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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Кашникова М. Е., Уткин Н. А., Смольников Н. А., Пискунов Ю. В., Садыков А. Ф., Казак, Наталья Валерьевна
Заглавие : 11B ЯМР-исследование кобальтового людвигита Co3BO5
Коллективы : "Новое в магнетизме и магнитных материалах", международная конференция, Научный совет по физике конденсированных сред РАН, МИРЭА - Российский технологический университет, Московский государственный университет им. М.В. Ломоносова, Магнитное общество России
Место публикации : Новое в магнетизме и магнитных материалах: сборник трудов XXV международной конференции/ прогр. ком.: Р. С. Исхаков, С. Г. Овчинников [и др.]. - 2024. - Секция 6 [Сборник 6]: Резонансные явления в магнетиках. - С. 25-28. - ISBN 978-5-4465-1869-2
Примечания : Библиогр.: 6. - Выполнено в рамках госзадания Минобрнауки № 122021000035-6
Аннотация: Впервые методами ядерного магнитного резонанса (ЯМР) выполнено исследование порошков оксибората кобальта Co3BO5 в широкой области температур (85 – 295 K) во внешнем магнитном поле H0 = 9.27 Тл. Определены параметры тензора градиента электрического поля (ГЭП) и магнитного сдвига линии ЯМР на позициях ядра-зонда 11B. Выделены орбитальный 11K0 и спиновый 11Ks вклады в сдвиг. Из температурных зависимостей сдвига и магнитной восприимчивости в Co3BO5 была определена константа сверхтонкого взаимодействия (СТВ) иона B3+ с ближайшим магнитным окружением.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Govorun I. V., Belyaev B. A., Zav'yalov Ya. B., Shumilov T. Y., Afonin A. O., Ugryumov A. V., Galeev R. G.
Заглавие : A 10 GHz monolithic filter based on stripline resonators with a split conductor
Колич.характеристики :6 с
Место публикации : Dokl. Phys. - 2023. - Vol. 68, Is. 12. - P.434-439. - ISSN 10283358 (ISSN), DOI 10.1134/S1028335823120030. - ISSN 15626903 (eISSN)
Примечания : Cited References: 18. - This work was carried out within the framework of Agreement no. 470 of August 30, 2022, between the Institute of Physics, Siberian Branch, Russian Academy of Sciences; the Regional Science Foundation; and JSC NPP Radiosvyaz, for a competition of scientific, technical, and innovative projects in the interests of the first climate Scientific and Educational Center "Yenisei Siberia"
Аннотация: The monolithic design of a compact bandpass filter X-band is made on the technology of multilayered printed circuit boards. Quarter-wave stripline resonators of the filter have two conductors divided by a layer of prepreg having low parameters that bond together the design. This eliminates the influence of the prepreg on the characteristics of the devices, ensuring good repeatability of filters in mass production. To increase the high-frequency stopband of the filter, one of the conductors of each resonator is cut in half by a transverse slit. The constructive sizes of the device were obtained by parametric synthesis using the electrodynamic analysis of its 3D model. The experimental data of the five-order filter are in good agreement with the electromagnetic simulation of filter of the 3D model. The experimental device has a central frequency of the passband of 10 GHz and a fractional bandwidth of 5.7%, and its dimensions and weight are 18.0 × 5.4 × 2.1 mm3 and 0.5 g. The important advantage of the developed design is the possibility of its installation on the board using the surface mounting method.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shauro V. P., Pekhterev D. I., Zobov V. E.
Заглавие : A Comparative Analysis of two Methods of Realizing Elementary Logic Operators for a Quantum Computer on Qutrits
Место публикации : Russian Physics Journal. - 2007. - Т. 50, № 6. - С. 566-573
Аннотация: In the present work, elementary logic operators (including selective rotation, Fourier transform, controlled phase shift, and controlled NOT operators) for a quantum computer on tristable systems (qutrits) are examined. Computer modeling of realization of these operators based on a system of two nuclear spins I = 1 is carried out by the methods of nuclear magnetic resonance. Two different methods of realizing the controlled NOT operator are presented: with the help of weak pulses of radio-frequency magnetic field selective in spin-spin interaction and with the help of strong pulses selective in quadrupole interaction. A dependence of realization errors on the interaction parameters, variable field amplitude, and pulse duration is calculated. Advantages and disadvantages of each method in the process of realization are indicated
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Fedorov A. S., Eremkin E. V., Krasnov P. O., Gerasimov V. S., Agren H., Polyutov S. P.
Заглавие : A hybrid quantum–classical theory for predicting terahertz charge-transfer plasmons in metal nanoparticles on graphene
Колич.характеристики :13 с
Место публикации : J. Chem. Phys. - 2024. - Vol. 160, Is. 4. - Ст.044117. - ISSN 00219606 (ISSN), DOI 10.1063/5.0178247. - ISSN 10897690 (eISSN)
Примечания : Cited References: 61. - This study was funded by the Ministry of Science and High Education of Russian Federation, Project No. FSRZ-2023-0006. The calculations of CTPs in specific NP–graphene complexes were performed within the RSF Grant No. 23-12-20007 and the Krasnoyarsk Territorial Foundation for Support of Scientific and R & D Activities, Agreement No. 256. H. Ågren was supported by the Swedish Science Research Council on Contract No. 2022-03405
Аннотация: Metal nanoparticle (NP) complexes lying on a single-layer graphene surface are studied with a developed original hybrid quantum–classical theory using the Finite Element Method (FEM) that is computationally cheap. Our theory is based on the motivated assumption that the carrier charge density in the doped graphene does not vary significantly during the plasmon oscillations. Charge transfer plasmon (CTP) frequencies, eigenvectors, quality factors, energy loss in the NPs and in graphene, and the absorption power are aspects that are theoretically studied and numerically calculated. It is shown the CTP frequencies reside in the terahertz range and can be represented as a product of two factors: the Fermi level of graphene and the geometry of the NP complex. The energy losses in the NPs are predicted to be inversely dependent on the radius R of the nanoparticle, while the loss in graphene is proportional to R and the interparticle distance. The CTP quality factors are predicted to be in the range ~ 10 – 100. The absorption power under CTP excitation is proportional to the scalar product of the CTP dipole moment and the external electromagnetic field. The developed theory makes it possible to simulate different properties of CTPs 3–4 orders of magnitude faster compared to the original FEM or the finite-difference time domain method, providing possibilities for predicting the plasmonic properties of very large systems for different applications.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mironov V. L., Savin I. V.
Заглавие : A Method for Calibrating a Strip Resonator Used in Measurements of the Complex Permittivity of Moist Soils and Grounds
Место публикации : Instruments and Experimental Techniques. - 2006. - Vol. 49, № 1. - С. 120-125. - ISSN 0032-8162, DOI 10.1134/S0020441206010179
Аннотация: A method for calibrating a microstrip microwave resonator used to measure the complex permittivity of moist soils and grounds is proposed. This method is based on the use of mixtures of a disperse solid substance and aqueous solutions of salts with known values of their complex permittivity. The resonator is composed of two segments of strip lines, the capacitive electromagnetic coupling between which occurs through a container with a moist soil sample. Sandy soil samples wetted by a sodium chloride solution were used as reference samples. The values of their complex permittivity were determined using the generalized refraction model and the reference data for the complex permittivity of a salt solution. A system of algebraic equations was set up, the solution to which, together with the formulas of the refraction model, allowed the complex permittivity of the test soil sample to be reconstructed from the measured values of the resonance frequency shifts and Q factor. The rms errors in measuring the real and imaginary parts of the complex permittivity, which varied over the ranges 4.79-11.03 and 0.39-3.15, were 0.21 and 0.03, respectively. © Pleiades Publishing, Inc. 2006.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Martyanov O., Yudanov V., Lee R., Volkov N. V., Sablina K. A.
Заглавие : A tool to investigate the spatial magnetic phase separation phenomena in manganites
Место публикации : Phys. Stat. Sol (RRL). - 2007. - Vol. 1, Is.1. - P.R22-R24. - DOI 10.1016/j.jmmm.2006.07.033
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Romanova T. A., Krasnov P. O.
Заглавие : Ab initio and post-ab initio quantum chemical study of the heme spin states in electron transfer reactions
Место публикации : Chemical Physics Letters: Elsevier Science Publishing Company, Inc., 2006. - Т. 420, № 4-6. - С. 281-285. - ISSN 0009-2614, DOI 10.1016/j.cplett.2005.12.067. - ISSN 1873-4448(eissn)
Примечания : Russian Federation State Program "Integration"
Аннотация: Quantum-chemical calculations of neutral and charged ironporphyrin (FeP, FeP+1 and FeP-) systems were performed using B3LYP and MP2 methods. It was shown that all ground states of FeP (S = 1), FeP +1 (S = 3/2) and FeP- (S = 1/2) systems have C 2v symmetry. During the first step of electron transfer process an electron goes to β-LUMO - 1 Fe dyz-orbital of FeP+1. The second electron goes to β-LUMO of FeP which is attributed to π-system of porphyrin ring. The 3s- and 3p-orbitals do not play a significant role in the electron transfer process. The ability of FeP -1 system to form π-dative chemical bond is low. The formation of π-π-complexes is preferable. © 2005 Elsevier B.V. All rights reserved
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Begunovich L. V., Kovaleva E. A., Korshunov M. M., Shabanov V. F.
Заглавие : Absorption spectra of the purple nonsulfur bacteria light-harvesting complex: A DFT study of the B800 part
Колич.характеристики :7 с
Место публикации : J. Photochem. Photobiol. A: Chem. - 2024. - Vol. 450. - Ст.115454. - ISSN 10106030 (ISSN), DOI 10.1016/j.jphotochem.2023.115454. - ISSN 18732666 (eISSN)
Примечания : Cited References: 42. - This work was supported by the state assignment of the Ministry of Science and Higher Education of the Russian Federation. Authors would like to thank Information Technology Centre, Novosibirsk State University for providing access to their supercomputers. L.V.B. would like to thank Irkutsk Supercomputer Center of SB RAS for providing the access to HPC-cluster «Akademik V.M. Matrosov» (Irkutsk Supercomputer Center of SB RAS, Irkutsk: ISDCT SB RAS; http://hpc.icc.ru, accessed 20.10.2023)
Аннотация: We’ve studied the B800 part of Rhodoblastus acidophilus light-harvesting complex (LH2) by several quantum chemical techniques based on the density functional theory (DFT) and determined the specific method and a minimal reliable model suitable for further studies of the LH2. In addition to bacteriochlorophyll a molecules, the minimal model includes two α and one β chain amino acids. Within the model, we are able to reproduce the contribution of the B800 ring of nine bacteriochlorophyll a molecules to the near infrared Qy absorption band. We also discuss the use of hybrid DFT calculations for precise energy and optical estimations and DFT-based tight binding (DFTB) method for the large-scale calculations. Crucial importance of Hartree-Fock exchange interaction for the correct description of B800 peak position was shown.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Liu Sh., Li L., Qin X., Du R., Sun Y., Xie Sh., Wang J., Molokeev M. S., Xi Sh., Bunzli J.-C. G., Zhou L., Wu M.
Заглавие : Achieving ultra-broadband sunlight-like emission in single-phase phosphors: The interplay of structure and luminescence
Колич.характеристики :9 с
Место публикации : Adv. Mater. - 2024. - Vol. 36, Is. 38. - Ст.2406164. - ISSN 09359648 (ISSN), DOI 10.1002/adma.202406164. - ISSN 15214095 (eISSN)
Примечания : Cited References: 43. - S.L. and L.L. contributed equally to this work. This work was ﬁnancially supported by grants from the National Natural Science Foundationof China (NSFC, No. 52272174) and its joint project with Guangdong(Nos. U22A20135, U1801253 and U1301242) Province. J. Wang acknowl-edges Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai) projects SML2021SP204, SML2023SP215/218/238. The authorsare grateful to Prof. Peter A. Tanner and Prof. Ka-Leung Wong for the indepth communication and valuable advice on the improvement of the manuscriptOpen access funding provided by Ecole Polytechnique Federale de Lausanne
Аннотация: The quest for artificial light sources mimicking sunlight has been a long-standing endeavor, particularly for applications in anticounterfeiting, agriculture, and color hue detection. Conventional sunlight simulators are often cost-prohibitive and bulky. Therefore, the development of a series of single-phase phosphors Ca9LiMg1-xAl2x/3(PO4)7:0.1Eu2+ (x = 0-0.75) with sunlight-like emission represents a welcome step towards compact and economical light source alternatives. The phosphors are obtained by an original heterovalent substitution method and emit a broad spectrum spanning from violet to deep red. Notably, the phosphor with x = 0.5 exhibits an impressive full width at half-maximum of 330 nm. A synergistic interplay of experimental investigations and theory unveils the mechanism behind sunlight-like emission due to the local structural perturbations introduced by the heterovalent substitution of Al3+ for Mg2+, leading to a varied distribution of Eu2+ within the lattice. Subsequent characterization of a series of organic dyes combining absorption spectroscopy with convolutional neural network analysis convincingly demonstrates the potential of this phosphor in portable photodetection devices. Broad-spectrum light source testing empowers the model to precisely differentiate dye patterns. This points to the phosphor being ideal for mimicking sunlight. Beyond this demonstrated application, the phosphor's utility is envisioned in other relevant domains, including visible light communication and smart agriculture.
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10.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Ivanova O. S., Edel'man I. S., Sventitsky E. S., Serdyuk A. A., Toropova E. S.
Заглавие : Adsorption and Catalytic Properties of Nanoparticles Fe3O4-Ag in Relation to Various Types of Organic Dyes
Коллективы : "Mechanisms of catalytic reactions", International conference, "Механизмы каталитических реакций", международная конференция, Институт катализа им. Г.К. Борескова Сибирского отделения РАН, Институт органической химии им. Н.Д. Зелинского РАН, Московский государственный университет им. М.В. Ломоносова, Сибирское отделение РАН, Центр компетенций НТИ "Водород как основа низкоуглеродной экономики"
Место публикации : XII lnternational conference "Mechanisms of catalvtic reactions": abstracts. - Novosibirsk, 2024. - Ст.PP-09. - P.174-175. - ISBN 978-5-906376-56-5
Примечания : Библиогр.: 2. - РНФ и Красноярский краевой фонд науки, проект 23-22-10025
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanova O. S., Lin, Chun-Rong, Edelman I. S., Svetlitsky E. S., Sokolov A. Е., Zharkov S. M., Sukhachev A. L., Vorobyev S. A., Petrov D. A., Lin, En-Szu
Заглавие : Adsorption properties and catalytic activity of Fe3O4-Ag nanostructures
Колич.характеристики :12 с
Место публикации : Appl. Surf. Sci. - 2024. - Vol. 665. - Ст.160236. - ISSN 01694332 (ISSN), DOI 10.1016/j.apsusc.2024.160236. - ISSN 18735584 (eISSN)
Примечания : Cited References: 48. - The work is supported by the Russian Science Foundation (project no. 23-22-10025, https://rscf.ru/project/ 23-22-10025/) and by the Krasnoyarsk Regional Fund of Science and Technology Support. The electron microscopy and EDS investigations were conducted in the SFU Joint Scientific Center. Magnetic investigations were carried out in the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center "Krasnoyarsk Science Center SB RAS"
Аннотация: The morphology and magnetic properties as well as adsorption capacity and catalytic activity of Fe3O4-Ag nanoparticles synthesized by the solvothermal method were studied in dependence on the duration of the thermolysis process (3, 6, and 8 h). X-ray diffraction, transmission electron microscopy, and energy-dispersive spectroscopy measurements showed that the morphology of nanoparticles changed strongly as the duration of thermolysis increased. At 6 and 8 h duration, Fe3O4 nanocrystals grow and assemble into porous spherical globules with an Ag core (samples 2 and 3). These samples demonstrate high magnetization value and very low coercivity. The adsorption capacity of nanoparticles was studied with respect to two organic dyes: cationic methylene blue (MB) and anionic Congo red (CR). The particles showed preferential adsorption of the cationic dye. High catalytic activity towards four dyes: MB, methyl orange (MO), CR, and Rhodamine C (RhC) at the presence of NaBH4 is the remarkable property of these samples. The rate constant of the catalytic reaction was 1.4 min−1. Simultaneous exposure of CR and MO dyes to nanoparticles and NaBH4 caused their irreversible 100 % degradation while in the case of MB and RhC, a transition to their leuco form occurred.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kim P. D., Khalyapin D. L., Bykova L. E.
Заглавие : An automatic setup for measuring low-field temperature dependencies of magnetoresistances of film samples : научное издание
Место публикации : Instruments and Experimental Techniques. - Москва: Pleiades Publishing, Ltd., 2007. - Т. 50, № 4. - P.547-549. - ISSN 0020-4412, DOI 10.1134/S0020441207040227. - ISSN 1608-3180(eissn)
Аннотация: A simple method for magnetoresistance measurements in weak fields based on using a low-frequency alternating magnetic field is proposed. The special feature of this method is the direct measurement of the difference in resistance ΔR of the sample under study in the field and in the absence of the field, which offers a chance to significantly increase measurement sensitivity. The automatic setup for measuring temperature dependencies of magnetoresistance of film metallic samples with a ΔR sensitivity of up to 10-7 Ω is described. The temperature dependencies of magnetoresistance of thin-film nanocrystalline Co-Cu alloy samples in weak magnetic fields and in a temperature range of 77-300 K are studied
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Belyaev B. A., Voloshin A. S., Shabanov V. F.
Заглавие : Analysis of microstrip analogues of bandpass filters on one-dimensional photonic crystals
Место публикации : Journal of Communications Technology and Electronics. - Москва: Pleiades Publishing, Ltd. (Плеадес Паблишинг, Лтд), 2006. - Т. 51, № 6. - С. 653-659. - ISSN 1064-2269, DOI 10.1134/S1064226906060052. - ISSN 1531-846X(eissn)
Примечания : Библиогр.: 22
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Golovkina E. V., Krylova S. N., Vtyurin A. N., Krylov A. S.
Заглавие : Analyzing the symmetry of the Raman spectra of crystals according to angular dependences
Колич.характеристики :6 с
Место публикации : Bull. Russ. Acad. Sci. Phys. - 2024. - Vol. 88, Is. 5. - P.773-778. - ISSN 10628738 (ISSN), DOI 10.1134/S1062873824706573. - ISSN 19349432 (eISSN)
Примечания : Cited References: 32. - This work was supported by the Russian Foundation for Basic Research, project no. 21-52-12018. The authors are grateful to Dr. Irena Senkovska for providing our DUT-8(Ni) samples
Аннотация: The authors propose a way of reconstructing the Raman tensor by studying the angular dependences of the intensities of the Raman lines of unoriented microcrystals. The technique is verified using familiar calomel Hg2Cl2 crystals. It is shown that the lines on DUT-8 (Ni) crystals indicating phases with open and closed pores have different types of symmetries. The technique can be used to reconstruct the Raman tensor for any unoriented crystalline sample.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Martynov S. N.
Заглавие : Anisotropic exchange interactions in a ferromagnet PbMnBO4
Колич.характеристики :6 с
Место публикации : JETP Lett. - 2024. - Vol. 119, Is. 11. - P.879-884. - ISSN 00213640 (ISSN), DOI 10.1134/S0021364024600812. - ISSN 10906487 (eISSN)
Примечания : Cited References: 43. - I am grateful to A.I. Pankrats, V.I. Zinenko, and S.N. Krylova for useful discussions
Аннотация: The field dependence of the magnetization along the hard axes in a four-sublattice ferromagnet PbMnBO4 is calculated by the numerical minimization of the ground state energy in the approximation of classical magnetic moments. The parameters of anisotropic interactions—the second-order single-ion anisotropy constants, the magnitude and direction of the antisymmetric exchange vector, and the symmetric anisotropic exchange tensor—are obtained by a comparison with experimental magnetization curves. The direction of the Dzyaloshinskii–Moriya interaction vector is close to the orthorhombic c axis. The symmetric exchange tensor has an almost uniaxial form with the easy axis perpendicular to the antisymmetric exchange vector. Changes in the energy of each anisotropic interaction during magnetization reorientation are calculated.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krylov A. S., Shipilovskikh S. A., Krylova S. N., Slyusarenko N. V., Timofeeva M., Kenzhebayeva Yu. A., Bachinin S. V., Yushina I. D., Cherepakhin A. V., Shestakov N. P., Nemtsev I. V., Vtyurin A. N., Milichko V. A.
Заглавие : Application of DUT-4 MOF structure switching for optical and electrical humidity sensing
Колич.характеристики :6 с
Место публикации : Dalton Trans. - 2024. - Vol. 53, Is. 8. - P.3459-3464. - ISSN 14779226 (ISSN), DOI 10.1039/D4DT00038B. - ISSN 14779234 (eISSN)
Примечания : Cited References: 37. - The authors acknowledge the support by the state assignment of the Kirensky Institute of Physics FRC KSC SB RAS, also this work was financially supported by the RFBR (Russian Foundation for Basic Research), project no. 21-52-12018. S. A. S. acknowledges the financial support by the Russian Science Foundation (chemical part, Grant No. 22-73-10069 "Design and application of flexible metal organic frameworks for photonics devices"). V.A.M. acknowledges the Priority 2030 Federal Academic Leadership Program Ivan Sergeev (student in ITMO Univ.) for supporting in IV curve analysis. Raman, FTIR and SEM experiments were performed in the Center for Common Use of the Krasnoyarsk Scientific Center SB RAS (Krasnoyarsk, Russia)
Аннотация: The threshold structural transformation of the DUT-4 metal–organic framework (MOF) from an ordered to distorted phase during exposure to ambient conditions has been revealed. The in situ X-ray diffraction analysis, in situ Raman and FTIR spectroscopy, scanning electron microscopy and synchronous thermal analysis have been used for investigation. The reversible effect of exposure time and humidity on such a phase transition has been confirmed. We also demonstrated that the observed phase transition correlated well with changes in the optical and electronic properties of DUT-4, paving the way to a new family of MOF-based phase change materials for optoelectronic applications.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Semenov A.P., Semenova I.A., Churilov G. N., Bulina N. V., Semenova A. A.
Заглавие : Application of electron beam explosive evaporation of fullerenes in vacuum for thin films deposition : научное издание
Место публикации : Elektronika ir Elektrotechnika. - 2006. - № 5-6. - С. 158-160. - ISSN 1392-1215
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vnukova N. G., Nikolaev N. S., Churilov G. N., Isakova V. G., Elesina V. I., Glushenko G. A.
Заглавие : Application of mechanical separation method with filtration for nanodispersed FeNi powders with carbon coating
Колич.характеристики :6 с
Место публикации : Fuller. Nanotub. Carbon Nanostructures. - 2024. - Article in press. - ISSN 1536383X (ISSN), DOI 10.1080/1536383X.2024.2400270. - ISSN 15364046 (eISSN)
Примечания : Cited References: 36
Аннотация: It was shown that the method of mechanical separation with filtration could be used to separate metal nanoparticles in a carbon shell. The method was used for separation of FeNi nanoparticles with a carbon shell, previously isolated from carbon condensate by boiling in acids. The particles had a crystalline structure and magnetic characteristics (Mr/Ms = 0.30, Hc = 270 Oe). Method of mechanical separation with filtration made it possible to separate the sample into particles coated with a carbon shell (particles size 40–50 nm, size of the metal core 10–15 nm), and into metal particles with a diameter of 6–15 nm, dispersed in a carbon matrix. The work shows that the samples have similar magnetic properties (Mr/Ms = 0.27, Hc = 236 Oe) and chemical composition (Ni ∼ 10 wt.%, Fe ∼ 12 wt.%, C ∼ 57 wt.%). However, the samples differ in structure, one contains FeNi(220), FeNi(200), FeNi(111) and C(002) phases, while the other contains only FeNi(200) and C(002) phases.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zenkov A. V., Sushko E. S., Mogilnaya O. A., Volochaev M. N., Shabanov A. V., Kamnev A. A., Tugarova A. V., Kudryasheva N. S.
Заглавие : Application of the luminous bacterium Photobacterium phosphoreum for toxicity monitoring of selenite and its reduction to selenium(0) nanoparticles
Колич.характеристики :9 с
Место публикации : Spectrochim. Acta - A: Mol. Biomol. Spectrosc. - 2025. - Vol. 325. - Ст.125078. - ISSN 13861425 (ISSN), DOI 10.1016/j.saa.2024.125078. - ISSN 18733557 (eISSN)
Примечания : Cited References: 63. - This research was funded by the Russian Science Foundation and Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, grant No. 24-24-20001We acknowledge A.V. Raikov (School of Fundamental Biology and Biotechnology, Siberian Federal University, Krasnoyarsk, Russia) for spectral measurements; Dr. A.B. Sarangova (School of Fundamental Biology and Biotechnology, Siberian Federal University, Krasnoyarsk, Russia) for methodology of bacterial cultivation; Y.V. Chugaeva (Institute of Biophysics SB RAS, Federal Research Center "Krasnoyarsk Science Center SB RAS", 660036 Krasnoyarsk, Russia) for support of the collection of bacteria and their cultivation. The SEM and TEM studies were performed in Krasnoyarsk Regional Center of Research Equipment of Federal Research Center "Krasnoyarsk Science Center SB RAS"
Аннотация: Luminous marine bacteria are traditionally used as a bioassay due to the convenience and high rate of registering the intensity of their physiological function – luminescence. This study aimed to develop the application of Photobacterium phosphoreum in traditional and novel fields – toxicity monitoring and biotechnology. We demonstrated (1) effects of selenite ions on bioluminescence, and (2) biotransformation of selenite to selenium(0) in the form of nanoparticles. The effects of selenite (SeO32−) on the intensity of bacterial bioluminescence were studied, and its dependencies on exposure time and concentration of Na2SeO3 were analyzed. Bioluminescence activation and inhibition were revealed; dose–effect dependencies corresponded to the hormesis model. The toxicity of SeO32− was characterized by an effective concentration of 10−3 M. Effects of SeO32− on reactive oxygen species (ROS) in bacterial suspensions were studied. High positive correlations were found between the bioluminescence intensity and ROS content, which indicates the decisive role of ROS and associated redox processes in the bioeffects of selenite ions. Scanning and transmission electron microscopy revealed the presence of nano-structures in the bacteria exposed to selenite. The energy dispersion spectrum detected a high content of selenium in the nanoparticles. The particle size distribution depended on Na2SeO3 concentration; maxima of the distribution varied within 45–55 nm.
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20.

Вид документа : Статья из журнала
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Автор(ы) : Andryushchenko T. A., Lyashchenko S. A., Lukyanenko A. V., Varnakov S. N., Ovchinnikov S. G.
Заглавие : Auger electron spectroscopy of the air-exposed (Cr0.5Mn0.5)2GaC MAX film surface
Колич.характеристики :6 с
Место публикации : Tech. Phys. Lett. - 2023. - Vol. 49, Is. 7. - P.59-64. - ISSN 10637850 (ISSN), DOI 10.61011/TPL.2023.07.56448.19430. - ISSN 10906533 (eISSN)
Примечания : Cited References: 16. - This study was supported by a grant from the Russian Science Foundation, project № 21-12-00226 (http://rscf.ru/project/21-12-00226/)
Аннотация: We have analyzed chemical bonding of atmospheric oxygen with chromium and manganese on the epitaxial MAX-phase (Cr0.5Mn0.5)2GaC surface using Auger electron spectroscopy combined with ion etching. It was found that the system has a specific anisotropic oxidation where oxygen atoms bind to chromium and manganese ones more actively at the faces of layered MAX phase crystallites in contrast to the (0001) basal plane. At the same time, the dominance of the Mn–O chemical bonding over Cr–O is observed on the latter.
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