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Эволюция мессбауэровских спектров людвигита Co3-xFexО2BO3 при замещении кобальта железом / Ю. В. Князев [и др.] // Физ. тверд. тела. - 2013. - Т. 55, Вып. 6. - С. 1088-1092. - Работа вып. при поддержке грантов РФФИ № 12-02-00175-а. - 12-02-90410-Укр-а. - 12-02-31543-мол-а. - гранта Президента НШ-1044.2012.2. - программы СО РАН № 38. - Фед. целевой прогр. ”Науч. и науч.-пед. кадры инновационной России 2009−2013 гг."
Аннотация: Синтезирован концентрационный ряд монокристаллов железо-кобальтовых людвигитов Co3-xFexO2BO3 (x= 0.0125, 0.025, 0.050, 0.10, 1.0). Проведены структурные исследования с помощью рентгеновской дифракции и эффекта Мессбауэра. Обнаружен предпочтительный характер заселения железом неэквивалентных кристаллографических позиций в структуре людвигита. Определена валентность замещающих ионов железа, равная трем. Для Co2FeO2BO3 выявлено усложнение структуры gamma-резонансного спектра, обусловленное композиционным беспорядком в системе.

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Переводная версия Evolution of the mossbauer spectra of ludwigite Co3-xFexO2BO3 with substitution of iron for cobalt. - [Б. м. : б. и.]

Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Князев, Юрий Владимирович; Knyazev, Yu. V.; Иванова, Наталья Борисовна; Ivanova, N.B.; Баюков, Олег Артемьевич; Bayukov, O. A.; Казак, Наталья Валерьевна; Kazak, N.V.; Безматерных, Леонард Николаевич; Bezmaternykh, L. N.; Васильев, Александр Дмитриевич; Vasiliev, A. D.
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Evolution of the mossbauer spectra of ludwigite Co3-xFexO2BO3 with substitution of iron for cobalt / Y. V. Knyazev [et al.] // Phys. Solid State. - 2013. - Vol. 55, Is. 6. - P. 1175-1179, DOI 10.1134/S1063783413060176 . - ISSN 1063-7834
Аннотация: A concentration series of single crystals of iron-cobalt ludwigites Co3-xFexO2BO3 (x = 0.0125, 0.025, 0.050, 0.10, 1.0) has been synthesized. The structure has been studied using X-ray diffraction and Mossbauer effect. A preferred occupation of nonequivalent crystallographic positions by iron in the ludwigite structure has been revealed. It has been found that the valence of substituting iron ions is three. It has been revealed that the structure of the ?-resonance spectrum of Co2FeO2BO3 is complicated due to a composition disorder in the system. В© 2013 Pleiades Publishing, Ltd.

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Публикация на русском языке Эволюция мессбауэровских спектров людвигита Co3-xFexО2BO3 при замещении кобальта железом // Физика твердого тела. - 2013. - Т. 55, Вып. 6. - С. 1088-1092

Держатели документа:
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Knyazev, Yu. V.; Князев, Юрий Владимирович; Ivanova, N. B.; Иванова, Наталья Борисовна; Bayukov, O. A.; Баюков, Олег Артемьевич; Kazak, N. V.; Казак, Наталья Валерьевна; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Vasiliev, A. D.; Васильев, Александр Дмитриевич
}
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Мёссбауэровские исследования в пленках Tb[[d]]x[[/d]]Fe[[d]]1 - x[[/d]]-сплавов с перпендикулярной магнитной анизотропией / Р. С. Исхаков [и др.] // Изв. РАН. Сер. физич. - 2013. - Т. 77, № 3. - С. 375-378DOI 10.7868/S0367676513030150. - Работа выполнена при финансовой поддержке Федеральной целевой программы “Научные и научно педагогические кадры инновационной России” на 2009–2013 гг., целевой программы “Развитие научного потенциала высшей школы” 2011 г
Аннотация: Получены аморфные ферримагнитные пленки TbxFe1 - x с перпендикулярной магнитной анизотропией и обменно-связанные структуры TbxFe1 - x/NiFe, характеризующиеся однонаправленной анизотропией. На основе мёссбауэровских исследований этих систем установлена магнитная и химическая неоднородность сплавов TbxFe1 - x компенсационных составов.

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Переводная версия Mossbauer studies on Tb x Fe1-x alloy films with perpendicular magnetic anisotropy. - [Б. м. : б. и.]

Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Исхаков, Рауф Садыкович; Iskhakov, R. S.; Баюков, Олег Артемьевич; Bayukov, O. A.; Середкин, Виталий Александрович; Seredkin, V. A.; Столяр, Сергей Викторович; Stolyar, S.V.; Яковчук, Виктор Юрьевич; Yakovchuk, V. Yu.; Фролов, Георгий Иванович; Frolov, G. I.; Бондаренко, Геннадий Васильевич; Bondarenko, G. V.
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Mossbauer studies on Tb x Fe1-x alloy films with perpendicular magnetic anisotropy / R. S. Iskhakov [et al.] // Bull. Russ. Acad. Sci.: Phys. - 2013. - Vol. 77, Is. 3. - P. 339-342, DOI 10.3103/S1062873813030155 . - ISSN 1062-8738
Аннотация: Amorphous ferrimagnetic Tb x Fe1-x films with perpendicular magnetic anisotropy and Tb x Fe1-x /NiFe exchange-coupled structures characterized by unidirectional anisotropy are obtained. The magnetic and chemical inhomogeneity of alloys of Tb x Fe1-x compensation composition is established on the basis of Mossbauer studies of these systems. В© 2013 Allerton Press, Inc.

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Публикация на русском языке Мёссбауэровские исследования в пленках Tb[[d]]x[[/d]]Fe[[d]]1 - x[[/d]]-сплавов с перпендикулярной магнитной анизотропией. - [S. l. : s. n.]

Держатели документа:
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk 660036, Russian Federation
Siberian Federal University, Krasnoyarsk 660041, Russian Federation

Доп.точки доступа:
Iskhakov, R. S.; Исхаков, Рауф Садыкович; Bayukov, O. A.; Баюков, Олег Артемьевич; Seredkin, V. A.; Середкин, Виталий Александрович; Stolyar, S. V.; Столяр, Сергей Викторович; Yakovchuk, V.Yu.; Яковчук, Виктор Юрьевич; Frolov, G. I.; Фролов, Георгий Иванович; Bondarenko, G. V.; Бондаренко, Геннадий Васильевич
}
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"γ-Fe problem" and epitaxial growth of fe on cu(001) / V. G. Myagkov [et al.] // Diffusion and Defect Data Pt.B: Solid State Phenomena. - 2012. - Vol. 190. - P. 502-505, DOI 10.4028/www.scientific.net/SSP.190.502 . - ISBN 1012-0394. - ISBN 9783037854365
Кл.слова (ненормированные):
?-Fe -- Cu-Fe system -- Magneto-volume effect -- Solid-state synthesis -- Thin films -- Cu-Fe system -- Interlayer formation -- Magnetic studies -- Magneto-volume effects -- Orientation relationship -- Pseudomorphic growth -- Residual gas -- Solid-state synthesis -- Ultra-thin -- Buffer layers -- Magnetic materials -- Mossbauer spectroscopy -- Thin films -- Epitaxial growth
Аннотация: We have observed the formation of a thin buffer layer on the Fe/Cu interface at a temperature of 520 K. Mossbauer spectroscopy and magnetic studies reveal that the residual gases in the chamber (especially oxygen) play an important role in the ultra-thin interlayer formation. It was shown that the Cu2O buffer layer does not change the Pitsh orientation relationships during epitaxial growth of ?-Fe(110) on Cu(001). Our analysis of the experimental results contradicts pseudomorphic growth and formation of ?-Fe on Cu(001). В© (2012) Trans Tech Publications.

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Доп.точки доступа:
Myagkov, V. G.; Bayukov, O. A.; Баюков, Олег Артемьевич; Zhigalov, V. S.; Жигалов, Виктор Степанович; Bykova, L. E.; Быкова, Людмила Евгеньевна; Drozdova, N. A.; Bondarenko, G. N.; Бондаренко, Галина Николаевна; Moscow International Symposium on Magnetism(5 ; 2011 ; Aug. ; 21-25 ; Moscow)
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Studies of ferroelectric and magnetic phase transitions in multiferroic PbFe0.5Ta0.5O3-PbTiO3 solid solution ceramics / I. P. Raevski [et al.] // J. Mater. Sci. - 2014. - Vol. 49, Is. 18. - P. 6459-6466, DOI 10.1007/s10853-014-8376-z. - Cited References: 35. - This study is partially supported by the Russian Foundation for Basic Research (RFBR) Project 12-08-00887_a and Research Committee of the University of Macau under Research and Development Grant for Chair Professor. . - ISSN 0022-2461. - ISSN 1573-4803

РУБ Materials Science, Multidisciplinary
Рубрики:
MOSSBAUER
   CRYSTALS
   BEHAVIOR
   NIOBATE
Аннотация: Dielectric, X-ray, Mossbauer and magnetization studies of (1 − x)PbFe0.5Ta0.5O3–(x)PbTiO3 ceramics with 0 ≤ x ≤ 0.3 have been carried out to determine the compositional evolution of ferroelectric and magnetic phase transition temperatures. Addition of PbTiO3 to PbFe0.5Ta0.5O3 increases the temperature T m of the dielectric permittivity maximum, decreases both the diffusion of this maximum and its frequency dependence. However, the Curie–Weiss temperature exceeds T m for all the compositions studied, indicating that the phase transition still remains diffused. Dilution of the (Fe, Ta)-sublattice by Ti lowers the Neel temperature T N but above a certain compositional threshold (x ≈ 0.1) fast lowering of T N stops and a new magnetic state stable in a rather wide compositional range appears. Large difference between the zero-field-cooled (ZFC) and FC magnetization–temperature curves as well as between the temperatures of magnetic phase transition determined from Mossbauer and magnetization studies for compositions with x 0.1 implies that this state is a spin-glass phase.

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Держатели документа:
Southern Fed Univ, Fac Phys, Rostov Na Donu 344090, Russia
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
Univ Macau, Fac Sci & Technol, Taipa, Peoples R China
Natl Taiwan Univ Sci & Technol, Taipei 106, Taiwan

Доп.точки доступа:
Raevski, I. P.; Titov, V. V.; Malitskaya, M. A.; Eremin, E. V.; Еремин, Евгений Владимирович; Kubrin, S. P.; Blazhevich, A. V.; Chen, H.; Chou, C.-C.; Raevskaya, S. I.; Zakharchenko, I. N.; Sarychev, D. A.; Shevtsova, S. I.; Russian Foundation for Basic Research (RFBR) [12-08-00887_a]; Research Committee of the University of Macau
}
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X-ray, mossbauer, magnetic study of Na0.3Li0.7FeGe2O6 pyroxene / T. V. Drokina [et al.] // Магнитные материалы. Новые технологии : тез. докл. VI Байкал. междунар. конф. BICMM-2014. - Иркутск, 2014. - P. 163-164 . - ISBN 978-5-9624-1024-1

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Drokina, T. V.; Дрокина, Тамара Васильевна; Petrakovskii, G. A.; Петраковский, Герман Антонович; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Bayukov, O. A.; Баюков, Олег Артемьевич; Shadrina, A. L.; Шадрина, Александра Леонидовна; Rezina, E. G.; Байкальская Международная конференция "Магнитные материалы. Новые технологии"(6 ; 2014 ; авг. ; 19-23 ; пос. Большое Голоустное, Иркутская обл.); "Магнитные материалы. Новые технологии", Байкальская Международная конференция(6 ; 2014 ; авг. ; 19-23 ; пос. Большое Голоустное, Иркутская обл.); "Magnetic materials. New tecnologies", Baikal International Conference(6 ; 2014 ; Aug. 19-23 ; Bol’shoe Goloustnoe, Irkutsk region); Иркутский государственный университет
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Magnetic properties and the mechanism of formation of the uncompensated magnetic moment of antiferromagnetic ferrihydrite nanoparticles of a bacterial origin / D. A. Balaev [et al.] // J. Exp. Theor. Phys. - 2014. - Vol. 119, Is. 3. - P. 479-487, DOI 10.1134/S1063776114080044. - Cited References: 42. - This work was supported by the Ministry of Education and Science of the Russian Federation (state contract in 2014-2016) and a program of the Siberian Branch of the Russian Academy of Sciences. . - ISSN 1063-7761. - ISSN 1090-6509

РУБ Physics, Multidisciplinary
Рубрики:
NIO NANOPARTICLES
   EXCHANGE BIAS
   HYSTERESIS ANOMALIES
   FERRITIN
   SURFACE
   MOSSBAUER
   ORDER
   SIZE
Аннотация: The magnetic properties of the superparamagnetic ferrihydrite nanoparticles that form as a result of the vital activity of Klebsiella oxytoca bacteria are studied. Both an initial powder with an average number of iron atoms N Fe ∼ 2000–2500 in a particle and this powder after annealing at 140°C for 3 h in air are investigated. The following substantial modifications of the magnetic properties of the ferrihydrite nanoparticles are detected after annealing: the superparamagnetic blocking temperature increases from 23 to 49.5 K, and the average magnetic moment of a particle increases (as follows from the results of processing of magnetization curves). The particles have antiferromagnetic ordering, and the magnetic moment resulting in the superparamagnetism of the system appears due to random spin decompensation inside the particle. For this mechanism, the number of uncompensated spins is proportional to the number of magnetically active atoms raised to the one-half power, and this relation holds true for the samples under study at a good accuracy. The possible causes of the detected shift of magnetic hysteresis loops at low temperatures upon field cooling are discussed.

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Публикация на русском языке Магнитные свойства и механизм формирования нескомпенсированного магнитного момента антиферромагнитных наночастиц ферригидрита бактериального происхождения [Текст] / Д. А. Балаев [и др.] // Журн. эксперим. и теор. физ. : Наука, 2014. - Т. 146 Вып. 3. - С. 546–556

Держатели документа:
Russian Acad Sci, Siberian Branch, Kirenskii Inst Phys, Krasnoyarsk 660041, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Russian Acad Sci, Int Sci Ctr Extreme States Organisms, Siberian Branch, Krasnoyarsk Sci Ctr, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Balaev, D. A.; Балаев, Дмитрий Александрович; Krasikov, A. A.; Красиков, Александр Александрович; Dubrovskii, A. A.; Дубровский, Андрей Александрович; Semenov, S. V.; Семёнов, Сергей Васильевич; Bayukov, O. A.; Баюков, Олег Артемьевич; Stolyar, S. V.; Столяр, Сергей Викторович; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Ladygina, V. P.; Ладыгина, Валентина Петровна; Ishchenko, L. A.; Ищенко, Л. А.; Ministry of Education and Science of the Russian Federation; Siberian Branch of the Russian Academy of Sciences
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Morphology of the asymmetric iron-silicon interfaces / L. Badia-Romano [et al.] // J. Alloys Compd. - 2015. - Vol. 627. - P. 136-145, DOI 10.1016/j.jallcom.2014.12.019. - Cited References:69. - The financial support of the Spanish MINECO MAT2011-23791, the Presidentof Russia Grant (NSh-1044.2012.2), RFFI Grant 13-02-01265, the Ministryof Education and Science of Russian Federation (14.604.21.0002 and02G25.31.0043), Aragonese DGA-IMANA E34 (cofunded by Fondo SocialEuropeo) and that received from the European Union FEDER funds isacknowledged. L.B.R. acknowledges the Spanish MINECO FPU 2010 grant. . - ISSN 0925. - ISSN 1873-4669. -

РУБ Chemistry, Physical + Materials Science, Multidisciplinary + Metallurgy &
Рубрики:
RAY PHOTOELECTRON-SPECTROSCOPY
ELECTRON MOSSBAUER-SPECTROSCOPY
Кл.слова (ненормированные):
Fe/Si nanolayers -- Interfaces -- Fe silicides -- Compositional depth -- HAXPES -- CEMS
Аннотация: A systematic study of the iron–silicon interfaces formed upon preparation of (Fe/Si) multilayers has been performed by combination of modern and powerful techniques. Samples were prepared by thermal evaporation under ultrahigh vacuum onto a Si(1 0 0) substrate. The morphology of these films and their interfaces was studied by a combination of scanning transmission electron microscopy, X-ray reflectivity, angle resolved X-ray photoelectron spectroscopy and hard X-ray photoelectron spectroscopy. The Si-on-Fe interface thickness and roughness were determined to be 1.4(1) nm and 0.6(1) nm, respectively. Moreover, determination of the stable phases formed at both Fe-on-Si and Si-on-Fe interfaces was performed using conversion electron Mössbauer spectroscopy on multilayers with well separated Si-on-Fe and Fe-on-Si interfaces. It is shown that while a fraction of Fe remains as α-Fe, the rest has reacted with Si, forming the paramagnetic c-Fe1−xSi phase and a ferromagnetic Fe rich silicide (DO3 type phase). We conclude that the paramagnetic c-Fe1−xSi silicide sublayer is identical in both Si-on-Fe and Fe-on-Si interfaces, whereas an asymmetry is revealed in the composition of the ferromagnetic silicide sublayer.

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Держатели документа:
Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, E-50009 Zaragoza, Spain
Univ Zaragoza, Dept Fis Mat Condensada, E-50009 Zaragoza, Spain
Univ Zaragoza, Dept Ciencia Mat & Ingn Met, E-50018 Zaragoza, Spain
Univ Zaragoza, INA, LMA, E-50018 Zaragoza, Spain
Fdn ARAID, E-50004 Zaragoza, Spain
Russian Acad Sci, Kirensky Inst Phys, Siberian Div, Krasnoyarsk 660036, Russia
Siberian Aerosp Univ, Krasnoyarsk 660014, Russia
ESRF, SpLine Spanish CRG, F-38043 Grenoble, France
CSIC, Inst Ciencia Mat Madrid, Madrid, Spain

Доп.точки доступа:
Badía-Romano, L.; Rubin, J.; Bartolomé, F.; Magen, C.; Bartolome, J.; Varnakov, S. N.; Варнаков, Сергей Николаевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Rubio-Zuazo, J.; Castro, G.R.
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10.

Spin-glass behavior of warwickite MgFeBO4 and CoFeBO4 crystals observed by Mössbauer spectroscopy / I. S. Lyubutin [et al.] // J. Alloys Compd. - 2015. - Vol. 642. - P. 204-209, DOI 10.1016/j.jallcom.2015.04.067. - Cited References:29. - This study was supported by the Russian Foundation for Basic Research (Grants # 14-02-00483a, 14-02-31051-mol-a, 13-02-00958- a, and 13-02-00358-a), by the Council for Grants of the President of the Russian Federation (Project Nos. NSh-2886.2014.2 and SP-938.2015.5), by the Grant of KSAI, Krasnoyarsk regional fund of supporting scientific and technological activities and by the program of Foundation for Promotion of Small Enterprises in Science and Technology (''UMNIK'' program). The Spanish MINECO project MAT2011/23791, MAT2014/53921 and DGA E-34 are acknowledged. . - ISSN 0925. - ISSN 1873-4669. -

РУБ Chemistry, Physical + Materials Science, Multidisciplinary + Metallurgy & Metallurgical Engineering
Рубрики:
SOLVABLE MODEL
SPECTRA
Кл.слова (ненормированные):
Warwickites -- Spin-glass -- Mossbauer spectroscopy
Аннотация: Single crystals of MgFeBO4 and СоFeBO4 warwickites were obtained. The effects of charge ordering and magnetic properties were investigated by Mössbauer spectroscopy. Cation distribution over M1 and M2 nonequivalent sites and the average charge at the metal positions were established. Low temperature Mössbauer spectra reveal spin-glass behavior, with spin-freezing temperatures TSG of 15.2 and 33.2 K for Mg- and Co-warwickites, respectively, higher than that observed from the d.c. and a.c. magnetic susceptibility measurements. The difference is explained in terms of dynamical scaling theory. The specific shape of the Mössbauer spectra in the vicinity of the magnetic transition at TSG shows the difference between spin-glass and superparamagnetic behavior and demonstrates an overwhelming role of the exchange anisotropy in the properties of Mg-warwickite. In Co-warwickite the increase of magnetocrystalline anisotropy provokes an increase in magnetic viscosity.
Были получены монокристаллы MgFeBO4 и CoFeBO4 warwickites. Эффекты упорядочения зарядов и магнитные свойства были исследованы методом мессбауэровской спектроскопии. Было определено распределение катионов на М1 и M2 неэквивалентных позициях и средний заряд на металлических позициях. При низкой температуре Мессбауэровские спектры показывают поведение типа спинового стекла, с температурой замораживания спинов TSG 15.2 и 33.2 K для MG-и Co-warwickites, соответственно, более высокие, чем наблюдалось от постоянного тока и на ~ измерениях магнитной восприимчивости. Разница объясняется в терминах динамической теории подобия. Удельный форма спектров Мессбауэра в непосредственной близости от магнитного перехода на TSG показывает разницу между спин-стекольным и суперпарамагнитным поведением и демонстрирует подавляющее роль обменной анизотропии в свойствах Mg-warwickite. В Co-warwickite увеличение магнитокристаллической анизотропия провоцирует увеличение магнитной вязкости.

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Держатели документа:
RAS, AV Shubnikov Crystallog Inst, Moscow 119333, Russia
SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660074, Russia
Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
Univ Zaragoza, Serv Medidas Fis, E-50009 Zaragoza, Spain
Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, E-50009 Zaragoza, Spain
Dept Fis Mat Condensada, Zaragoza 50009, Spain

Доп.точки доступа:
Lyubutin, I. S.; Korotkov, N. Yu.; Frolov, K. V.; Kazak, N. V.; Казак, Наталья Валерьевна; Platunov, M. S.; Платунов, Михаил Сергеевич; Knyazev, Yu. V.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Arauzo, A.; Bartolome, J.
}
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11.

The effect of low-temperature heat treatment on the magnetic properties of biogenic ferrihydrite nanoparticles / D. A. Balaev [et al.] // Tech. Phys. Lett. - 2015. - Vol. 41, Is. 7. - P. 705-709, DOI 10.1134/S1063785015070172. - Cited References: 12. - This study was supported in part by the Ministry of Education and Science of the Russian Federation in the framework of a federal program for 2014-2016. . - ISSN 1063-7850

РУБ Physics, Applied
Рубрики:
BACTERIAL FERRIHYDRITE
MOSSBAUER
Аннотация: We have studied the influence of low-temperature heat treatment (annealing) on the magnetic properties of superparamagnetic nanoparticles of biogenic ferrihydrite. It is established that the proposed treatment leads to an increase in the blocking temperature and magnetic susceptibility of samples. After subsequent exposure in aqueous medium, the magnetic properties of annealed sol remain constant. The character of changes in the magnetic properties of samples studied shows that low-temperature heat treatment allows nanoparticle dimensions to be increased in a controlled way. © 2015, Pleiades Publishing, Ltd.

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Публикация на русском языке Влияние низкотемпературной термообработки на магнитные свойства наночастиц ферригидрита биогенного происхождения [Текст] / Д. А. Балаев [и др.] // Письма в Журн. техн. физ. : Санкт-Петербургская издательская фирма "Наука" РАН, 2015. - Т. 41 Вып. 14. - С. 88-96

Держатели документа:
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Balaev, D. A.; Балаев, Дмитрий Александрович; Krasikov, A. A.; Dubrovskii, A. A.; Дубровский, Андрей Александрович; Bayukov, O. A.; Баюков, Олег Артемьевич; Stolyar, S. V.; Столяр, Сергей Викторович; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Ladygina, V. P.; Ладыгина, Валентина Петровна; Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Ministry of Education and Science of the Russian Federation
}
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12.

Nature of the active sites of ferrospheres in the oxidative condensation of methane / A. G. Anshits [et al.] // Kinet. Catal. - 2015. - Vol. 56, Is. 4. - P. 523-531, DOI 10.1134/S0023158415040023. - Cited References:37. - This work was supported by the Russian Science Foundation (grant no. 14-13-00289). . - ISSN 0023. - ISSN 1608-3210. -

РУБ Chemistry, Physical
Рубрики:
GLASS CRYSTAL CATALYSTS
   HIGH-TEMPERATURE
   MOSSBAUER
   MAGNETITES
   MICROSPHERES
   SELECTIVITY
   CONVERSION
   FERRITES
   ASHES
   IRON
Кл.слова (ненормированные):
oxidative condensation of methane -- ferrospheres -- iron spinel -- Mossbauer spectroscopy -- structural defects
Аннотация: The catalytic properties of ferrospheres containing 76–97 wt % Fe2O3 in the oxidative condensation of methane were compared with their phase composition and the distribution of iron cations over the crystallographic positions of iron-containing phases in a steady state. It was established that the reaction route of methane oxidation changed at a Fe2O3 content of 89 wt %. Deep oxidation was the main reaction route on ferrospheres with a Fe2O3 content of <88.8 wt %. At a Fe2O3 content of ≥89 wt %, the yield of C2 hydrocarbons sharply increased and the contribution of deep oxidation decreased. The yield of C2 hydrocarbons correlated with the amount of defects in the structure of iron spinel, which are iron ions with the tetrahedral cation of Ca2+ and the octahedral cation vacancy among the nearest neighbors.

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Публикация на русском языке Природа активных центров ферросфер в процессе окислительной конденсации метана [Текст] / А. Г. Аншиц [и др.] // Кинетика и катализ : Наука, 2015. - Т. 56 № 4. - С. 529-538

Доп.точки доступа:
Anshits, A. G.; Аншиц, Александр Георгиевич; Bayukov, O. A.; Баюков, Олег Артемьевич; Anshits, N. N.; Pletnev, O. N.; Плетнев, Олег Николаевич; Rabchevskii, E. V.; Vereshchagin, S. N.; Kondratenko, E. V.; Russian Science Foundation [4-13-00289]; Russian Congress on Catalysis (2 ; 2014 ; Oct. ; 2–5 ; Samara)
}
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13.

    Structural and magnetic properties of Fe1−xCoxSe1.09 nanoparticles obtained by thermal decomposition / O. A. Li [et al.] // Mater. Res. Express. - 2015. - Vol. 2, No. 12. - Ст. 126501, DOI 10.1088/2053-1591/2/12/126501. - Cited References: 30. - This work is supported by the Ministry of Science and Technology of Taiwan (MOST103-2811-M-153 -001 and MOST102-2112-M-153 -002 -MY3). . - ISSN 2053-1591
   Перевод заглавия: Структурные и магнитные свойства наночастиц Fe1−xCoxSe1.09, полученных тепловым разложением

РУБ Materials Science, Multidisciplinary
Рубрики:
X-RAY-DIFFRACTION
   MOSSBAUER-SPECTROSCOPY
   CRYSTAL-STRUCTURES
   IRON SELENIDES
   SUPERCONDUCTIVITY
   FeSe
   MARCASITE
   PYRITE
Кл.слова (ненормированные):
nanoparticles -- chalcogenide -- iron-cobalt selenide -- ferrimagnetism -- paramagnetism -- Mossbauer spectroscopy
Аннотация: A series of Fe1−xCoxSe1.09 (x = 0 to ) nanoparticles were synthesized by thermal decomposition method. Particles in composition range Fe0.5Co0.5Se1.09 to CoSe1.09 crystallized in monoclinic structure of Co6.8Se8 , while FeSe1.09 crystallized in hexagonal structure of FeSe achavalite. Magnetization dependences on temperature and external magnetic field reveal complicated magnetic behavior and correspond to the sum of paramagnetic and superparamagnetic response. Mössbauer spectra contain several paramagnetic doublets with parameters corresponding to nonequivalent positions of divalent and trivalent iron cations with low spin. The nonequivalent positions appeared due to inhomogeneous distribution of Co ions or metal vacancies in iron surrounding.

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Доп.точки доступа:
Li, Oksana A.; Lin, Chun-Rong; Chen, Hung-Yi; Hsu, Hua-Shu; Wu, Kai-Wun; Tseng, Yaw-Teng; Bayukov, O. A.; Баюков, Олег Артемьевич; Edelman, I. S.; Эдельман, Ирина Самсоновна; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Shih, Kun-Yauh
}
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14.

Conditions for diamond and graphite formation from iron carbide at the P-T parameters of lithospheric mantle / Y. V. Bataleva [et al.] // Russ. Geol. Geophys. - 2016. - Vol. 57, Is. 1 : Tectonics, geodynamics, and petrology of earth’s lithosphere and mantle (to the 80th birthday of Academician Nikolai Leontievich Dobretsov). - P. 176-189, DOI 10.1016/j.rgg.2016.01.012. - Cited References:55. - This work was supported by the Russian Science Foundation under Grant No. 14-27-00054. . - ISSN 1068-7971. - ISSN 1878-030X

РУБ Geosciences, Multidisciplinary
Рубрики:
DEEP CARBON-CYCLE
   EARTHS MANTLE
   MINERAL INCLUSIONS
   HIGH-PRESSURE
   KOKCHETAV MASSI
   SUBDUCTION ZONES
   REDOX BUDGET
   FERRIC IRON
   MOSSBAUER
   METAL
Кл.слова (ненормированные):
iron carbide -- wusite -- graphite -- diamond -- oxides -- olivine -- subduction -- redox interaction -- lithospheric mantle -- high-pressure experiment
Аннотация: To estimate conditions for the stability of iron carbide under oxidation conditions and to assess the possibility of formation of elemental carbon by interaction between iron carbide and oxides, experimental modeling of redox interaction in the systems Fe3C-Fe2O3 and Fe3C-Fe2O3-MgO-SiO2 was carried out on a split-sphere high-pressure multianvil apparatus at 6.3 GPa and 900-1600 degrees C for 18-20 h. During carbide-oxide interaction in the system Fe3C-Fe2O3, graphite crystallizes in assemblage with Fe3+-containing wusite. Graphite forms from carbide carbon mainly by cohenite oxidation: Fe3C + 3Fe(2)O(3) -> 9FeO + C-0 and FeO + Fe3C -> (Fe2+, Fe3+)O + C-0. At above-solidus temperatures (>= 1400 degrees C), when metal-carbon melt is oxidized by wusite, graphite and diamond crystallize by the redox mechanism and form the Fe3+-containing wstite + graphite/diamond assemblage. Interaction in the system Fe3C-Fe2O3-MgO-SiO2 results in the formation of Fe3+-containing mannesiowusite-olivine-graphite assemblage. At >= 1500 degrees C, two melts with contrasting f(O2) values are generated: metal-carbon and silicate-oxide; their redox interaction leads to graphite crystallization and diamond growth. Under oxidation conditions, iron carbide is unstable in the presence of iron, silicon, and magnesium oxides, even at low temperatures. Iron carbide-oxide interaction at the mantle temperatures and pressures leads to the formation of elemental carbon; graphite is produced from carbide carbon mainly by redox reactions of cohenite (or metal-carbon melt) with Fe2O3 and FeO as well as by interaction between metal-carbon and silicate-oxide melts. The results obtained suggest that cohenite can be a potential source of carbon during graphite (diamond) formation in the lithospheric mantle and the interaction of iron carbide with iron, silicon, and magnesium oxides, during which carbon is extracted can be regarded as a process of the global carbon cycle. (C) 2016, V.S. Sobolev IGM, Siberian Branch of the RAS. Published by Elsevier B.V. All rights reserved.

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Публикация на русском языке Условия образования графита и алмаза из карбида железа при Р, Т-параметрах литосферной мантии [Текст] / Ю. В. Баталева [и др.] // Геол. и геофиз. - 2016. - Т. 57 № 1. - С. 225-240

Держатели документа:
Russian Acad Sci, Siberian Branch, VS Sobolev Inst Geol & Mineral, Pr Akad Koptyuga 3, Novosibirsk 630090, Russia.
Novosibirsk State Univ, Ul Pirogova 2, Novosibirsk 630090, Russia.
Russian Acad Sci, Siberian Branch, LV Kirensky Inst Phys, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Bataleva, Yu. V.; Palyanov, Yu. N.; Borzdov, Yu. M.; Bayukov, O. A.; Баюков, Олег Артемьевич; Sobolev, N. V.; Russian Science Foundation [14-27-00054]
}
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15.

Heat capacity and magnetic properties of fluoride CsFe2+Fe3+F6 with defect pyrochlore structure / M. V. Gorev [et al.] // J. Solid State Chem. - 2016. - Vol. 237. - P. 330-335, DOI 10.1016/j.jssc.2016.02.045. - Cited References: 19. - This study was partially supported by the Grant NSh-924.2014.2 of the President of the Russian Federation for the Support of Leading Scientific Schools. . - ISSN 0022-4596

РУБ Chemistry, Inorganic & Nuclear + Chemistry, Physical
Рубрики:
Crystal-structure
   Mossbauer
   CsFe2F6
   Spectra
Кл.слова (ненормированные):
Pyrochlore structure -- Phase transition -- Magnetic properties -- Thermal properties
Аннотация: Heat capacity, Mossbauer and Raman spectra as well as magnetic properties of fluoride CsFe2F6 with defect pyrochlore structure were studied. In addition to recently found above room temperature three successive structural transformations Pnma-Imma-I41amd-Fd-3m, phase transition of antiferromagnetic nature with the 13.7 K Neel temperature and a broad heat capacity anomaly with a maximum at about 30 K were observed. The room temperature symmetry Pnma is unchanged at least down to 7 K. Simple model of indirect bond used to estimate the exchange interactions and to propose a magnetic structure model. © 2016 Elsevier Inc. All rights reserved.

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Держатели документа:
Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk, Russian Federation
Institute of Engineering Physics and Radio Electronics, Siberian State University, Krasnoyarsk, Russian Federation
Institut de Chimie de la Matiere Condensee, ICMCB, CNRS, Universite Bordeaux, Pessac Cedex, France
Astafijev Krasnoyarsk State Pedagogical University, Krasnoyarsk, Russian Federation
Krasnoyarsk State Agrarian University, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Flerov, I. N.; Флёров, Игорь Николаевич; Tressaud, A.; Bogdanov, E. V.; Богданов, Евгений Витальевич; Kartashev, A. V.; Карташев, Андрей Васильевич; Bayukov, O. A.; Баюков, Олег Артемьевич; Eremin, E. V.; Еремин, Евгений Владимирович; Krylov, A. S.; Крылов, Александр Сергеевич
}
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16.

Magnetic properties of heat treated bacterial ferrihydrite nanoparticles / D. A. Balaev [et al.] // J. Magn. Magn. Mater. - 2016. - Vol. 410. - P. 171-180, DOI 10.1016/j.jmmm.2016.02.059. - Cited References: 66. - TEM studies were performed on facility of Resource Sharing Center of Krasnoyarsk Scientific Center of Siberian Branch of Russian Academy of Sciences. Authors acknowledge to M.N. Volochaev for the TEM measurements. . - ISSN 0304-8853

РУБ Materials Science, Multidisciplinary + Physics, Condensed Matter
Рубрики:
Hematite nanoparticles
   NiO nanoparticles
   Porous-glass
   Ferritin
   Particles
   Temperature
   Hysteresis
   Transition
   Anomalies
   Mossbauer
Кл.слова (ненормированные):
Ferrihydrite -- Nanoparticles -- Superparamagnetism
Аннотация: The magnetic properties of ferrihydrite nanoparticles, which are products of vital functions of Klebsiella oxitoca bacteria, have been studied. The initial powder containing the nanoparticles in an organic shell was subjected to low-temperature (T=160 °C) heat treatment for up to 240 h. The bacterial ferrihydrite particles exhibit a superparamagnetic behavior. Their characteristic blocking temperature increases from 26 to 80 K with the heat treatment. Analysis of the magnetization curves with regard to the magnetic moment distribution function and antiferromagnetic contribution shows that the low-temperature heat treatment enhances the average magnetic moment of a particle; i.e., the nanoparticles coarsen, probably due to their partial agglomeration during heat treatment. It was established that the blocking temperature nonlinearly depends on the particle volume. Therefore, a model was proposed that takes into account both the bulk and surface magnetic anisotropy. Using this model, the bulk and surface magnetic anisotropy constants KV≈1.7×105 erg/cm3 and KS≈0.055 erg/cm2 have been determined. The effect of the surface magnetic anisotropy of ferrihydrite nanoparticles on the observed magnetic hysteresis loops is discussed.

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Держатели документа:
Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
Presidium of Krasnoyarsk Scientific Center, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk, Russian Federation
International Laboratory of High Magnetic Fields and Low Temperatures, Gajowicka 95, Wroclaw, Poland

Доп.точки доступа:
Balaev, D. A.; Балаев, Дмитрий Александрович; Krasikov, A. A.; Красиков, Александр Александрович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Popkov, S. I.; Попков, Сергей Иванович; Stolyar, S. V.; Столяр, Сергей Викторович; Bayukov, O. A.; Баюков, Олег Артемьевич; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Ladygina, V. P.; Yaroslavtsev, R. N.
}
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17.

    Low-temperature structural and magnetic phase transitions in multiferroic GdFe3(BO3)4 / K. V. Frolov [et al.] // J. Alloys Compd. - 2016. - Vol. 671. - P. 545-551, DOI 10.1016/j.jallcom.2016.02.083. - Cited References:36. - We thank Dr. A.P. Dudka for help in the low temperature XRD measurements. This study was supported in part by the Russian Foundation for Basic Research (projects # 14-02-00483a and 13-02-12442), and the Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools (grant # NSh-1130.2014.5 and # NSh-924.2014.2). This work was performed using the equipment of the Shared Research Center IC RAS and was supported by the Russian Ministry of Education and Science (project RFMEFI62114X0005). . - ISSN 0925-8388. - ISSN 1873-4669
   Перевод заглавия: Низкотемпературные структурные и магнитные фазовые переходы в мультиферроике GdFe3(BO3)4

РУБ Chemistry, Physical + Materials Science, Multidisciplinary + Metallurgy & Metallurgical Engineering
Рубрики:
IRON BORATE GDFE3(BO3)4
   BIFEO3 THIN-FILMS
   MAGNETOELASTIC PROPERTIES
   RM3(BO3)4 CRYSTALS
   TRIGONAL GDFE3(BO3)4
   ENHANCED POLARIZATION
   HIGH-PRESSURES
   CRYSTALLIZATION
   BEHAVIOR
   GROWTH
Кл.слова (ненормированные):
Multiferroics -- Rare earth compounds -- X-ray diffraction -- Mossbauer -- spectroscopy -- Crystal structure -- Spin dynamics
Аннотация: X-ray analysis revealed that at temperature decreasing from room temperature to Tstr = 155 K the crystal unit cell GdFe3(BO3)4 is reduced only along the c axis (at 0.01 Å), while the a and b axes are unchanged within the error limits. The volume of the crystal decreases uniformly in the direction of all three axes at 155–80 K. At 80–30 K the crystal volume is decreased only by reduction of the parameters a and b, while the parameter c increases conversely. In the paramagnetic region Mössbauer spectra do not distinguish between the two structural positions of iron ions Fe1 and Fe2, appearing at T < Tstr. Below the temperature of the magnetic phase transition at TN = 38.0(1) K the Mössbauer data indicate quasi-one-dimensional magnetic ordering of iron moments in the sublattice Fe2 and a two-dimensional one in the iron sublattice Fe1. The dynamics of spin reorientation in sublattices Fe1 and Fe2 is studied in detail.
Рентгеновский анализ показал, что при уменьшении температуры от комнатной до Tstr = 155 K изменение параметра элементарной ячейки кристалла GdFe3(BO3)4 происходит лишь вдоль оси с (при 0,01 Å), в то время как а и b оси остаются неизменными в пределах погрешности измерений. Объем кристалла уменьшается равномерно в направлении всех трех осей при 155-80 K. При 80-30 K объем кристалла уменьшается только уменьшением параметров a и b, в то время как параметр с наоборот увеличивается. В парамагнитной области Мессбауэровские спектры не различают двух структурных позиций ионов железа Fe1 и Fe2, появляющиеся при Т˂Tstr. Ниже температуры магнитного фазового перехода при TN = 38,0(1) К Мёссбауэрские данные указывают на квази-одномерный магнитное упорядочение моментов железа в подрешетке Fe2 и двумерное в железной подрешетке Fe1. Динамика спиновой переориентации в подрешетках Fe1 и Fe2 подробно изучается.

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Держатели документа:
Russian Acad Sci, AV Shubnikov Crystallog Inst, Moscow 119333, Russia.
Carnegie Inst Sci, Geophys Lab, Washington, DC 20015 USA.
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Frolov, K. V.; Lyubutin, I. S.; Smirnova, E. S.; Alekseeva, O. A.; Verin, I. A.; Artemov, V. V.; Kharlamova, S. A.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Gudim, I. A.; Гудим, Ирина Анатольевна; Russian Foundation for Basic Research [14-02-00483a, 13-02-12442]; Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools [NSh-1130.2014.5, NSh-924.2014.2]; Russian Ministry of Education and Science [RFMEFI62114X0005]
}
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18.

Uniaxial magnetic anisotropy in Co2.25Fe0.75O2BO3 compared to Co3O2BO3 and Fe3O2BO ludwigites / J. . Bartolome [et al.] // Phys. Rev. B. - 2011. - Vol. 83, Is. 14. - Ст. 144426, DOI 10.1103/PhysRevB.83.144426. - Cited References: 25. - The authors acknowledge V. V. Rudenko for the oxyborate samples they made and O. A. Bayukov for fruitful discussion. The financial support of Spanish MINCYT, Grant No. MAT08/1077, and the Aragonese E-34 project are acknowledged. Fruitful discussions with F. Bartolome and P. Bordet are acknowledged. The latter is thanked for providing the FeINF3/INFOINF2/INFBOINF3/INF single crystal. Also this study was supported by the Russian Foundation for Basic Research (Project No. 09-02-00171-a), the Federal Agency for Science and Innovation (Rosnauka) (Project No. MK-5632.2010.2), and the Physical Division of the Russian Academy of Science (Program "Strongly Correlated Electrons," Project No. 2.3.1). . - ISSN 1098-0121

РУБ Physics, Condensed Matter
Рубрики:
CRYSTAL-STRUCTURE
MOSSBAUER
CO3BO5
Аннотация: Magnetic and Mossbauer spectroscopy (MS) measurements have been performed on a single crystal of Co2.25Fe0.75O2BO3 with ludwigite structure. Two magnetic transitions (T-N = 115 K and T-C = 70 K) were traced from the ac susceptibility temperature dependence. The MS spectra as a function of temperature clearly show the onset of magnetic ordering below 115 K. Magnetization measurements on the parent Co3O2BO3 and Fe3O2BO3 compounds have been done for comparison. In Fe3O2BO3 the anisotropy of the different phases has been determined, showing that the anisotropy axis changes from the a to the b axis in the low-temperature antiferromagnetic phase. High magnetic uniaxial anisotropy has been detected for both Co3O2BO3 and Co2.25Fe0.75O2BO3. From the angle-dependent magnetization measurements it is found that in both compounds the easy axis of magnetization is the b [010] axis, where an antiferromagnetic component is superimposed on the main ferromagnetic component. In the c direction the behavior is purely antiferromagnetic. In Co2.25Fe0.75O2BO3 a strong reduction of the remanent magnetization and a very strong increase in coercive field along the b axis with respect to those found in Co3O2BO3 were observed from magnetic hysteresis cycles measured below T-C. The increase of coercive field is caused by the increase of defects upon Co substitution by Fe.

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Держатели документа:
[Bartolome, J.] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, E-50009 Zaragoza, Spain
[Bartolome, J.] Univ Zaragoza, CSIC, Dept Fis Mat Condensada, E-50009 Zaragoza, Spain
[Arauzo, A.] Univ Zaragoza, Serv Instrumentac Cientif, Area Medidas Fis, E-50009 Zaragoza, Spain
[Kazak, N. V.
Ovchinnikov, S. G.] RAS, SB, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Ivanova, N. B.
Knyazev, Yu. V.] Siberian Fed Univ, Krasnoyarsk 660074, Russia
[Ivanova, N. B.] Krasnoyarsk State Agrarian Univ, Krasnoyarsk, Russia
[Ovchinnikov, S. G.] Siberian State Aerosp Univ, Krasnoyarsk, Russia
[Lyubutin, I. S.] RAS, AV Shubnikov Crystallog Inst, Moscow 119333, Russia
ИФ СО РАН
Instituto de Ciencia de Materiales de Aragon, Departamento de Fisica de la Materia Condensada, CSIC-Universidad de Zaragoza, 50009 Zaragoza, Spain
Servicio de Instrumentacion Cientifica, Area de Medidas Fisicas, Universidad de Zaragoza, Pedro Cerbuna 12, 50009 Zaragoza, Spain
L.V. Kirensky Institute of Physics, SB of RAS, 660036, Akademgorodok, Krasnoyarsk, Russian Federation
Siberian Federal University, Kirensky street 26, 660074, Krasnoyarsk, Russian Federation
Krasnoyarsk State Agrarian University, Mira street 90, Krasnoyarsk, Russian Federation
Siberian State Aerospace University, Krasnoyarskiy Rabochiy street 31, Krasnoyarsk, Russian Federation
Shubnikov Institute of Crystallography, RAS, Leninskiy prospect 59, 119333, Moscow, Russian Federation

Доп.точки доступа:
Bartolome, J.; Arauzo, A.; Kazak, N. V.; Казак, Наталья Валерьевна; Ivanova, N. B.; Иванова, Наталья Борисовна; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Knyazev, Yu. V.; Князев, Юрий Владимирович; Lyubutin, I. S.
}
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19.

Short-range correlations and their thermal hysteresis in the paramagnetic phase of YFe3(BO3)(4) / L. . Rebbouh [et al.] // Phys. Rev. B. - 2011. - Vol. 83, Is. 14. - Ст. 140406, DOI 10.1103/PhysRevB.83.140406. - Cited References: 21. - This work was supported by grants from the Natural Sciences and Engineering Research Council of Canada and the Canada Foundation for Innovation. J.M.C. acknowledges support from the Canada Research Chairs program. . - ISSN 1098-0121

РУБ Physics, Condensed Matter
Рубрики:
MOSSBAUER-SPECTRA
GDFE3(BO3)(4)
RELAXATION
Аннотация: Neutron diffraction and Mossbauer spectroscopy have been used to examine the connections between long-and short-range magnetic order in the rare-earth iron ferroborate YFe3(BO3)(4). We establish the presence of short-range magnetic order in the pseudo-one-dimensional Fe-spin chains of the FeO6 octahedra while the ferroborates are in their (long-range) paramagnetic phase. The short-range order exists at temperatures several times the Neel temperature. In addition, we observe thermal hysteresis of the short-range ordered Fe spins. The observed Fe-spin dynamics are suggestive of the presence of solitons within the domains that form in the Fe-spin chains.

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Держатели документа:
[Rebbouh, L.
Desautels, R. D.
Cadogan, J. M.
van Lierop, J.] Univ Manitoba, Dept Phys & Astron, Winnipeg, MB R3T 2N2, Canada
[Ritter, C.] Inst Laue Langevin, F-38042 Grenoble, France
[Temerov, V.
Pankrats, A.] RAS, LV Kirenskii Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
Department of Physics and Astronomy, University of Manitoba, Winnipeg, MB R3T 2N2, Canada
Institut Laue-Langevin, Boite Postale 156, F-38042 Grenoble, France
L. V. Kirenskii Institute of Physics, Siberian Branch of RAS, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Rebbouh, L.; Desautels, R. D.; Ritter, C.; Cadogan, J. M.; Temerov, V.; Pankrats, A. I.; Панкрац, Анатолий Иванович; van Lierop, J.
}
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20.

Mossbauer Investigation of Temperature Transformations in Bacterial Ferrihydrite / S. V. Stolyar [et al.] // Phys. Solid State. - 2011. - Vol. 53, Is. 1. - P. 100-104, DOI 10.1134/S1063783411010306. - Cited References: 10. - This study was supported by the Federal Agency for Science and Innovation of the Russian Federation within the framework of the Russian Federal Target Program "Scientific and Scientific-Pedagogical Personnel of the Innovative Russia" for 2009-2013 and the Russian Foundation for Basic Research (project no. 09-04-98038-r_sibir'_a). . - ISSN 1063-7834

РУБ Physics, Condensed Matter

Аннотация: Ferrihydrite nanoparticles formed as a result of the microorganism activity have been studied using Mossbauer spectroscopy, X-ray powder diffraction analysis, and X-ray fluorescence analysis. Three positions of trivalent iron with nonoverlapping ranges of quadrupole splittings have been revealed in bacterial ferrihydrite: QS{Fe(3+)(1)} = 0.49-0.83 mm/s, QS{Fe(3+)(2)} = 0.84-1.10 mm/s, and QS{Fe(3+)(3)} = 1.25-1.73 mm/s. It has been experimentally demonstrated that the Fe(3+)(3) positions are the centers of nucleation of the hematite phase in the course of heat treatment.

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Держатели документа:
[Stolyar, S. V.
Bayukov, O. A.
Iskhakov, R. S.
Ishchenko, L. A.
Yakovchuk, V. Yu.
Piksina, O. E.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
[Stolyar, S. V.
Bayukov, O. A.
Iskhakov, R. S.
Ishchenko, L. A.
Yakovchuk, V. Yu.
Pozdnyakov, A. I.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Ladygina, V. P.] Russian Acad Sci, Siberian Branch, Presidium Krasnoyarsk Sci Ctr, Int Res Ctr Extreme States Organism, Krasnoyarsk 660036, Russia
[Dobretsov, K. G.] Joint Stock Co Russian Railways RZhD, Railway Clin Hosp Krasnoyarsk Stn, Krasnoyarsk 660021, Russia
ИФ СО РАН
КНЦ СО РАН
Siberian Federal University, Svobodnyi pr. 79, Krasnoyarsk 660041, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk 660036, Russian Federation
International Research Center for Extreme States of the Organism, Presidium of Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk 660036, Russian Federation
Railway Clinical Hospital at the Krasnoyarsk station, Joint Stock Company Russian Railways (RZhD), pr. Mira 154, Krasnoyarsk 660021, Russian Federation

Доп.точки доступа:
Stolyar, S. V.; Столяр, Сергей Викторович; Bayukov, O. A.; Баюков, Олег Артемьевич; Ladygina, V. P.; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Ishchenko, L. A.; Yakovchuk, V. Y.; Dobretsov, K. G.; Pozdnyakov, A. I.; Piksina, O. E.
}
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