron interaction that depends on the occupation number of a multielectron term and on the carrier concentration due to strong electron correlations. (c) 2005 Pleiades Publishing, Inc.
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Публикация на русском языке
Овчинников, Сергей Геннадьевич. Эффективный гамильтониан для ВТСП-купратов с учетом электрон-фононного взаимодействия в режиме сильных корреляций [Текст] / С. Г. Овчинников, Е. И. Шнейдер // Журнал экспериментальной и теоретической физики. - 2005. - Т. 128 Вып. 5. - С. 974-986
Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirenskii Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, Akademgorodok, 660036, Russian Federation
Доп.точки доступа:
Shneider, E. I.; Шнейдер, Елена Игоревна; Овчинников, Сергей Геннадьевич
}
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5.
Ovchinnikov, S. G.
Effects of intense electron correlations on x-ray and x-ray electron copper spectra of high-temperature superconductors / S. G. Ovchinnikov, P. V. Avramov> // Fiz. Tverd. Tela. - 1995. -
Vol. 37
,
Is. 9
. - P. 2559-2567. - Cited References: 22 . - ISSN 0367-3294
РУБ
Physics, Condensed Matter
Рубрики:
HIGH-ENERGY SPECTROSCOPY
HIGH-TC SUPERCONDUCTORS
SATELLITES
LA2CUO4
OXIDES
HOLES
STATE
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Доп.точки доступа:
Avramov, P. V.; Аврамов, Павел Вениаминович; Овчинников, Сергей Геннадьевич
}
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6.
Avramov, P. V.
Effects of the intense electron correlations on the shape of x-ray CuK absorption spectra of La2-xSrxCuO4 / P. V. Avramov, S. G. Ovchinnikov> // Zhurnal Eksperimentalnoi Teor. Fiz. - 1995. -
Vol. 108
,
Is. 4
. - P. 1479-1488. - Cited References: 28 . - ISSN 0044-4510
РУБ
Physics, Multidisciplinary
Рубрики:
HIGH-TC SUPERCONDUCTIVITY
EDGE STRUCTURE
LA2CUO4
SATELLITES
ALPHA
EXCITATIONS
COPPER
OXIDES
STATE
SHAKE
WOS
Доп.точки доступа:
Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Аврамов, Павел Вениаминович
}
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7.
Electron structure and
electron-phonon interaction in the strongly correlated electron system of cuprates / S. G. Ovchinnikov [et al.]> // Low Temp. Phys. - 2006. -
Vol. 32
,
Is. 4-5
. - P. 483-488 ; Физика низких температур,
DOI
10.1063/1.2199450. - Cited References: 37 . - ISSN 1063-777X
РУБ
Physics, Applied
Рубрики:
HIGH-TEMPERATURE SUPERCONDUCTORS
HIGH-TC SUPERCONDUCTIVITY
C SUPERCONDUCTORS
J MODEL
BAND
REPRESENTATION
REGIME
OXIDES
Аннотация:
The generalized tight-binding method presents a practical realization of the scheme that describes quasiparticles in a strongly correlated electron system and consists of exact intra-cell diagonalization of the model Hamiltonian and perturbative treatment of the inter-cell hoppings. In the present paper this method and its ab initio modification are applied to undoped and weakly doped HTSC cuprates. Results are in very good agreement with the experimental ARPES data on various compounds. Starting with a multiband p-d model the realistic effective low-energy Hamiltonian of strongly correlated electrons interacting with spin fluctuations and phonons is derived both for hole- and electron-doped systems. Without electron-phonon interaction the pure magnetic mechanism of pairing does not provide the correct value of T, even for single-layer La2-xSrxCuO4 and Nd2-xCexCuO4. (c) 2006 American Institute of Physics.
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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
L. V. Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk 660036, Russian Federation
Доп.точки доступа:
Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Gavrichkov, V. A.; Гавричков, Владимир Александрович; Korshunov, M. M.; Коршунов, Максим Михайлович; Shneyder, E. I.; Шнейдер, Елена Игоревна
}
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8.
Gavrichkov, V. A.
Electronic structure and order parameter symmetry in high-temperature superconductors / V. A. Gavrichkov, E. V. Kuz'min, S. G. Ovchinnikov> // Uspekhi Fiz. Nauk. - 2000. -
Vol. 170
,
Is. 2
. - P. 189-192. - Cited References: 31 . - ISSN 0042-1294
РУБ
Physics, Multidisciplinary
Рубрики:
CORRELATED ELECTRONS
HUBBARD-MODEL
OXIDES
LA2-XSRXCUO4
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Держатели документа:
LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Krasnoyarsk State Univ, Krasnoyarsk, Russia
ИФ СО РАН
Доп.точки доступа:
Kuz'min, E. V.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Гавричков, Владимир Александрович
}
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9.
Engineering oxygen vacancies
towards self-activated BaLuAlxZn4-xO7-(1-x)/2 photoluminescent materials: An experimental and theoretical analysis / L. Ma [et al.]> // Phys. Chem. Chem. Phys. - 2015. -
Vol. 17
,
Is. 46
. - P. 31188-31194,
DOI
10.1039/c5cp05130d. - Cited References: 28. - The present work was supported by the National Natural Science Foundations of China (Grant No. 51572023, 51272242 and 51511130035), and Fundamental Research Funds for the Central Universities (FRF-TP-15-005A1). The author A. H. Reshak would like to acknowledge the CENTEM project, reg. no. CZ.1.05/2.1.00/03.0088, cofunded by the ERDF as part of the Ministry of Education, Youth and Sports OP RDI programme and, in the follow-up sustainability stage, supported through CENTEM PLUS (LO1402) by financial means from the Ministry of Education, Youth and Sports under the National Sustainability Programme I. Computational resources were provided by MetaCentrum (LM2010005) and CERIT-SC (CZ.1.05/3.2.00/08.0144) infrastructures. SA would like to thank CSIR-NPL and Physics Department IIT Delhi for financial support. This work was partly supported by the Russian Foundation for Basic Research (Grant No. 15-52-53080 GFEN_a). VVA was partly supported by the Ministry of Education and Science of the Russian Federation. . - ISSN 1463-9076
Перевод заглавия:
Разработка кислородных вакансий для самоактивируемых люминесцентных материалов BaLuAlxZn4-xO7-(1-x)/2: экспериментальный и теоретический анализ
РУБ
Chemistry, Physical + Physics, Atomic, Molecular & Chemical
Рубрики:
PHOSPHOR
LUMINESCENCE
EVOLUTION
OXIDES
IONS
Аннотация:
Novel self-activated yellow-emitting BaLuAlxZn4-xO7-(1-x)/2 photoluminescent materials were investigated by a combined experimental and theoretical analysis. The effects of Al/Zn composition modulation, calcination atmosphere and temperature on the crystal structure and photoluminescence properties have been studied via engineering oxygen vacancies. Accordingly, BaLuAl0.91Zn3.09O7 prepared in an air atmosphere was found to be the stable crystalline phase with optimal oxygen content and gave a broad yellow emission band with a maximum at 528 nm. The self-activated luminescence mechanism is ascribed to the O-vacancies based on the density functional theory (DFT) calculation. A theoretical model originating from the designed oxygen vacancies has been proposed in order to determine the influence of O-vacancies on the band structure and self-activated luminescence. Therefore, the appearance of a new local energy level in the band gap will cause the wide-band optical transitions in the studied BaLuAlxZn4-xO7-(1-x)/2 materials.
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Держатели документа:
School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing, China
Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk, Russian Federation
Functional Electronics Laboratory, Tomsk State University, Tomsk, Russian Federation
Laboratory of Semiconductor and Dielectric Materials, Novosibirsk State University, Novosibirsk, Russian Federation
Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
Council of Scientific and Industrial Research-National Physical Laboratory Dr K S Krishnan Marg, New Delhi, India
Department of Physics, Indian Institute of Technology, Hauz Khas, New Delhi, India
New Technologies-Research Centre, University of West Bohemia, Univerzitni 8, Pilsen, Czech Republic
Center of Excellence Geopolymer and Green Technology, School of Material Engineering, University Malaysia Perlis, Kangar, Perlis, Malaysia
Доп.точки доступа:
Ma, L.; Xia, Z.; Atuchin, V. V.; Атучин, Виктор Валерьевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Auluck, S.; Reshak, A. H.; Liu, Q.
}
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10.
Ferromagnetism in single-valent
manganites / I. O. Troyanchuk [et al.]> // J. Alloys Compd. - 2015. -
Vol. 619
. - P. 719-725,
DOI
10.1016/j.jallcom.2014.08.236. - Cited References: 46. - The authors would like to thank J.B. Goodenough for the fruitful discussion. This work has been supported by Belarusian Republican Foundation for Fundamental Research (Grant F14R-040). . - ISSN 0925-8388. - ISSN 1873-4669
РУБ
Chemistry, Physical + Materials Science, Multidisciplinary + Metallurgy & Metallurgical Engineering
Рубрики:
PHASE-SEPARATION
DOPED MANGANITES
DOUBLE EXCHANGE
DIFFRACTION
OXIDES
NMR
Кл.слова (ненормированные):
Magnetically ordered materials
--
Solid state reactions
--
Exchange and superexchange
--
Magnetic measurements
--
Neutron diffraction
Аннотация:
Structural and magnetization measurements have been performed on the La0.7Sr0.3Mn0.85 Nb 0.15 - x 5 + Mg x 2 + O3 stoichiometric compounds. With rise of the Mg2+ content the formal oxidation state manganese increases from +3 ( x = 0 ) up to +3.55 ( x = 0.15 ) . The compositions with 0 ⩽ x ≤ 0.08 undergo a structural transition from rhombohedral to orthorhombic symmetry below room temperature whereas x = 0.1 and x = 0.15 compounds are rhombohedral down to 2 K. The structural parameters evidence that the orthorhombic phase is not long-range orbitally ordered and that the structural transition is associated with a steric effect. The Mg-free compound is ferromagnetic with the Curie point of around 150 K and a magnetic moment of 3.1 μ B /Mn. The substitution of Nb5+ with Mg2+ leads to a gradual weakening of the ferromagnetic component while in the x = 0.15 compound A-type antiferromagnetic short-range order is stabilized in spite of macroscopic R 3 ¯ c symmetry. All the compositions show insulating behavior. It is suggested that ferromagnetism is originated from superexchange interactions via oxygen. Covalence enhances the positive part of the superexchange interactions whereas structural disorder induced by Nb5+ and Mg2+ ions leads to suppression of ferromagnetism.
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Держатели документа:
Sci Pract Mat Res Ctr NAS Belarus, Minsk 220072, Byelarus
Helmholtz Zentrum Berlin, D-14109 Berlin, Germany
Joint Inst Nucl Res, Dubna 141980, Russia
LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Inst Max Von Laue Paul Langevin, F-38042 Grenoble 9, France
ISMRA Univ Caen, UMR Associee CNRS 6508, Lab CRISMAT, F-14050 Caen, France
Univ Caen, F-14050 Caen, France
Доп.точки доступа:
Troyanchuk, I. O.; Bushinsky, M. V.; Sikolenko, V.; Efimov, V.; Volkov, N. V.; Волков, Никита Валентинович; Tobbens, D. M.; Ritter, C.; Raveau, B.
}
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11.
Giant red shift
of the absorption spectra due to nonstoichiometry in GdCoO3–δ / S. G. Ovchinnikov [et al.]> // JETP Letters. - 2016. -
Vol. 103
,
Is. 3
. - P. 161-166,
DOI
10.1134/S0021364016030115. - Cited References:40. - This work was supported by the Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools (project no. NSh-2886.2014.2), by the Presidium of Russian Academy of Sciences (Program 34), by the Russian Foundation for Basic Research (project nos. 16-02-00507, 16-02-00273, 16-02-00098, and 14-02-00186), and by Internationale Buro, Bundesministerium fur Bildung und Forschung (BMBF, grant no. 05K12GU2). . - ISSN 0021-3640. - ISSN 1090-6487
РУБ
Physics, Multidisciplinary
Рубрики:
TRANSITION-METAL COMPOUNDS
TOTAL-ENERGY CALCULATIONS
AUGMENTED-WAVE METHOD
ELECTRONIC-STRUCTURE
MAGNETIC-PROPERTIES
SPIN TRANSITION
BAND-GAPS
BASIS-SET
LaCoO3
OXIDES
Аннотация:
The GdCoO3–δ perovskite is a semiconductor with the energy gap Eg ≈ 0.5 eV from electrical transport measurements. It reveals unusual optical absorption spectra without transparency window expected for semiconductors. Instead we have measured the narrow transmittance peak at the photon energy ε0 = 0.087 eV. To reconcile the transport and optical data we have studied the effect of oxygen vacancies on the electronic structure of the GdCoO3–δ. We have found that oxygen vacancies result in the in-gap states inside the charge-transfer energy gap of the GdCoO3. It is a multielectron effect due to strong electron correlations forming the electronic structure of the GdCoO3–δ. These in-gap states decrease the transparency window and result in a narrow absorption minimum. The predicted temperature dependence of the absorption spectra has been confirmed by our measurements.
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Публикация "на русском языке"
Giant red shift of the absorption spectra due to nonstoichiometry in GdCoO3–δ [Текст] / S. G. Ovchinnikov [и др.] // Письма в Журн. эксперим. и теор. физ. : Наука, 2016. - Т. 103 Вып. 3-4. - С. 177-183
Держатели документа:
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Siberian State Technol Univ, Krasnoyarsk 660049, Russia.
Доп.точки доступа:
Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Orlov, Yu. S.; Орлов, Юрий Сергеевич; Kuzubov, A. A.; Кузубов, Александр Александрович; Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Sokolov, A. E.; Соколов, Алексей Эдуардович; Zabluda, V. N.; Заблуда, Владимир Николаевич; Naumov, S. B.; Shestakov, N. P.; Шестаков, Николай Петрович; Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools [NSh-2886.2014.2]; Presidium of Russian Academy of Sciences [34]; Russian Foundation for Basic Research [16-02-00507, 16-02-00273, 16-02-00098, 14-02-00186]; Internationale Buro, Bundesministerium fur Bildung und Forschung (BMBF) [05K12GU2]
}
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12.
Heat capacity and
thermodynamic properties of HoMnO3 in the range of 364–1046 K / L. T. Denisova [et al.]> // Phys. Solid State. - 2016. -
Vol. 58
,
Is. 3
. - P. 481-484,
DOI
10.1134/S1063783416030070. - Cited References:27 . - ISSN 1063-7834. - ISSN 1090-6460
РУБ
Physics, Condensed Matter
Рубрики:
High-temperature
Rare-earth
YMnO3
Oxides
System
Аннотация:
The temperature dependence of the molar heat capacity of HoMnO3 has been measured by differential scanning calorimetry. The experimental data have been used to calculate the thermodynamic properties of the oxide compound (changes in the enthalpy H°(T)–H°(364 K), entropy S°(T)–S°(364 K), and reduced Gibbs energy Φ°(T)). The data on the heat capacity of HoMnO3 have been generalized in the range of 40–1000 K.
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Публикация на русском языке
Теплоемкость и термодинамические свойства HoMnO3 в области 364-1046 K [Текст] / Л. Т. Денисова [и др.] // Физ. тверд. тела : Физико-технический институт им. А. Ф. Иоффе РАН, 2016. - Т. 58 Вып. 3. - С. 469-472
Держатели документа:
Siberian Fed Univ, Svobodnyi Pr 79, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Akademgorodok 50, Krasnoyarsk 660036, Russia.
Доп.точки доступа:
Denisova, L. T.; Chumilina, L. G.; Shaikhutdinov, K. A.; Шайхутдинов, Кирилл Александрович; Patrin, G. S.; Патрин, Геннадий Семёнович; Denisov, V. M.
}
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13.
High-temperature heat capacity
of copper metaborate CuB2O4 / V. M. Denisov [et al.]> // Phys. Solid State. - 2012. -
Vol. 54
,
Is. 10
. - P. 2142-2144,
DOI
10.1134/S1063783412100113. - Cited References: 17 . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Рубрики:
SINGLE-CRYSTALS
MAGNETIC-PROPERTIES
SYSTEM
OXIDES
Аннотация:
The heat capacity of copper metaborate CuB2O4 has been measured over a wide temperature range. A correlation between the composition of the CuO-B2O3 system and the heat capacity of the oxide compounds has been found.
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Публикация на русском языке
Высокотемпературная теплоемкость метабората меди CuB2O4 // Физика твердого тела : Физико-технический институт им. А.Ф.Иоффе РАН, 2012. - Т. 54, № 10. - С. 2012-2014. - ISSN 0367-3294
Держатели документа:
[Denisov, V. M.
Denisova, L. T.
Irtyugo, L. A.
Chumilina, L. G.] Siberian Fed Univ, Inst Nonferrous Met & Mat Sci, Krasnoyarsk 660025, Russia
[Volkov, N. V.
Patrin, G. S.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Volkov, N. V.
Patrin, G. S.] Siberian Fed Univ, Inst Engn Phys & Radioelect, Krasnoyarsk 660041, Russia
Доп.точки доступа:
Denisov, V. M.; Denisova, L. T.; Irtyugo, L. A.; Volkov, N. V.; Волков, Никита Валентинович; Patrin, G. S.; Патрин, Геннадий Семёнович; Chumilina, L. G.
}
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14.
High-temperature heat capacity
of Y2.93Ho0.07Fe5O12 / V. M. Denisov [et al.]> // Phys. Solid State. - 2012. -
Vol. 54
,
Is. 11
. - P. 2205-2207,
DOI
10.1134/S1063783412110078. - Cited References: 28 . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Рубрики:
PHYSICAL-PROPERTIES
SYSTEM
OXIDES
Аннотация:
This paper presents data on the heat capacity of Y2.93Ho0.07Fe5O12 obtained in the temperature range 343-1000 K. A correlation between the composition of the Fe2O3-Y2O3 pseudobinary system and the specific heat capacity of oxide compounds is pointed out.
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Публикация на русском языке
Высокотемпературная теплоемкость Y2.93Ho0.07Fe5O12 // Физика твердого тела : Издательство "Наука", 2012. - Т. 54, N 11. - С. 2073-2075. - ISSN 0367-3294
Держатели документа:
Denisov, V. M.
Denisova, L. T.
Irtyugo, L. A.
Chumilina, L. G.] Siberian Fed Univ, Inst Nonferrous Met & Mat Sci, Krasnoyarsk 660025, Russia
Patrin, G. S.
Volkov, N. V.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Доп.точки доступа:
Denisov, V. M.; Denisova, L. T.; Irtyugo, L. A.; Patrin, G. S.; Патрин, Геннадий Семёнович; Volkov, N. V.; Волков, Никита Валентинович; Chumilina, L. G.
}
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15.
Methane oxidation over
A-site ordered and disordered Sr0.8Gd0.2CoO3−δ perovskites / S. N. Vereshchagin [et al.]> // Chem. Commun. - 2014. -
Vol. 50
,
Is. 46
. - P. 6112-6115,
DOI
10.1039/c4cc00913d. - Cited References: 20. - The authors acknowledge the financial support from SB RAS project N 38 (2012) and RFBR grant 13-02-00358. . - ISSN 1359-7345. - ISSN 1364-548X
РУБ
Chemistry, Multidisciplinary
Рубрики:
MEMBRANE REACTORS
OXYGEN
OXIDES
PERFORMANCE
COMBUSTION
FEATURES
PHASES
Аннотация:
A tetragonal phase Sr0.8Gd0.2CoO3−δ with ordered Gd3+/Sr2+ ions and oxygen vacancy sites is found to be about five times less active in the reaction of methane combustion than a quenched cubic perovskite phase with randomly distributed (disordered) Gd3+/Sr2+ ions over the A-sites of the crystal lattice.
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Держатели документа:
Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk 660036, Russia
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Доп.точки доступа:
Vereshchagin, S. N.; Solovyov, L. A.; Соловьев, Леонид Александрович; Rabchevskii, E. V.; Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Anshits, A. G.; Аншиц, Александр Георгиевич; SB RAS project [38]; RFBR [13-02-00358]
}
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16.
Mossbauer studies of
FexMn1-xS single crystals / G. M. Abramova [et al.]> // Phys. Solid State. - 2008. -
Vol. 50
,
Is. 2
. - P. 237-240,
DOI
10.1134/S1063783408020042. - Cited References: 16 . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Рубрики:
METAL-INSULATOR-TRANSITION
MAGNETIC-PROPERTIES
ALPHA-MNS
SULFIDES
MAGNETORESISTANCE
PRESSURE
SYSTEM
OXIDES
Аннотация:
Single crystals of iron manganese sulfides FexMn1-xS (0.25
WOS
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Держатели документа:
[Abramova, G. M.
Petrakovskii, G. A.
Bayukov, O. A.
Bovina, A. F.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Varnek, V. A.
Sokolov, V. V.] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
ИФ СО РАН
Доп.точки доступа:
Abramova, G. M.; Абрамова, Галина Михайловна; Petrakovskii, G. A.; Петраковский, Герман Антонович; Bayukov, O. A.; Баюков, Олег Артемьевич; Varnek, V. A.; Sokolov, V. V.; Bovina, A. F.; Бовина, Ася Федоровна
}
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17.
Val'kov, V. V.
Nature of Cooper instability of spin polarons in cuprate high-Tc superconductors / V. V. Val'kov, D. M. Dzebisashvili, A. F. Barabanov> // J. Low Temp. Phys. - 2015. -
Vol. 181
,
Is. 3-4
. - P. 134-138,
DOI
10.1007/s10909-015-1331-9. - Cited References:10. - This study was supported by the Russian Foundation for Basic Research, Projects Nos. 13-02-00523, 13-02-00909 and the Dynasty Foundation. . - ISSN 0022. - ISSN 1573-7357
Перевод заглавия:
Природа куперовской неустойчивости спиновых поляронов в купратных высокотемпературных сверхпроводниках
РУБ
Physics, Applied + Physics, Condensed Matter
Рубрики:
OXIDES
MODEL
Кл.слова (ненормированные):
High-T-c superconductors
--
Spin polarons
--
Spin-fermion model
Аннотация:
It is shown that the exchange interaction in the subsystem of localized moments of copper ions can trigger a Cooper instability in the ensemble of spin-polaron quasiparticles in cuprate high-temperature superconductors. It is important that, inherent to cuprates, strong coupling between Fermi and spin degrees of freedom leads on the one hand to formation of spin-polaron quasiparticles and, on the other hand, allows to transfer the interaction between Bose degrees of freedom onto the interaction between Fermi quasiparticles. The solution of the integral equation for the d-wave superconducting order parameter is well consistent with the available experimental data.
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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia.
MF Reshetnev Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia.
Russian Acad Sci, Inst High Pressure Phys, Troitsk 142092, Moscow Region, Russia.
Доп.точки доступа:
Dzebisashvili, D. M.; Дзебисашвили, Дмитрий Михайлович; Barabanov, A. F.; Вальков, Валерий Владимирович; Russian Foundation for Basic Research [13-02-00523, 13-02-00909]; Dynasty Foundation
}
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18.
Near-infrared luminescence and
color tunable chromophores based on Cr3+-Doped Mullite-Type Bi2(Ga,Al)4O9 solid solutions / C. Liu [et al.]> // Inorg. Chem. - 2015. -
Vol. 54
,
Is. 4
. - P. 1876-1882,
DOI
10.1021/ic502779d. - Cited References: 26. - The present work was supported by the National Natural Science Foundations of China (Grants 51002146, 51272242), Natural Science Foundations of Beijing (2132050), the Program for New Century Excellent Talents in University of Ministry of Education of China (NCET-12-0950), Beijing Nova Program (Z131103000413047), Beijing Youth Excellent Talent Program (YETP0635), the Funds of the State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University (KF201306), and Fundamental Research Funds for the Central Universities (FRF-TP-14-005A1). . - ISSN 0020-1669
Перевод заглавия:
Ближняя инфракрасная люминесценция и перестраиваемые цвет хромофоры построенные на допированных Cr3+ твердых растворах Bi2(Ga,Al)4O9 со структурой муллита.
РУБ
Chemistry, Inorganic & Nuclear
Рубрики:
PERSISTENT LUMINESCENCE
PHOSPHORS
PIGMENT
GARNET
OXIDES
FIELD
RED
Аннотация:
Cr3+-activated mullite-type Bi2Ga(4-x)AlxO9 (x = 0, 1, 2, 3, and 4) solid solutions were prepared by the solid state reaction, and their spectroscopic properties were investigated in conjunction with the structural evolution. Under excitation at 610 nm, Bi2[Ga(4-y)Aly]3.97O9:0.03Cr3+ (y = 0, 1, 2, 3, and 4) phosphors exhibited broad-band near-infrared (NIR) emission peaking at ?710 nm in the range 650?850 nm, and the optimum Cr3+ concentrations and concentration quenching mechanism were determined. Except for the interesting NIR emission, the body color changed from white (at x = 0) to green (at x = 0.08) for Bi2Ga4?xO9:xCr3+, and from light yellow (at x = 0) to deep brown (at x = 0.08) for Bi2Al4?xO9:xCr3+, respectively. Moreover, as a result of variable Al/Ga ratio, the observed body color for Bi2[Ga(4-y)Aly]3.97O9:0.03Cr3+ (y = 0, 1, 2, 3, and 4) varied from deep brown to green. The relationship between the observed colors and their diffuse reflectance spectra were also studied for the understanding of the different absorption bands. The results indicated that Cr3+-doped Bi2Ga(4-x)AlxO9 solid solutions appeared as the bifunctional materials with NIR phosphors and color-tunable pigments.
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Держатели документа:
Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China.
China Univ Geosci, Sch Mat Sci & Technol, Beijing 100083, Peoples R China.
RAS, SB, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.
Доп.точки доступа:
Liu, C.; Xia, Zhiguo; Chen, M.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Liu, Q.
}
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19.
New hexagonal perovskite
with Mn4+ and Mn5+ at distinct structural positions / N. V. Tarakina [et al.]> //
J. Phys.: Conf. Ser. - 2015. -
Vol. 644
. - Ст. UNSP 012004,
DOI
10.1088/1742-6596/644/1/012004. - Cited References:13 . - ISSN 1742-6588
Рубрики:
MAGNETIC-PROPERTIES
OXIDES
PHASES
Аннотация:
A new hexagonal perovskite, Ba7Li1.75Mn3.5O15.75, has been synthesised using microwave-assisted solid-state synthesis. Its crystal structure has elements typical for the layered hexagonal perovskites and quasi-one-dimensional
oxides
, hence representing a new polytype. Structural solution based on simultaneous refinement of X-ray and neutron diffraction data shows that Ba7Li1.75Mn3.5O15.75 crystallizes in a hexagonal unit cell with parameters a = 5.66274(2) Å and c = 16.7467(1) Å ( V = 465.063(4) Å3). Columns of face- shared octahedra occupied by Mn4+, Li+ cations and vacancies along the c axis are separated in the ab plane by barium atoms, so that every sixth layer, the coordination of Mn5+ and Li+ changes to tetrahedral. Separation of Mn4+ and Mn5+ cations in two distinct structural positions makes the structure unique. A scanning transmission electron microscopy study revealed the formation of a rhombohedrally centered supercell, which might be attributed to the ordering of manganese and lithium atoms among cationic sites.
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Доп.точки доступа:
Tarakina, N. V.; Tyutyunnik, A. P.; Bazuev, G. V.; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Berger, I. F.; Gould, C.; Nikolaenko, I. V.; Electron Microscopy and Analysis Group Conference(2015 ; Jun 02-Jul 02 ; Manchester, England)
}
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20.
New method for
regulating the activity of ABO3 perovskite catalysts / S. N. Vereshchagin [et al.]> // Kinet. Catal. - 2015. -
Vol. 56
,
Is. 5
. - P. 640-645,
DOI
10.1134/S0023158415040199. - Cited References:23. - This work was supported in part by the Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools (grant no. NSh-2886.2014.2). . - ISSN 0023. - ISSN 1608-3210. -
РУБ
Chemistry, Physical
Рубрики:
MEMBRANE REACTORS
METHANE COMBUSTION
OXIDATION
OXIDES
OXYGEN
PERFORMANCE
FEATURES
PHASES
CO
Кл.слова (ненормированные):
perovskite
--
cobalt
--
methane
--
deep oxidation
--
oxidative condensation
Аннотация:
A new possibility of changing the activity and selectivity of perovskite catalysts in the oxidative conversion of methane was demonstrated using the Sr x Gd1–x CoO3–δ (0.5 < x < 0.9) compounds as an example. It was established that, at the same chemical composition, the disordering of Sr2+/Gd3+ ions over the A positions of the crystal structure led to a significant increase in activity in the deep oxidation reaction of CH4, as compared with the samples with an ordered distribution of cations.
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Публикация на русском языке
Новый способ регулирования активности катализаторов АВО3 со структурой перовскита [Текст] / С. Н. Верещагин [и др.] // Кинетика и катализ. - М. : Наука, 2015. - Т. 56 № 5. - С. 649-664
Держатели документа:
Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Siberian Branch, Kirenskii Inst Phys, Krasnoyarsk 660036, Russia.
Доп.точки доступа:
Vereshchagin, S. N.; Solov'ev, L. A.; Соловьев, Леонид Александрович; Rabchevskii, E. V.; Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Anshits, A. G.; Аншиц, Александр Георгиевич; Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools [NSh-2886.2014.2]
}
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