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Effect of electrode material on impedance spectra of metal-polyethylene structures with carbon nanotubes / N. A. Drokin [et al.] // Phys. Solid State. - 2012. - Vol. 54, Is. 4. - P. 844-848, DOI 10.1134/S1063783412040063. - Cited References: 15. - This study was supported by the Ministry of Education and Science of the Russian Federation within the framework of the Russian Federal Targeted Program "Scientific and Scientific-Pedagogical Human Resources for the Innovative Russia in 2009-2011" and the Presidium of the Russian Academy of Sciences (integration project no. 27.1). . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
SPECTROSCOPY
Аннотация: The effect of an electrode material on electrical properties of a composite material based on super-high-molecular polyethylene (SHMPE) filled with carbon nanotubes has been studied using impedance spectroscopy. Using the method of replacing the sample by an equivalent electric circuit, it has been found that, depending on the electrode material, a blocking barrier with high active resistance and a space charge region adjacent to it arise in the interface region. It has been shown that the barrier height is controlled by surface electronic states of SHMPE and weakly depends on the electron work function of metal electrodes (Bardeen barrier). The characteristic times of electrical relaxation characterizing bulk and interface regions of the composite under study have been determined.

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Публикация на русском языке Влияние материала электродов на импедансные спектры структур металл-полиэтилен с углеродными нанотрубками [Текст] / Н. А. Дрокин [и др.] // Физ. тверд. тела : Физико-технический институт им. А.Ф.Иоффе РАН, 2012. - Т. 54 вып. 4. - С. 791-796

Держатели документа:
[Drokin, N. A.
Glushchenko, G. A.
Osipova, I. V.
Maslennikov, A. N.
Churilov, G. N.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Drokin, N. A.] Reshetnev Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
[Kokourov, G. A.] Siberian Fed Univ, Krasnoyarsk 660041, Russia

Доп.точки доступа:
Drokin, N. A.; Дрокин, Николай Александрович; Kokourov, G. A.; Glushchenko, G. A.; Глущенко, Гарий Анатольевич; Osipova, I. V.; Осипова, Ирина Владимировна; Maslennikov, A. N.; Масленников, Алексей Николаевич; Churilov, G. N.; Чурилов, Григорий Николаевич
}
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    Synthesis and electronic properties of β-RbNd(MoO4)2 / V. V. Atuchin [et al.] // Asian J. Chem. - 2014. - Vol. 26, No. 5. - P. 1284-1286, DOI 10.14233/ajchem.2014.17209. - Cited References: 26. - This study is partly supported by by the Ministry of Education and Science of the Russian Federation. . - ISSN 0970-7077
   Перевод заглавия: Синтез и электронные свойства бета-RbNd(MoO4)2

РУБ Chemistry, Multidisciplinary
Рубрики:
UP-CONVERSION PHOTOLUMINESCENCE
   VIBRATIONAL PROPERTIES
   CRYSTAL-STRUCTURE
   PARTICLES
   MOLYBDATE
   SPECTROSCOPY
   SYSTEM
   ER3+
Кл.слова (ненормированные):
β-RbNd(MoO4)2 -- Electronic structure -- Ab initio calculations -- X-Ray photoelectron spectroscopy
Аннотация: The electronic structure of β-RbNd(MoO4)2 has been evaluated from experimental and theoretical points of view. For the molybdate, X-ray photoelectron valence-band spectra have been measured. The total and partial densities of states of the constituent atoms of β-RbNd(MoO4)2 have been calculated using the FP-LAPW method. The FP-LAPW data reveal that main contributors in the valence-band region of β-RbNd(MoO4)2 are the Rb 4p-, Nd 4f-, Mo 4d- and O 2p-like states.

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Держатели документа:
SB RAS, Lab Opt Mat & Struct, Inst Semicond Phys, Novosibirsk 630090, Russia
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia
Novosibirsk State Univ, Novosibirsk 630090, Russia
Natl Acad Sci Ukraine, Frantsevich Inst Problems Mat Sci, UA-03142 Kiev, Ukraine
SB RAS, Lab Oxide Syst, Baikal Inst Nat Management, Ulan Ude 670047, Russia
SB RAS, Lab Crystal Phys, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Hanseo Univ, Dept Adv Mat Sci & Engn, Seosan 356706, South Korea

Доп.точки доступа:
Atuchin, V. V.; Bekenev, V. L.; Chimitova, O. D.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Bazarov, B. G.; Базаров Б. Г.; Bazarova, J. G.; Базарова Ж. Г.; Khuzhum, O. Y.; Lim, C. S.
}
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Val'kov, V. V.
Effects of multiple reflection in the process of inelastic electron transport through an anisotropic magnetic atom / V. V. Val'kov, S. V. Aksenov, E. A. Ulanov // JETP Letters. - 2013. - Vol. 98, Is. 7. - P. 403-409, DOI 10.1134/S0021364013200162. - Cited References: 27. - This work was supported by the Presidium of the Russian Academy of Sciences (program "Quantum Mesoscopic and Disordered Systems"), the Ministry of Education and Science of Russian Federation (state contract no. 16.740.11.0644, federal program "Human Capital for Science and Education in Innovative Russia" for 2009-2013), and the Russian Foundation for Basic Research (project nos. 12-02-31130, 13-02-00523, and 13-02-98013). S. V. A. is grateful to the Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools, project nos. MK-526.2013.2 and SP-6361.2013.5. . - ISSN 0021-3640

РУБ Physics, Multidisciplinary
Рубрики:
QUANTUM
SPECTROSCOPY
STATE
Аннотация: The effect of multiple reflection in the process of electron transport on the current-voltage characteristics of an adsorbed magnetic atom with single-ion anisotropy has been investigated. All orders of the perturbation theory with respect to the parameter of coupling between the contacts and the multilevel impurity have been taken into account by the Keldysh diagram technique with the use of Hubbard operators. It has been shown that the current-voltage characteristics of the system in a strongly nonequilibrium regime contains regions of negative differential conductance. The ways of enhancing this effect are discussed.

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Публикация на русском языке Эффекты многократного отражения при неупругом электронном транспорте через анизотропный магнитный атом. - [S. l. : s. n.]

Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia

Доп.точки доступа:
Aksenov, S. V.; Аксенов, Сергей Владимирович; Ulanov, E. A.; Вальков, Валерий Владимирович; Presidium of the Russian Academy of Sciences; Ministry of Education and Science of Russian Federation [16.740.11.0644]; Russian Foundation for Basic Research [12-02-31130, 13-02-00523, 13-02-98013]; Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools [MK-526.2013.2, SP-6361.2013.5]
}
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Magneto-optical activity of crude oil and its heavy fractions / A. E. Sokolov [et al.] // Opt. Spectrosc. - 2012. - Vol. 112, Is. 5. - P. 755-762, DOI 10.1134/S0030400X12050165. - Cited References: 18. - This work was performed under Interdisciplinary Integration Project no. 118 of the Siberian Branch of the Russian Academy of Sciences (2009-2011). . - ISSN 0030-400X

РУБ Optics + Spectroscopy
Рубрики:
MAGNETIC CIRCULAR-DICHROISM
   SINGLE-CRYSTALS
   SPECTROSCOPY
   EPR
   ABSORBENCY
   PORPHYRIN
   SYSTEMS
Аннотация: We have experimentally studied optical and magneto-optical spectra of solutions of crude oils of different origin and their heavy fractions in the visible spectral range. Magnetic circular dichroism of oil in the wavelength range similar to 550 nm has been revealed. We show that the shape of the spectra of this dichroism depends on the origin of crude oil, with the magnetic dichroism magnitude being proportional to the concentration of the oil in the solution. A comparison of the data of magneto-optical spectroscopy with electron paramagnetic resonance spectra and chemical composition of samples has allowed us to conclude that the observed magneto-optical activity is determined by the occurrence of VO2+ complexes in the oil samples. The revealed magneto-optical activity of crude oil can form the basis of a unique method of analysis of the composition and properties of oils of different origin and heavy fractions thereof.

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Публикация на русском языке Магнитооптическая активность природной нефти и ее тяжелых фракций [Текст] / А. Э. Соколов [и др.] // Оптика и спектроскопия : Наука, 2012. - Т. 112 № 5. - С. 820-827

Держатели документа:
[Sokolov, A. E.
Edelman, I. S.
Zabluda, V. N.
Petrakovskaya, E. A.
Aleksandrovskii, A. S.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Shubin, A. A.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
[Trukhan, S. N.
Mart'yanov, O. N.] Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia

Доп.точки доступа:
Sokolov, A. E.; Соколов, Алексей Эдуардович; Edelman, I. S.; Эдельман, Ирина Самсоновна; Zabluda, V. N.; Заблуда, Владимир Николаевич; Petrakovskaya, E. A.; Петраковская, Элеонора Анатольевна; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Shubin, A. A.; Trukhan, S. N.; Mart'yanov, O. N.
}
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Experimental and theoretical methods to study structural phase transition mechanisms in K3WO3F3 oxyfluoride / A. S. Krylov [et al.] // J. Solid State Chem. - 2014. - Vol. 218. - P. 32-37, DOI 10.1016/j.jssc.2014.05.028. - Cited References: 21. - The Authors are grateful to Prof. Zinenko V.I. for constructive discussion of the results. The work has been done with financial support of the Russian Foundation for Basic Research projects nos. 4828.2012.2, 12-02-31205; Federal Special Program "Scientific and scientific-pedagogical staff of innovative Russia" project no. 8379. . - ISSN 0022-4596. - ISSN 1095-726X

РУБ Chemistry, Inorganic & Nuclear + Chemistry, Physical
Рубрики:
LATTICE-DYNAMICS
   RAMAN-SCATTERING
   ELPASOLITE
   (NH4)3WO3F3
   SPECTROSCOPY
   CRYSTALS
Кл.слова (ненормированные):
Raman spectroscopy -- IR spectroscopy -- NMR spectroscopy -- High hydrostatic pressure -- Oxyfluorides -- Lattice dynamics calculations
Аннотация: The results of structural phase transitions mechanisms study in K3WO3F3oxyfluoride are represented by different experimental and theoretical methods. The structural phase transition anomalies at T1=452 K and T2=414 K of Raman and IR spectra have been analyzed. Using vibrational spectroscopy methods, the NMR-experiment has been done to clarify the nature of found phase transitions: displacive types or order-disorder types. The model of “disordered” crystal was proposed, and the results of lattice dynamics calculation in frameworks of the generalized Gordon–Kim method of ordered (R3) and “disordered” crystals were compared. The high pressure phases were studied by the Raman technique too.

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Держатели документа:
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Russian Acad Sci, Siberian Branch, VS Sobolev Inst Geol & Mineral, Novosibirsk 630090, Russia

Доп.точки доступа:
Krylov, A. S.; Крылов, Александр Сергеевич; Sofronova, S. N.; Софронова, Светлана Николаевна; Kolesnikova, E. M.; Колесникова, Евгения Михайловна; Ivanov, Y. N.; Иванов, Юрий Николаевич; Sukhovsky, A. A.; Суховский, Андрей Андреевич; Goryainov, S. V.; Ivanenko, A. A.; Иваненко, Александр Анатольевич; Shestakov, N. P.; Шестаков, Николай Петрович; Kocharova, A. G.; Кочарова, Алла Георгиевна; Vtyurin, A. N.; Втюрин, Александр Николаевич; Russian Foundation for Basic Research [4828.2012.2, 12-02-31205]; Federal Special Program "Scientific and scientific-pedagogical staff of innovative Russia" [8379]
}
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Val'kov, V. V.
Inelastic tunnel transport of electrons through an anisotropic magnetic structure in an external magnetic field / V. V. Val'kov, S. V. Aksenov, E. A. Ulanov // J. Exp. Theor. Phys. - 2014. - Vol. 119, Is. 1. - P. 124-137, DOI 10.1134/S1063776114060065. - Cited References: 35. - This work was performed under the Program "Quantum Mesoscopic and Disordered Systems" of the Presidium of the Russian Academy of Sciences and supported financially by the Russian Foundation for Basic Research (project nos. 13-02-00523, 13-02-98013, and 14-02-31280). The work of one of coauthors (S. V. A.) was supported by grant no. MK-526-526.2013.2 of the President of the Russian Federation and scholarship SP-6361.2013.5 of the President of the Russian Federation. . - ISSN 1063-7761. - ISSN 1090-6509

РУБ Physics, Multidisciplinary
Рубрики:
SINGLE-MOLECULE
   SPECTROSCOPY
   ATOM
   STATE
Аннотация: Quantum transport of electrons through a magnetic impurity located in an external magnetic field and affected by a substrate is considered using the Keldysh diagram technique for the Fermi and Hubbard operators. It is shown that in a strongly nonequilibrium state induced by multiple reflections of electrons from the impurity, the current-voltage (I-V) characteristic of the system contains segments with a negative conductivity. This effect can be controlled by varying the anisotropy parameter of the impurity center as well as the parameters of coupling between the magnetic impurity and metal contacts. The application of the magnetic field is accompanied by an increase in the number of Coulomb steps in the I-V curve of the impurity. The effect of appreciable magnetoresistance appears in this case. We demonstrate the possibility of switching between magnetic impurity states with different total spin projection values in the regime of asymmetric coupling of this impurity with the contacts.

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Переводная версия Вальков, Валерий Владимирович. Неупругий туннельный транспорт электронов через анизотропную магнитную структуру во внешнем магнитном поле [Текст] / В. В. Вальков, С. В. Аксенов, Е. А. Уланов // Журн. эксперим. и теор. физ. : Наука, 2014. - Т. 146 Вып. 1. - С. 144-159

Держатели документа:
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Siberian Aerosp Univ, Krasnoyarsk 660014, Russia

Доп.точки доступа:
Aksenov, S. V.; Аксенов, Сергей Владимирович; Ulanov, E. A.; Уланов Е. А.; Вальков, Валерий Владимирович; Russian Foundation for Basic Research [13-02-00523, 13-02-98013, 14-02-31280]; Russian Federation [MK-526-526.2013.2, SP-6361.2013.5]
}
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Val'kov, V. V.
Quantum transport through a multilevel magnetic structure with multiple inelastic scattering in a magnetic field taken into account / V. V. Val'kov, S. V. Aksenov, E. A. Ulanov // Low Temp. Phys. - 2015. - Vol. 41, Is. 2. - P. 98-105, DOI 10.1063/1.4913204. - Cited References:33. - This work was supported by the Program of the Presidium of RAS "Quantum mesoscopic and disordered systems" and Russian Foundation for Basic Research (Grant Nos. 13-02-00523, 13-02-98013, and 14-02-31280).One of the authors (S.V.A.) is grateful to the grant of the President of the Russian Federation MK-526.2013.2 and the scholarship of the President of the Russian Federation SP-6361.2013.5 for the support. . - ISSN 1063. - ISSN 1090-6517. -

РУБ Physics, Applied
Рубрики:
SINGLE-MOLECULE
   SPECTROSCOPY
   ATOM
   ANISOTROPY
Аннотация: We present a solution for the problem of quantum electron transport through a magnetic atom adsorbed inside a break junction with paramagnetic metal electrodes. In agreement with experimental data, it was assumed that the conduction electrons experience inelastic scattering by the adsorbate due to s–d(f)-exchange interaction. The Keldysh technique was employed to obtain a general expression describing a current through the multilevel structure at finite temperatures in terms of the nonequilibrium Green's function. The use of the atomic representation allowed to exactly account for the non-equidistant structure of the energy spectrum of a magnetic atom and to simplify substantially the application of the Wick theorem for construction of the nonequilibrium diagrammatic technique for the Hubbard operators. The calculation of the current-voltage characteristics of the magnetic adatom in the tunnel regime at low temperatures revealed the presence of regions with a negative differential conductance in a magnetic field.

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Публикация на русском языке Вальков, Валерий Владимирович. Квантовый транспорт через многоуровневую магнитную структуру при учете процессов многократного неупругого рассеяния в магнитном поле [Текст] / В. В. Вальков, С. В. Аксенов, Е. А. Уланов // Физ. низких температур : Физико-технический институт низких температур им. Б. И. Веркина НАН Украины, 2015. - Т. 41 Вып. 2. - С. 129-138

Держатели документа:
Kirenskii Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Aerosp Univ, Krasnoyarsk 660014, Russia.

Доп.точки доступа:
Aksenov, S. V.; Аксенов, Сергей Владимирович; Ulanov, E. A.; Вальков, Валерий Владимирович; Program of the Presidium of RAS "Quantum mesoscopic and disordered systems"; Russian Foundation for Basic Research [13-02-00523, 13-02-98013, 14-02-31280]; Russian Federation [MK-526.2013.2, SP-6361.2013.5]
}
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Arkhipkin, V. G.
Electromagnetically induced transparency and controlling the time shape of laser pulses / V. G. Arkhipkin, I. V. Timofeev // Dokl. Phys. - 2005. - Vol. 50, Is. 4. - P. 165-168, DOI 10.1134/1.1922553. - Cited References: 14 . - ISSN 1028-3358

РУБ Mechanics + Physics, Multidisciplinary
Рубрики:
SPECTROSCOPY

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Публикация на русском языке Архипкин, Василий Григорьевич. Электромагнитно индуцированная прозрачность и управление временной формой лазерных импульсов [Текст] / В. Г. Архипкин, И. В. Тимофеев // Доклады Академии наук. - 2005. - Т. 401 № 4. - С. 467-470

Доп.точки доступа:
Timofeev, I. V.; Тимофеев, Иван Владимирович; Архипкин, Василий Григорьевич
}
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    Raman study of datolite CaBSiO4(OH) at simultaneously high pressure and high temperature / S. V. Goryainov [et al.] // J. Raman Spectrosc. - 2015. - Vol. 46, Is. 1. - P. 177-181, DOI 10.1002/jrs.4614. - Cited References:30. - This work was partly supported by the Russian Foundation for BasicResearch (grants N 14-05-00616 and 13-05-00185) and the Ministry ofEducation and Science of the Russian Federation. . - ISSN 0377. - ISSN 1097-4555
   Перевод заглавия: Исследование датолита CaBSiO4(ОН) при одновременно высоком давлении и высокой температуре методом спектроскопии комбинационного света

РУБ Spectroscopy
Рубрики:
X-RAY-DIFFRACTION
   CRYSTAL-STRUCTURE
   HYDROGEN-BOND
   SPECTROSCOPY
Кл.слова (ненормированные):
Raman spectra -- datolite -- high pressure -- high temperature -- diamond anvil -- cell
Аннотация: Using an in situ method of Raman spectroscopy and resistance-heated diamond anvil cell, the system datolite CaBSiO4(OH) – water has been investigated at simultaneously high pressure and temperature (up to Р ~5 GPa and Т ~250 °С). Two polymorphic transitions have been observed: (1) pressure-induced phase transition or the feature in pressure dependence of Raman band wavenumbers at P = 2 GPа and constant T = 22 °С and (2) heating-induced phase transition at T ~90 °С and P ~5 GPа. The number of Raman bands is retained at the first transition but changed at the second transition. The first transition is mainly distinguished by the changes in the slopes of pressure dependence of Raman peaks at 2 GPa. The second transition is characterized by several strong changes: the wavenumber jumps of major bands, the merging of strong doublets at 378 and 391 cm−1 (values for ambient conditions), the splitting of the intermediate-intensity band at 292 cm−1, and the transformation of some low-wavenumber bands at 160–190 cm−1. No spectral and visual signs of overhydration and amorphization have been observed. No noticeable dissolution of datolite in the water medium occurred at 5 GPa and 250 °С after 3 h, which corresponds to typical conditions of the ‘cold’ zones of slab subduction. Copyright © 2014 John Wiley & Sons, Ltd.

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Держатели документа:
VS Sobolev Inst Geol & Mineral SB RAS, Novosibirsk 630090, Russia.
LV Kirensky Inst Phys SB RAS, Krasnoyarsk 660036, Russia.
Univ Saskatchewan, Dept Geol Sci, Saskatoon, SK S7N 5E2, Canada.

Доп.точки доступа:
Goryainov, S. V.; Krylov, A. S.; Крылов, Александр Сергеевич; Vtyurin, A. N.; Втюрин, Александр Николаевич; Pan, Y.; Russian Foundation for Basic Research [N 14-05-00616, 13-05-00185]; Ministry of Education and Science of the Russian Federation
}
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10.

Spectral signatures of spin-phonon and electron-phonon interactions in multiferroic iron borates / M. N. Popova [et al.] // J. Magn. Magn. Mater. - 2015. - Vol. 383. - P. 250-254, DOI 10.1016/j.jmmm.2014.10.095. - Cited References:32. - This work was supported by the Russian Science Foundation (Grant no. 14-12-01033). Experiments at U4-IR beamline NSLS-BNL (T.N.S. and A.A.S.) were performed under Contract no. DE-FG02-07ER46382 from the U.S. Department of Energy. The National Synchrotron Light Source is operated as a User Facility for the U.S. Department of Energy under Contract no. DE-AC02-98CH10886. M.N.P. thanks B.Z. Malkin for helpful discussions. . - ISSN 0304-8853. - ISSN 1873-4766

РУБ Materials Science, Multidisciplinary + Physics, Condensed Matter
Рубрики:
SMFE3(BO3)4
   SPECTROSCOPY
   CRYSTALS
   SM
Кл.слова (ненормированные):
Rare-earth iron borates -- Spin phonon interactions -- Electron phonon coupling -- Optical spectroscopy
Аннотация: High-resolution far-infrared reflection and polarized ellipsometry, as well as Raman scattering temperature-dependent measurements are used to study spin-phonon and electron-phonon interactions in rare-earth (RE) iron borates with the R32 structure of a natural mineral huntite, namely, in RFe3(BO3)4 with R=Pr, Nd, and Sm. Pronounced peculiarities in the ω(T) dependences at the Néel temperature TN≈32 K are observed for all the compounds studied and the origin of these peculiarities is discussed. A coupling between lattice phonons and crystal-field excitations of a RE ion manifests itself by a renormalization of frequencies and intensities of coupled modes. Modeling of the spectra has revealed the value of about 15 cm−1 for the electron–phonon coupling constant in PrFe3(BO3)4.
Высокоразрешающая эллипсометрия дальнего инфракрасного отражения и поляризованный света, а также температурнозависимые измерения комбинационного рассеяния используются для изучения спин-фононных и электрон-фононных взаимодействий в редкоземельных (RE) боратах железа со структурой R32 природного минерала хантита , а именно, в RFe3 (BO3) 4 с R = Pr, Nd, и Sm. Выраженные особенности ω (T) зависимостей при температуре Нееля TN ≈32 K наблюдаются для всех исследованных соединений и происхождение этих особенностей обсуждается.Связь между фононами решетки и возбуждениями кристаллического поля РЗ иона проявляется себя перенормализации частоты и интенсивности связанных мод. Моделирование спектров показал значение около 15cm-1 для константы электрон-фононной связи в PrFe3 (BO3) 4.

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Доп.точки доступа:
Popova, M. N.; Boldyrev, K. N.; Klimin, S. A.; Stanislavchuk, T. N.; Sirenko, A. A.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Russian Science Foundation [14-12-01033]; U.S. Department of Energy [DE-FG02-07ER46382, DE-AC02-98CH10886]; Moscow International Symposium on Magnetism(6 ; 2014 ; June-July ; Moscow)
}
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11.

    Antiferromagnetic dichroism in a complex multisublattice magnetoelectric CuB2O4 / K. N. Boldyrev [et al.] // Phys. Rev. Lett. - 2015. - Vol. 114, Is. 24. - Ст. 247210, DOI 10.1103/PhysRevLett.114.247210. - Cited References:40. - This study was supported by the Russian Academy of Sciences under the Programs for Basic Research, by the President of the Russian Federation (Grant No. MK-3521.2015.2, K. N. B.), by the Russian Foundation for Basic Research (Grants No. 15-32-20613, K. N. B., and No. 15-02-04222, R. V. P.), and by the Ministry of Education and Science of the Russian Federation (Grant No. 14.B25.0031.25, R. V. P.). . - ISSN 0031. - ISSN 1079-7114
   Перевод заглавия: Антиферромагнитный дихроизм в сложном многоподрешеточном магнетоэлектрике CuB2O4

РУБ Physics, Multidisciplinary
Рубрики:
MAGNETIC SOLITON LATTICE
   COPPER METABORATE
   GYROTROPIC BIREFRINGENCE
   SPECTROSCOPY
   EXCITATIONS
   TRANSITIONS
   CRYSTALS
   Cr2O3
   FIELD
Аннотация: Magnetic control of the crystal chirality was announced by Saito et al. [Phys. Rev. Lett. 101, (2008)] on the ground of experiments in CuB2O4. This claim has raised a sharp dispute in the literature because it seemed to contradict the fundamental symmetry principles. We settle this dispute on the basis of a high-resolution optical spectroscopy study of excitonic transitions in CuB2O4. We find that a large sublattice-sensitive antiferromagnetic linear dichroism (LD) emerges at the Néel temperature TN=21 K and show how it could simulate a “magnetic-field control of the crystal chirality.” We prove that the discovered LD is related microscopically to the magnetic Davydov splitting. This LD is highly sensitive to subtle changes in the spin subsystems, which allowed us to observe a splitting of the phase transition into an incommensurate magnetic phase into two transitions (T∗1=8.5 and T∗2=7.9 K) and to suggest elliptical spiral structures below T∗1, instead of a simple circular helix proposed earlier.
О магнитном контроле кристаллической хиральности сообщил Сайто и др. [Phys. Rev. Lett. 101, 117402 (2008)] на основании экспериментов в CuB2O4. Это требование вызвало резкий спор в литературе, потому что это казалось, противоречат основным принципам симметрии. Мы урегулировать этот спор на основе исследования с помощью оптической спектроскопии высокого разрешения экситонных переходов в CuB2O4. Мы считаем, что большой подрешетко-чувствительный антиферромагнитный линейный дихроизм (LD) возникает при температуре Нееля TN= 21 Kи показываем, как это может имитировать "контроль магнитным полем кристаллической хиральности." Мы докажем, что обнаруженный LD связанс микроскопическим магнитным Давыдовским расщеплением. Этот Л.Д. весьма чувствителен к тонким изменениям в спиновых подсистем, которые позволили нам наблюдать расщепление фазового перехода в несоизмеримы магнитная фаза в двух переходов (T*1= 8,5 и Т*2 = 7,9 К) и предположить эллиптическую спиральную структуру ниже T*1, вместо простой круговой спирали предложенный ранее.

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Держатели документа:
RAS, Inst Spect, Moscow 142190, Russia.
RAS, Ioffe Phys Tech Inst, St Petersburg 194021, Russia.
RAS, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Boldyrev, K. N.; Pisarev, R. V.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Popova, M. N.; Russian Academy of Sciences under the Programs for Basic Research; Russian Federation [MK-3521.2015.2]; Russian Foundation for Basic Research [15-32-20613, 15-02-04222]; Ministry of Education and Science of the Russian Federation [14.B25.0031.25]
}
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12.

    Crystal and local atomic structure of MgFeBO4,Mg0.5Co0.5FeBO4, and CoFeBO4: effects of Co substitution / N. V. Kazak [et al.] // Phys. Status Solidi B. - 2015. - Vol. 252, Is. 10. - P. 2245-2258, DOI 10.1002/pssb.201552143. - Cited References: 46. - This work has been financed by the MECOM Project MAT11/23791, and DGA IMANA project E-34, Council for Grants of the President of the Russian Federation (project nos. NSh-2886.2014.2, SP-938.2015.5), and Russian Foundation for Basic Research (project nos. 13-02-00958-a, 13-02-00358-a, 14-02-31051-mol-a). The work of one of the coauthors (M.S.P.) was supported by the program of Foundation for promoting the development of small enterprises in scientific and technical sphere ("UMNIK" program). . - ISSN 0370. - ISSN 1521-3951
   Перевод заглавия: Кристаллическая и локальная атомная структура MgFeBO4, Mg0.5Co0.5FeBO4 and CoFeBO4: эффект замещения Со

РУБ Physics, Condensed Matter
Рубрики:
SPIN-GLASS BEHAVIOR
   MAGNETIC WARWICKITES
   SINGLE-CRYSTALS
   PHASE-RELATIONS
   OXYBORATE
   SYSTEM
   SPECTROSCOPY
   ANISOTROPY
   MN2OBO3
   FE2OBO3
Кл.слова (ненормированные):
crystal structure -- XANES -- EXAFS -- magnetic semiconductor -- oxyborate
Аннотация: Single-crystalline MgFeBO4, Mg0.5Co0.5FeBO4, and CoFeBO4 have been grown by the ﬂux method. The samples have been characterized by X-ray spectral analysis, X-ray diffraction, and X-ray absorption spectroscopy. The X-ray absorption near-edge structure (XANES) and extended X-ray absorption ﬁne structure (EXAFS) spectra have been measured at the Fe and Co K-edges over a wide temperature range (6.5– 300 K). The composition, the charge state, and local environ- ment of both Fe and Co atoms have been determined. The effects of Co substitution for Mg on the local structural distortions have been revealed experimentally and the M–O bond anisotropy has been found.
Монокристаллические образцы CoFeBO4 были выращены раствор-расплавным методом. Образцы были охарактеризованы с помощью рентгеноспектрального анализа, рентгеновской дифракции и спектроскопии поглощения рентгеновских лучей. Спектры вблизи K-края поглощения рентгеновского излучения структуры (XANES) и далее рентгеновского поглощения тонкой структуры (EXAFS) были измерены для Fe и Co в широком диапазоне температур (6.5- 300К). Состав, состояние заряда, и локальная положение и Fe и Co атомов были определены. Эффекты замещения Co магнием Mg на местные структурные искажения были выявлены экспериментально и анизотропия связи М-О была найдена.

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Держатели документа:
Kirensky Institute of Physics, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
National Research Center Kurchatov Institute, Moscow, Russian Federation
Servicio de Medidas Fi, sicas, Universidad de Zaragoza, Zaragoza, Spain
Departamento de Fisica de la Materia Condensada, Instituto de Ciencia de Materiales de Aragon, CSIC, Universidad de Zaragoza, Zaragoza, Spain
O. O. Galkin Institute for Physics and Engineering, National Academy of Sciences of Ukraine, Donetsk, Ukraine

Доп.точки доступа:
Kazak, N. V.; Казак, Наталья Валерьевна; Platunov, M. S.; Платунов, Михаил Сергеевич; Knyazev, Yu. V.; Князев, Юрий Владимирович; Ivanova, N. B.; Иванова, Наталья Борисовна; Zubavichus, Y. V.; Veligzhanin, A. A.; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Bayukov, O. A.; Баюков, Олег Артемьевич; Arauzo, A.; Bartolome, J.; Lamonova, K. V.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич
}
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13.

Magnetic properties, morphology and interfaces of (Fe/Si)n nanostructures / Bartolome J. [et al.] // J. Magn. Magn. Mater. - 2016. - Vol. 400. - P. 271-275, DOI 10.1016/j.jmmm.2015.07.046. - Cited References: 43. - The financial support of the Spanish MINECOMAT2011-23791 and MAT2015-53921-R, Aragonese DGA-IMANAE34 (cofounded by Fondo Social Europeo) and European FEDER funds is acknowledged. Program of the President of the Russian Federation for the support of leading scientific schools (Scientific School 2886.2014.2), RFBR (Grant no. 13-02-01265), the Ministry of Education and Science of the Russian Federation (State contract no. 02.G25.31.0043 and State task no. 16.663.2014К) . - ISSN 0304-8853

РУБ Materials Science, Multidisciplinary + Physics, Condensed Matter
Рубрики:
INTERLAYER EXCHANGE
   Fe/Si(100) INTERFACE
   SILICIDE FORMATION
   ULTRAHIGH-VACUUM
   FILMS
   IRON
   MAGNETORESISTANCE
   SUPERLATTICES
   SPECTROSCOPY
   DEPOSITION
Аннотация: A systematic study of the iron–silicon interfaces formed upon preparation of (Fe/Si) multilayers has been performed by the combination of modern and powerful techniques. Samples were prepared by molecular beam epitaxy under ultrahigh vacuum onto Si wafers or single crystalline Ag(100) buffer layers grown on GaAs(100). The morphology of these films and their interfaces was studied by a combination of scanning transmission electron microscopy, X-ray reflectivity, angle resolved X-ray photoelectron spectroscopy and hard X-ray photoelectron spectroscopy. The Si-on-Fe interface thickness and roughness were determined to be 1.4(1) nm and 0.6(1) nm, respectively. Moreover, determination of the stable phases formed at both Fe-on-Si and Si-on-Fe interfaces was performed using conversion electron Mössbauer spectroscopy on multilayers with well separated Si-on-Fe and Fe-on-Si interfaces. It is shown that while a fraction of Fe remains as α-Fe, the rest has reacted with Si, forming the paramagnetic FeSi phase and a ferromagnetic Fe rich silicide. We conclude that there is an identical paramagnetic c-Fe1−xSi silicide sublayer in both Si-on-Fe and Fe-on-Si interfaces, whereas an asymmetry is revealed in the composition of the ferromagnetic silicide sublayer.

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Bartolome, J.; Badía-Romano, L.; Rubin J.; Bartolome F.; Varnakov, S. N.; Варнаков, Сергей Николаевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Burgler D.E.; International Conference on Magnetism(20 ; 2015 ; Jul ; 5-10 ; Barselona, Spain)
Свободных экз. нет}
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14.

Gorelik, V. S.
Raman scattering in sodium nitrite crystals near the phase transition / V. S. Gorelik, A. Y. Pyatyshev, A. S. Krylov // Phys. Solid State. - 2016. - Vol. 58, Is. 1. - P. 170-176, DOI 10.1134/S1063783416010133. - Cited References: 39. - This study was supported by the Russian Foundation for Basic Research (project nos. 12-02-00491, 13-02-00449, 13-02-90420, and 14-02-00190). . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
NaNO2
   SPECTROSCOPY
   DEPENDENCE
   SPECTRUM
   SEARCH
   MODES
Аннотация: Optical Raman spectra of a ferroelectric sodium nitrite crystal have been detected in a wide spectrum range at various temperatures, including the region of the ferroelectric phase transition. A manifestation of a transverse soft polar mode of the A1(z) type responsible for the ferroelectric phase transition has been discovered in the spectrum at room temperature. This mode has been found to become overdamped even far from the ferroelectric phase transition temperature. This mode also appears as a central peak under heating. It has been found that the pseudoscalar mode of the A2 type has the highest intensity in the Raman spectrum of sodium nitrite. The frequency corresponding to the maximum intensity of this mode in the Raman spectrum varies from 130 cm–1 at 123 K to 106 cm–1 at T = 513 K. A fair agreement of the experimental data for the A1(z) mode with the Lyddane–Sachs–Teller relation has been established. The polariton curves for the A1(z) polar mode and the dispersion curves for axinons has been plotted. © 2016, Pleiades Publishing, Ltd.

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Публикация на русском языке Горелик, Владимир Семенович. Комбинационное рассеяние света в области фазового перехода в кристаллах нитрита натрия [Текст] / В. С. Горелик, А. Ю. Пятышев, А. С. Крылов // Физ. тверд. тела : Физико-технический институт им. А. Ф. Иоффе РАН, 2016. - Т. 58 Вып. 1. - С. 163-169

Держатели документа:
Lebedev Physical Institute, Russian Academy of Sciences, Leninskii pr. 53, Moscow, Russian Federation
Bauman Moscow State Technical University, Vtoraya Baumanskaya ul. 5, Moscow, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Pyatyshev, A. Y.; Krylov, A. S.; Крылов, Александр Сергеевич
}
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15.

NMR applications for polymer composite materials moisture uptake investigation / V. M. Bouznik [et al.] // Appl. Magn. Reson. - 2016. - Vol. 47, Is. 3. - P. 321-334, DOI 10.1007/s00723-015-0748-2. - Cited References: 41. - This research was performed with the financial support of Russian Foundation for Basic Research (project no. 14-29-10178 ofi_m). . - ISSN 0937-9347

РУБ Physics, Atomic, Molecular & Chemical + Spectroscopy
Рубрики:
FIELD GRADIENT NMR
   REINFORCED EPOXY COMPOSITES
   WATER SELF-DIFFUSION
   TRANSPORT
   GLASS
   SYSTEM
   SPECTROSCOPY
   TEMPERATURE
   ABSORPTION
   ADHESIVE
Аннотация: The 1H nuclear magnetic resonance (NMR) spectroscopy, NMR imaging, and pulsed field gradient NMR (PFG NMR) were applied for comparative study of moisture–polymer composite materials (PCM) interaction. The water uptake in PCM reinforced by aramid and carbon fibers was measured by NMR spectroscopy techniques. The aramid fiber-reinforced PCM absorbs water more intensively compared with PCM reinforced by carbon fiber, but both of them are retaining water inside of pores without formation of chemical bonds. Using NMR imaging the spatial distribution of water absorbed was visualized; preferable water pathways and influence of surface treatment on water-resistant properties were revealed. It was found that the surface rough treatment sufficiently improves the water absorption, but penetration of water molecules is still occurring only through the surfaces and it happens within a thin layer. PFG NMR technique revealed influence of pore structure on moisture–PCM interaction; it was found that additionally to strong hydrophobic properties of carbon fiber, the smaller total volume of pores sufficiently decrease the water uptake. Results achieved in this work demonstrate efficiency of NMR methods applied all together for investigation of PCM, and information obtained is practically important when designing advanced PCM with required properties. © 2016, Springer-Verlag Wien.

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Держатели документа:
Institute of Problems of Chemical Physics RAS, Chernogolovka, Russian Federation
All-Russian Scientific Research Institute of Aviation Materials, Moscow, Russian Federation
Kirensky Institute of Physics SB RAS, Krasnoyarsk, Russian Federation
Institute of Chemistry and Chemical Technology SB RAS, Krasnoyarsk, Russian Federation
Science Center in Chernogolovka of the Russian Academy of Sciences, Chernogolovka, Russian Federation

Доп.точки доступа:
Bouznik, V. M.; Morozov, E. V.; Морозов, Евгений Владимирович; Avilova, I. A.; Volkov, V. I.
}
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16.

    Preparation and characterization of colloidal copper xanthate nanoparticles / Y. Mikhlin [et al.] // New J. Chem. - 2016. - Vol. 40, Is. 4. - P. 3059-3065, DOI 10.1039/c6nj00098c. - Cited References:50. - This research was supported by the Russian Science Foundation grant 14-17-00280. We thank Dr Roberto Felix Duarte (HZB) and bilateral program "German-Russian laboratory at BESSY II" for assistance with the X-ray absorption experiments. . - ISSN 1144-0546. - ISSN 1369-9261
   Перевод заглавия: Получение и исследование коллоидных наночастиц ксантогената меди

РУБ Chemistry, Multidisciplinary
Рубрики:
X-ray-absorption
   Self-assembled monolayers
   Sulfide nanoparticles
   Electronic-structure
   Waste-water
   Complexes
   Flotation
   Spectroscopy
   Adsorption
   Oxidation
Аннотация: Despite the important role of metal xanthates in a number of industrial processes and emerging applications, no attempts have been made to prepare the metal xanthate nanoparticles and to study colloidal solutions of insoluble heavy metal xanthates. Here, we examined the formation of colloidal copper xanthate particles during the reactions of aqueous solutions of cupric sulfate and various potassium xanthates, which occur in flotation and water treatment slurries and can be used to manufacture nanoparticles for materials science (e.g., as precursors for copper sulfide nanoparticles and biomedicine). The products were characterized using UV-vis absorption, dynamic light scattering, zeta potential measurements, transmission electron microscopy (TEM), electron diffraction, Fourier transform infrared spectroscopy, thermogravimetry, X-ray photoelectron spectroscopy, and X-ray absorption spectroscopy (XANES). Colloidal copper xanthates with compositions of ROCSSCu (R = ethyl, isopropyl, butyl, isobutyl, and amyl groups), disordered structures and average diameters of 20–80 nm easily formed and aggregated and were stable for at least several hours, especially if excessive xanthate was used. The hydrodynamic diameters of the nanoparticles were smaller at lower temperatures. Dixanthogens, which were produced in the reactions along with ROCSSCu, seemed to promote nanoparticle aggregation and precipitated with the copper xanthate, affecting their thermal decomposition. The TEM micrographs and S K- and Cu K-edge XANES spectra revealed core/shell particle morphologies, likely with Cu(I) bonded to four S atoms in the core and reduced copper coordination in the shell.

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Держатели документа:
Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Akad 50-24, Krasnoyarsk 6600036, Russia.
Siberian Fed Univ, Svobodny Pr 79, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Akad 50-38, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Mikhlin, Y. L.; Михлин, Юрий Леонидович; Vorobyev, S.; Saikova, S. V.; Сайкова, С. В.; Tomashevich, Y.; Fetisova, O.; Kozlova, S.; Zharkov, S. M.; Жарков, Сергей Михайлович; Russian Science Foundation [14-17-00280]
}
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17.

Aver'yanov, E. M.
Local field anisotropy in Langmuir-Blodgett films of cadmium arachidate / E. M. Aver'yanov // Phys. Solid State. - 2011. - Vol. 53, Is. 12. - P. 2492-2494, DOI 10.1134/S1063783411120031. - Cited References: 9 . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
SPECTROSCOPY
Аннотация: Lorentz tensor and local field tensor components for uniaxial Langmuir-Blodgett films of cadmium arachidate from 3 to 100 nm thick on silver, polymethyl methacrylate, and glass substrates have been experimentally determined using the data on the film refractive index dispersion in the visible range. The constraints from below on the mean value and anisotropy of the molecular polarizability caused by the intermolecular interactions in the film have been established.

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Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Аверьянов, Евгений Михайлович
}
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18.

Antiferromagnetic Resonance and Dielectric Properties of Rare-earth Ferroborates in the Submillimeter Frequency Range / A. M. Kuz'menko [et al.] // J. Exp. Theor. Phys. - 2011. - Vol. 113, Is. 1. - P. 113-120, DOI 10.1134/S106377611105013X. - Cited References: 27. - This work was supported by the Russian Foundation for Basic Research, project no. 10-02-00846. . - ISSN 1063-7761

РУБ Physics, Multidisciplinary
Рубрики:
GDFE3(BO3)(4)
SPECTROSCOPY
CRYSTAL
Кл.слова (ненормированные):
Antiferromagnetic resonance -- Basic parameters -- Effective anisotropy constant -- Ferroborates -- Ferroics -- Ferromagnetic orderings -- Frequency ranges -- Magnetic interactions -- Magnetoresonance -- Millimeter frequency range -- Rare earth ions -- Submillimeters -- Antiferromagnetic materials -- Crystallography -- Erbium -- Europium -- Ferromagnetic resonance -- Ion exchange -- Magnetic anisotropy -- Magnetic devices -- Magnetic structure -- Permittivity -- Resonance -- Antiferromagnetism
Аннотация: The magnetoresonance and dielectric properties of a number of crystals of a new family of multiferroics, namely, rare-earth ferroborates RFe(3)(BO(3))(4) (R = Y, Eu, Pr, Tb, Tb(0.25)Er(0.75)), are studied in the submillimeter frequency range (nu = 3-20 cm(-1)). Ferroborates with R = Y, Tb, and Eu exhibit permittivity jumps at temperatures of 375, 198, and 58 K, respectively, which are caused by the R32 -> P3(1)2(1) phase transition. Antiferromagnetic resonance (AFMR) modes in the subsystem of Fe(3+) ions are detected in the range of antiferromagnetic ordering (T < T(N) = 30-40 K) in all ferroborates that have either an easy-plane (Y, Eu) or easy-axis (Pr, Tb, Tb(0.25)Er(0.75)) magnetic structure. The AFMR frequencies are found to depend strongly on the magnetic anisotropy of a rare-earth ion and its exchange interaction with the Fe subsystem, which determine the type of magnetic structure and the sign and magnitude of an effective anisotropy constant. The basic parameters of the magnetic interactions in these ferroborates are found, and the magnetoelectric contribution to AFMR is analyzed.

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Держатели документа:
[Kuz'menko, A. M.
Mukhin, A. A.
Ivanov, V. Yu.
Lebedev, S. P.] Russian Acad Sci, Inst Gen Phys, Moscow 119991, Russia
[Kadomtseva, A. M.] Moscow MV Lomonosov State Univ, Moscow 119991, Russia
[Bezmaternykh, L. N.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
Institute of General Physics, Russian Academy of Sciences, ul. Vavilova 38, Moscow, 119991, Russian Federation
Moscow State University, Moscow, 119991, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Kuz'menko, A. M.; Mukhin, A. A.; Ivanov, V. Y.; Kadomtseva, A. M.; Lebedev, S. P.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич
}
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19.

Optical spectra, crystal-field parameters, and magnetic susceptibility of multiferroic NdFe3(BO3)(4) / M. N. Popova [et al.] // Phys. Rev. B. - 2007. - Vol. 75, Is. 22. - Ст. 224435, DOI 10.1103/PhysRevB.75.224435. - Cited References: 22 . - ISSN 1098-0121

РУБ Physics, Condensed Matter
Рубрики:
IRON BORATE GDFE3(BO3)(4)
   CRYSTALLIZATION
   SPECTROSCOPY
   LASER
   ND3+
Аннотация: We report high-resolution optical absorption spectra for NdFe3(BO3)(4) trigonal single crystal, which is known to exhibit a giant magnetoelectric effect below the temperature of magnetic ordering T-N=33 K. The analysis of the temperature-dependent polarized spectra reveals the energies and, in some cases, symmetries and exchange splittings of Nd3+ 84 Kramers doublets. We perform crystal-field calculations starting from the exchange-charge model, obtain a set of six real crystal-field parameters, and calculate wave functions and magnetic g factors. In particular, the values g(perpendicular to)=2.385 and g(parallel to)=1.376 were found for the Nd3+ ground-state doublet. We obtain B-loc=7.88 T and parallel to J(FN)parallel to=0.48 K for the values of the local effective magnetic field at liquid-helium temperatures at the Nd3+ site and the Nd-Fe exchange integral, respectively, using the experimentally measured Nd3+ ground-state splitting of 8.8 cm(-1). To check the reliability of our set of crystal-field parameters, we model the magnetic susceptibility data from literature. A dimer containing two nearest-neighbor iron ions in the spiral chain is considered to partly account for quasi-one-dimensional properties of iron borates, and then the mean-field approximation is used. The results of calculations with the exchange parameters for Fe3+ ions J(nn)=-6.25 K (intrachain interactions) and J(nnn)=-1.92 K (interchain interactions) obtained from fitting agree well with the experimental data.

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Держатели документа:
Russian Acad Sci, Inst Spect, Troitsk 142190, Moscow Region, Russia
Kazan VI Lenin State Univ, Kazan 420008, Russia
Ecole Natl Super Chim Paris, CNRS, UMR7574, Lab Chim Appl & Etat Solide, F-75231 Paris, France
Moscow MV Lomonosov State Univ, Fac Phys, Moscow 119992, Russia
RAS, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
Institute of Spectroscopy, Russian Academy of Sciences, 142190 Troitsk, Russian Federation
Kazan State University, 420008 Kazan, Russian Federation
Laboratoire de Chimie Applique'e de l'E Tat Solide, CNRS-UMR7574, ENSCP, 11, Rue Pierre et Marie Curie, F-75231 Paris Cedex 05, France
Physics Faculty, Moscow State University, 119992 Moscow, Russian Federation
L.V. Kirensky Institute of Physics, Siberian Branch of RAS, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Popova, M. N.; Chukalina, E. P.; Stanislavchuk, T. N.; Malkin, B. Z.; Zakirov, A. R.; Antic-Fidancev, E.; Popova, E. A.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Temerov, V. L.; Темеров, Владислав Леонидович
}
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20.

Magnetic circular dichroism and optical absorption in TmAl3(BO3)(4) / A. V. Malakhovskii [et al.] // Phys. Solid State. - 2007. - Vol. 49, Is. 1. - P. 34-38, DOI 10.1134/S1063783407010076. - Cited References: 19 . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
SINGLE-CRYSTALS
   SPECTROSCOPY
   TRANSITIONS
   HUNTITE
   GROWTH
Аннотация: The polarized spectra of absorption and magnetic circular dichroism in a TmAl3(BO3)(4) single crystal are studied in the re-ion of H-3(6) - F-3(4), H-3(6) - F-3(3),and H-3(3) - F-3(2) electronic transitions in e Tm3+ ion. The structure of the spectra is interpreted qualitatively. It is shown that the magnetic circular dichroism of the H-3(6) - F-3(4) transition is determined by the contribution from the splitting of the ground state, whereas the magnetic circular dichroism of the H-3(6) - F-3(3) transition is governed by the contribution from the splitting of an excited state in a trigonal crystal field.

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Держатели документа:
Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Malakhovskii, A. V.; Малаховский, Александр Валентинович; Sokolov, A. E.; Соколов, Алексей Эдуардович; Sukhachev, A. L.; Сухачев, Александр Леонидович; Temerov, V. L.; Темеров, Владислав Леонидович; Stolbovaya, N. A.; Edelman, I. S.; Эдельман, Ирина Самсоновна
}
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