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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Соколов, Алексей Эдуардович, Овчинников, Сергей Геннадьевич, Заблуда, Владимир Николаевич, Кальсин А. М., Зубавичус Я. В.
Заглавие : Магнитный круговой дихроизм и природа ферромагнетизма в коллоидных наночастицах золота
Место публикации : Письма в Журн. эксперим. и теор. физ. - 2013. - Т. 97, Вып. 2. - С. 104-107. - DOI 10.7868/S0370274X13020070
Аннотация: Измерены спектры оптического поглощения и магнитного кругового дихроизма (МКД) в интервале длин волн 350-1150 нм для серии коллоидных растворов наночастиц Au со средним размером 6.0 нм с различной степенью хиральности тиолятного покрытия. Вид спектров поглощения и МКД свидетельствует о дипольном характере межзонных переходов 5d-6(sp)-орбиталей. Отсутствие зависимости (в пределах погрешности эксперимента) МКД от вида покрытия позволяет исключить гипотезу об орбитальной природе магнетизма. Делается вывод о преобладающей роли спиновой поляризации в формировании магнетизма наночастиц золота с тиолятным покрытием.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Достовалов А. В., Носков Ф. М., Жигалов, Виктор Степанович, Нявро А. В.
Заглавие : Влияние охлаждения на возникновение намагниченности в никелиде титана
Место публикации : Изв. Алт. гос. ун-та. - 2021. - № 1 (117). - С. 17-20. - ISSN 1561-9443 (ISSN), DOI 10.14258/izvasu(2021)1-02. - ISSN 1561-9451 (eISSN)
Примечания : Библиогр.: 15
Аннотация: Вопрос возникновения намагниченности в сплавах системы никель-титан до сих пор изучен недостаточно. Наши ранние работы показали возможность возникновения намагниченности при многократных циклах прямых и обратных мартенситных переходах в сплаве Ni51Ti49, а также после деформации этого сплава растяжением до разрыва. Представленная работа посвящена выявлению эффекта намагниченности в образцах сплава Ni51Ti49 в результате их однократного охлаждения в жидком азоте, а также исчезновению намагниченности при нагревании образцов до комнатной температуры. С помощью индукционного петлескопа выявлено, что непосредственно после охлаждения образец имел высокую намагниченность. По мере нагревания образца петли гистерезиса изменяются, приобретая меньший наклон к горизонтальной оси, что свидетельствует об уменьшении магнитной индукции практически до нуля с повышением температуры до комнатной. Причину появления и исчезновения намагниченности можно связать с микродеформационными процессами, проходящими при охлаждении и нагревании образцов, связанными с прямым и обратным мартенситными переходами.The occurrence of magnetization in alloys of the nickel-titanium system is still studied insufficiently. Our early work showed the possibility of magnetization arising during multiple cycles of forward and reverse martensitic transitions in the Ni51Ti49 alloy, as well as after deformation of this alloy by tensile stress to rupture. The purpose of this paper is devoted to revealing the effect of magnetization in samples of the Ni51Ti49 alloy as a result of their single cooling in liquid nitrogen, as well as the disappearance of magnetization when the samples are heated to room temperature. Using an induction hysteresigraph it is found out that the sample has a high magnetization immediately after cooling. As the sample is heated, the hysteresis loops change, acquiring a smaller inclination to the horizontal axis. It indicates a decrease in the magnetic induction to almost zero as the temperature rises to room temperature. The reason for the occurrence and disappearance of magnetization can be associated with micro-deformation processes related to forward and reverse martensitic transitions during cooling and heating of the samples.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Petrakovskii G. A., Sablina K. A., Velikanov D. A., Vorotynov A. M., Volkov N. V., Bovina A. F.
Заглавие : Weak ferromagnetism in copper metaborate CuB2O4
Место публикации : Phys. Solid State: AMER INST PHYSICS, 1999. - Vol. 41, Is. 7. - P1157-1161. - ISSN 1063-7834, DOI 10.1134/1.1130957
Примечания : Cited References: 10
Предметные рубрики: SUSCEPTIBILITY
Аннотация: CuB2O4 single crystals have been grown and their magnetic and resonance properties have been investigated for the first time. The temperature dependence of the susceptibility was found to contain features at T = 21 and 10 K. The CuB2O4 single crystal transformed at T = 21 K to a weakly ferromagnetic state. The sharp drop in susceptibility at T 10 K is caused by a transition of the magnetic system of CuB2O4 to an antiferromagnetic state. The effective magnetic moment of the Cu2+ ion, determined from the high-temperature part of the magnetic susceptibility, is 1.77 mu(B). The room-temperature g factors are, respectively, 2.170 and 2.133 for magnetic field parallel and perpendicular to the c axis of the crystal. The antiferromagnetic resonance parameters in the weakly ferromagnetic and antiferromagnetic phases were measured. (C) 1999 American Institute of Physics. [S1063-7834(99)02907-X].
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : FEDOSEEVA N. V., VELIKANOVA T. A.
Заглавие : WEAK FERROMAGNETISM IN ALPHA-KMNCL3
Место публикации : Fiz. Tverd. Tela: MEZHDUNARODNAYA KNIGA, 1989. - Vol. 31, Is. 2. - P224-225. - ISSN 0367-3294
Примечания : Cited References: 5
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Fedoseeva N. V., Aplesnin S. S., Nikolaev E. M., Perepelitsa A. P.
Заглавие : Weak ferromagnetism and magnetic-behavior of (CH3NH3)2MNCL4 quasidimetric antiferromagnetic
Место публикации : Fiz. Tverd. Tela: MEZHDUNARODNAYA KNIGA, 1994. - Vol. 36, Is. 9. - P.2609-2617. - ISSN 0367-3294
Примечания : Cited References: 8
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ovchinnikov S. G., Rudenko V. V., Tugarinov V. I.
Заглавие : Weak ferromagnetism along the triad axis of FeBO3 crystals
Место публикации : Phys. Solid State: Maik Nauka-Interperiodica Publishing, 2016. - Vol. 58, Is. 10. - P.1995-1998. - ISSN 10637834 (ISSN), DOI 10.1134/S1063783416100279
Примечания : Cited References: 14
Аннотация: Weak ferromagnetic moment along the triad axis of FeBO3 crystals has been calculated on the basis of the single-ion model taking into account the cubic invariant of the crystal field in the spin Hamiltonian. © 2016, Pleiades Publishing, Ltd.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ovchinnikov S. G., Rudenko V. V., Vorotynov A. M.
Заглавие : Weak Ferromagnetism along the Triad Axis and the Basal Anisotropy Caused by the Dzyaloshinskii-Moriya Interaction and the Cubic Electric Field of the FeBO3 Crystal
Место публикации : J. Exp. Theor. Phys. - 2019. - Vol. 128, Is. 3. - P.443-449. - ISSN 1063-7761, DOI 10.1134/S1063776119020110. - ISSN 1090-6509(eISSN)
Примечания : Cited References: 18
Предметные рубрики: MN2+
EPR
Аннотация: Based on the spin Hamiltonian and taking into account the cubic invariant of the crystal field and the Dzyaloshinskii-Moriya interaction, the weak ferromagnetic moment along the triad axis and the basal anisotropy of FeBO3 crystals are calculated in the approximation of second-order perturbation theory.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ovchinnikov S. G., Rudenko V. V., Vorotynov A. M.
Заглавие : Weak ferromagnetism along the third-order axis of the FeBO3 crystals caused by Fe2+ impurity ions
Место публикации : J. Magn. Magn. Mater. - 2018. - Vol. 454. - P.139-143. - ISSN 03048853 (ISSN), DOI 10.1016/j.jmmm.2018.01.037
Примечания : Cited References: 22
Ключевые слова (''Своб.индексиров.''): week ferromagnetism--magnetic anisotropy--impurity
Аннотация: Using the single-ion approximation, the weak ferromagnetic moment σZ(Fe2+) along the third-order axis of FeBO3 crystals, which is caused by the contribution of Fe2+ ions, has been investigated in the framework of the model Fe2+ impurity ion – vacancy. The extreme low-temperature behavior of the total magnetic moment due to the strong dependence of the Fe2+ion contribution is predicted.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zenkov A. A., Rudenko V. V., Fedorov Y. M.
Заглавие : Weak ferromagnetism along the 3rd order of FeBo(3)
Место публикации : Fiz. Tverd. Tela: MEZHDUNARODNAYA KNIGA, 1996. - Vol. 38, Is. 2. - P.659-663. - ISSN 0367-3294
Примечания : Cited References: 15
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ovchinnikov S. G., Rudenko V. V., Kazak N. V., Edelman I. S., Gavrichkov V. A.
Заглавие : Weak antiferromagnet iron borate FeBO3. classical object for magnetism and the state of the art
Коллективы : Russian Science FoundationRussian Science Foundation (RSF) [18-12-00022]
Место публикации : J. Exp. Theor. Phys. - 2020. - Vol. 131, Is. 1. - P.177-188. - ISSN 1063-7761, DOI 10.1134/S106377612007016X. - ISSN 1090-6509(eISSN)
Примечания : Cited References: 74. - This work was supported by the Russian Science Foundation, project no. 18-12-00022
Предметные рубрики: ELECTRONIC-STRUCTURE
TRANSITION
RESONANCE
FERROMAGNETISM
DEPENDENCE
Аннотация: The simple lattice and magnetic structure, the high Neel temperature, the narrow antiferromagnetic resonance line of FeBO3, and the narrow electron paramagnetic resonance line of its isostructural diamagnetic analogs MBO3:Fe3+(M = Ga, In, Sc, Lu) make iron borate unique for investigations and applications. Iron borate is a model crystal for numerous experimental and theoretical studies, including spin crossovers and metallization at megabar pressures and many-electron effects in optics and X-ray spectroscopy. The recent works dealing with the investigation of the properties of FeBO(3)are reviewed.
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11.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Samoshkina Yu. E., Edel'man I. S., Petrov D. A., Chou, Hsiung, Ovchinnikov S. G.
Заглавие : Visible MCD spectroscopy and nature of room temperature ferromagnetism in hydrogenated Сo - and (Co+Al) - doped ZnO films
Коллективы : Japanese-Mediterranean Workshop on Applied Electromagnetic Engineering for Magnetic, Superconducting, Multifunctional and Nanomaterials
Место публикации : Book of abstracts of The Eleventh Japanese-Mediterranean Workshop on Applied Electromagnetic Engineering for Magnetic, Superconducting, Multifunctional and Nanomaterials (JAPMED’11). - 2019. - P.121-122
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kuklin A. V., Kuzubov A. A., Kovaleva E. A., Mikhaleva N. S., Tomilin F. N., Lee H., Avramov P. V.
Заглавие : Two-dimensional hexagonal CrN with promising magnetic and optical properties: A theoretical prediction
Место публикации : Nanoscale: Royal Society of Chemistry, 2017. - Vol. 9, Is. 2. - P.621-630. - ISSN 20403364 (ISSN), DOI 10.1039/c6nr07790k
Примечания : Cited References: 76. - We acknowledge the Siberian Supercomputer Center (SSCC) of SB RAS, Novosibirsk; the Institute of Computational Modeling of SB RAS, Krasnoyarsk; the Joint Supercomputer Center of RAS, Moscow; and the ICC of Novosibirsk State University for providing the computing resources. This work was supported by the government contract of the Ministry of Education and Science of the Russian Federation to Siberian Federal University (Grant No. 16.1500.2014/K). P. V. A. acknowledges the Kyungpook National University Research Fund, 2014. N. S. M. acknowledges the Russian Foundation for Basic Research (RFBR 16-32-60003 mol_a_dk).
Ключевые слова (''Своб.индексиров.''): boron nitride--calculations--energy gap--ferromagnetic materials--ferromagnetism--graphene--magnetism--metals--transition metals--transparency--dielectric functions--ferromagnetic orderings--first-principles calculation--half-metallic properties--magnetic and optical properties--optical transparency--spintronics application--transition metal dichalcogenides--optical properties
Аннотация: Half-metallic ferromagnetic materials with planar forms are promising for spintronics applications. A wide range of 2D lattices like graphene, h-BN, transition metal dichalcogenides, etc. are non-magnetic or weakly magnetic. Using first principles calculations, the existence of graphene-like hexagonal chromium nitride (h-CrN) with an almost flat atomically thin structure is predicted. We find that freestanding h-CrN has a 100% spin-polarized half-metallic nature with possible ferromagnetic ordering and a high rate of optical transparency. As a possible method for stabilization and synthesis, deposition of h-CrN on 2D MoSe2 or on MoS2 is proposed. The formation of composites retains the half-metallic properties and leads to the reduction of spin-down band gaps to 1.43 and 1.71 eV for energetically favorable h-CrN/MoSe2 and h-CrN/MoS2 configurations, respectively. Calculation of the dielectric functions of h-CrN, h-CrN/MoSe2 and h-CrN/MoS2 exhibit the high transparency of all three low-dimensional nanomaterials. The honeycomb CrN may be considered as a promising fundamental 2D material for a variety of potential applications of critical importance. © The Royal Society of Chemistry 2017.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Ryabinkina L. I., Romanova O. B., Velikanov D. A., Balaev A. D., Balaev D. A., Yanushkevich K. I., Galyas A. I., Demidenko O. F., Bandurina O. N.
Заглавие : Transport properties and ferromagnetism of Co(x)Mn(1-x)Ssulfides
Разночтения заглавия :авие SCOPUS: Transport properties and ferromagnetism of Co x Mn 1 - X S sulfides
Место публикации : J. Exp. Theor. Phys.: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2008. - Vol. 106, Is. 4. - P765-772. - ISSN 1063-7761, DOI 10.1134/S1063776108040158
Примечания : Cited References: 39
Предметные рубрики: GIANT VOLUME MAGNETOSTRICTION
COLOSSAL MAGNETORESISTANCE
MAGNETIC SEMICONDUCTORS
ELECTRICAL-PROPERTIES
ROOM-TEMPERATURE
ALPHA-MNS
SPINTRONICS
TRANSITION
FEXMN1-XS
FIELDS
Ключевые слова (''Своб.индексиров.''): coulomb interactions--current voltage characteristics--electromotive force--ferromagnetism--magnetic susceptibility--magnetization--thermoelectricity--transport properties--charge susceptibility--external magnetic fields--temperature intervals--thermoelectromotive force--cobalt compounds
Аннотация: We have studied the resistivity and thermoelectromotive force (thermo emf) in a temperature range of T = 80-1000 K, the magnetic susceptibility and magnetization in a temperature range of T= 4.2-300 K at an external magnetic field of up to 70 kOe, and the structural characteristics of CoxMn1 - S-x sulfides (0
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Martynov S. N.
Заглавие : Transition between incommensurate phases accompanied by reversal of the magnetic structure vector in CuB2O4
Место публикации : Phys. Solid State: AMER INST PHYSICS, 2005. - Vol. 47, Is. 4. - P678-683. - ISSN 1063-7834, DOI 10.1134/1.1913980
Примечания : Cited References: 17
Предметные рубрики: COPPER METABORATE CUB2O4
WEAK FERROMAGNETISM
10 K
Аннотация: The incommensurate magnetic state of copper metaborate CuB2O4 is studied in the temperature range 2 T 12 K. Competition between frustrated and non-frustrated antisymmetric exchange interactions is shown to cause the magnetic structure vector to reverse at T
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sun S.-J., Hsu, Hua-Shu, Ovchinnikov S. G., Chen G.-L.
Заглавие : Theoretical investigation of magnetic properties in interfaces of magnetic nanoparticles and amorphous carbons
Место публикации : J. Magn. Magn. Mater.: Elsevier, 2017. - Vol. 432. - P.102-105. - ISSN 03048853 (ISSN), DOI 10.1016/j.jmmm.2017.02.001
Примечания : Cited References: 21. - We would like to thank the Ministry of Science and Technology, Taiwan, for the Grant No. MOST 104-2112-M-390-001 and 104-2923-M-390-001-MY3 (Shih-Jye Sun). The work is supported also by the President of Russia program of the leading scientific schools, Grant NSh-7559.2016.2.
Ключевые слова (''Своб.индексиров.''): antiferroelectricity--antiferromagnetism--ferromagnetism--molecular dynamics--nanomagnetics--nanoparticles--spin waves--antiferro-magnetic interactions--antiferromagnetics--kondo interactions--magnetic nano-particles--molecular dynamics simulations--spinwave excitation--theoretical investigations--theoretical modeling--amorphous carbon
Аннотация: Based on the experimental finding of the exchange bias in amorphous carbon samples with embedded Co nanoparticles and on the graphited character of the amorphous carbon interface confirmed by molecular dynamics simulations we have proposed the interface of graphited carbon to be antiferromagnetic. A theoretical model, which comprises the Kondo interactions in the interfaces of Co nanoparticles and the induced antiferromagnetic interactions in the graphited carbons, is employed to evaluate the ferromagnetism of the interfaces of Co nanoparticles. We have shown that the ferromagnetism of interfaces of Co nanoparticles will be enhanced by the increase of antiferromagnetic interaction as well as the increase of electron density in the graphited carbons. In particular, we found that the antiferromagnetic interactions in graphited carbons will change the spin-wave excitation in interfaces of Co nanoparticles from the quasiacoustic mode to the quasioptical one. © 2017 Elsevier B.V.
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16.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Sandalov I. S., Zamkova N. G., Zhandun V. S., Ovchinnikov S. G.
Заглавие : The microscopic origin of ferromagnetism in Fe silicides : Invited
Коллективы : Federal Research Center KSC SB RAS, Kirensky Institute of Physics, Siberian Federal Univercity, International Workshop on Actual Problems of Condensed Matter Physics
Место публикации : Int. workshop on actual probl. of cond. matt. phys.: Program. Book of abstracts/ Fed. Res. Center KSC SB RAS, Kirensky Inst. of phys., Sib. Fed. Univ. - Krasnoyarsk, 2017. - P.16
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Martynov S. N.
Заглавие : The incommensurate magnetic structure of a tetragonal antiferromagnet with antisymmetric exchange
Место публикации : J. Exp. Theor. Phys. - 2009. - Vol. 109, Is. 6. - P.979-988. - ISSN 1063-7761, DOI 10.1134/S1063776109120097
Примечания : Cited References: 34
Предметные рубрики: FLUCTUATION-INDUCED PHASE
FIELD-INDUCED GAP
COPPER METABORATE
WEAK FERROMAGNETISM
SOLITON LATTICE
SPIN-WAVES
CUB2O4
BA2CUGE2O7
CSCUCL3
CHAINS
Ключевые слова (''Своб.индексиров.''): anti-symmetric--antiferromagnetic sublattices--antiferromagnets--antisymmetric exchange--exchange bonds--ferromagnetic component--ferromagnetic moments--ginzburg-landau functional--incommensurate magnetic structures--mean field approximation--modulation vectors--polarization planes--polarization vectors--symmetry groups--antiferromagnetic materials--antiferromagnetism--crystal orientation--crystal symmetry--ferromagnetic materials--ferromagnetism--magnetic devices--magnetic structure--modulation--polarization--vector spaces--vectors--crystallography
Аннотация: Analysis of the incommensurate magnetic structure that emerges for two coexisting types of the antisymmetric Dzyaloshinski-Moriya exchange interaction (the weakly ferromagnetic component of vector D along the tetragonal axis and the helicoidal component distributed in the tetragonal plane) is carried out for the first time for a tetragonal antiferromagnet. The helicoidal component for each pair of interacting spins has a 2D distribution; its direction in the tetragonal plane depends on the direction of the exchange bond in each pair. The Lifshits invariant of the Ginzburg-Landau functional is obtained, which is responsible for the formation of an incommensurate magnetic structure for such a distribution. It is shown in the mean field approximation that the incommensurate magnetic structure that forms in this case is a nonlinear double helicoid with a modulation vector lying in the tetragonal plane and with a varying angle between the polarization planes of quasi-antiferromagnetic sublattices. The ground state of the magnet is degenerate in the orientation of the modulation vector in the tetragonal plane. The rate of variation in the orientations of moments in the polarization planes passing through the tetragonal axis is controlled by the angle between the directions of the moments and the tetragonal axis. The local weakly ferromagnetic moment remaining in the polarization plane varies in magnitude and sign. The relation between the orientations of the modulation and polarization vectors is derived for the cases of simple and inversion tetragonal axes in the space symmetry group of the crystal.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bondarenko G. V., Ovchinnikov S. G., Rudenko V. V., Sosnin V. M., Tugarinov V. I., Vorotynov A. M.
Заглавие : The generalized method of quantitative description of the uniaxial anisotropy in weak ferromagnet rhombohedral calcite type structure crystals with S-state ions
Место публикации : J. Magn. Magn. Mater. - 2013. - Vol. 335. - P.90-96. - ISSN 0304-8853, DOI 10.1016/j.jmmm.2013.01.037
Примечания : Cited References: 35
Ключевые слова (''Своб.индексиров.''): weak ferromagnetism--magnetic anisotropy--impurity
Аннотация: The method for investigation of the uniaxial and hexagonal anisotropies in weakly ferromagnetic rhombohedral FeBO3 crystals with the Fe2þ magnetic impurity with the use of the single-ion and pair approximation has been developed. In the framework of this method, a quantitative discrepancy between theoretical and experimental data on a uniaxial ﬁeld has been eliminated. The energy contributions to the hexagonal anisotropy that are caused by the Dzyaloshinsky–Moriya interaction, the crystal ﬁeld of Fe3þ ions and the temperature dependence of this anisotropy were analytically treated. The experimental temperature dependence of the hexagonal anisotropy of FeBO3 crystals is explained. It is shown that the compensation point and the typical temperature dependence of the hexagonal anisotropy result from the competition of the contributions of Fe3þ and Fe2þ ions. It is shown that respective considerable contributions to the anisotropy of Fe3þ and Fe2þ ions are made by the cubic symmetry and the uniaxial symmetry of the exchange ‘‘single-ion’’ type. The anisotropy constants for FeBO3 crystal was obtained by using the described results. It was shown, that for the calcite type structure crystals (iron borate and manganese carbonate) with S-state ions, the single ion and pair models (which previously raised doubts in their validity and accuracy) describe the experimental data good enough.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ovchinnikov S. G., Zabluda V. N.
Заглавие : The energy band structure and optical spectra of FeBO3 calculated with allowance for strong electron correlations
Место публикации : J. Exp. Theor. Phys.: AMER INST PHYSICS, 2004. - Vol. 98, Is. 1. - P135-143. - ISSN 1063-7761, DOI 10.1134/1.1648107
Примечания : Cited References: 32. - This study was supported by the Russian Foundation for Basic Research (project no. 03-02-16286) and by the “Strongly Correlated Electrons” Program of the Department of Physical Sciences of the Russian Academy of Sciences
Предметные рубрики: PHASE-TRANSITION
HIGH-PRESSURE
FERROMAGNETISM
MODEL
Ключевые слова (''Своб.индексиров.''): atomic physics--band structure--charge transfer--excitons--green's function--light absorption--dielectric gap--energy band structure--lehmann spectral representation--optical spectra--iron compounds
Аннотация: A model of the energy band structure of iron borate (FeBO3) is proposed that combines a one-electron description of the sp states of boron and oxygen with a many-electron description of the d states of iron. The Green functions of d electrons are calculated using the exact Lehmann spectral representation. The energies of the d-type quasiparticles are calculated using terms of the d(4) , d(5) , and d(6) electron configurations. The optical absorption spectrum of FeBO3 is determined by local excitons and by the electron excitations with charge transfer. The latter excitations control the nature of the dielectric gap in FeBO3 crystals. The model parameters are determined from a comparison to the exciton energies. The density of single-particle states in FeBO3 is calculated. The main bands in the calculated optical absorption spectrum agree well with experimental data for energies up to 3 eV. (C) 2004 MAIK "Nauka/Interperiodica".
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ushakov A. V., Karpov I. V., Fedorov L. Y., Demin V. G., Goncharova E. A., Shaihadinov A. A., Zeer G. M., Zharkov S. M.
Заглавие : The effect of microstructural features on the ferromagnetism of nickel oxide nanoparticles synthesized in a low-pressure arc plasma
Место публикации : Physica E. - 2020. - Vol. 124. - Ст.114352. - ISSN 13869477 (ISSN), DOI 10.1016/j.physe.2020.114352
Примечания : Cited References: 31. - The work was performed with a support of the grant of the Russian Science Foundation (Project No. 16-19-10054 ). The electron microscopy investigations were conducted in the SFU Joint Scientific Center supported by the State assignment (#FSRZ-2020-0011) of the Ministry of Science and Higher Education of the Russian Federation
Аннотация: Nickel oxide nanoparticles were first synthesized by sputtering high-purity nickel in an oxygen plasma of a low-pressure arc discharge. The structure, morphology, and optical and magnetic properties of NiO nanoparticles were studied by XRD, TEM, FTIR, UV-VIS, and VSM. TEM images showed that the obtained NiO nanoparticles have a narrow particle size distribution and an average particle size of 12 nm. The XRD results and the processing of diffractograms by the Rietveld method showed that the obtained nanoparticles have a face-centered cubic lattice with an average particle size of 13 nm. With decreasing temperature, residual stresses increase and peaks corresponding to the superstructure appear. The band gap of NiO was determined from the optical absorption spectrum and amounted to 3.21 eV. Magnetic measurements showed that, at temperatures of 200 and 300 K, NiO nanoparticles, unlike bulk particles, exhibit ferromagnetic behavior, and at 5 K a magnetic hysteresis loop appears. Based on the studies, a dendritic model of the nanoparticle microstructure is proposed.
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