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1.


    Ignatchenko, V. A.
    Effect of the correlation properties of one- and three-dimensional inhomogeneities on the high-frequency magnetic susceptibility of sinusoidal superlattices / V. A. Ignatchenko, Y. I. Mankov // Phys. Solid State. - 2005. - Vol. 47, Is. 3. - P. 587-594, DOI 10.1134/1.1884725. - Cited References: 29 . - ISSN 1063-7834
РУБ Physics, Condensed Matter
Рубрики:
PERIODIC MULTILAYERS
   WAVE SPECTRUM

   SPIN-WAVES

   LOCALIZATION

   SYSTEMS

   DISORDER

Аннотация: The effect of one-(1D) and three-dimensional (3D) inhomogeneities on the high-frequency magnetic susceptibility at the boundary of the first Brillouin zone of a ferromagnetic superlattice is studied. The study is performed with an earlier developed method of random spatial modulation (RSM) of the superlattice period. In this method, structural inhomogeneities are described in terms of the random-phase model, in which the phase depends on three coordinates in the general case. The frequency spacing Delta v(m) between two peaks in the imaginary part of the averaged Green's function, which characterizes the gap width in the frequency spectrum at the boundary of the Brillouin zone, is calculated as a function of both the root-mean-square fluctuations gamma(i) and the correlation wavenumbers eta(i) of phase inhomogeneities (i = 1 and 3 for 1D and 3D inhomogeneities, respectively). The function Delta v(m)(gamma(1), eta(1)) for 1D inhomogeneities is shown to be symmetric with respect to inter- changing the variables gamma(1)(2) and eta(1), whereas the function Delta v(m)(gamma(3), eta(3)) for 3D inhomogeneities is strongly asym- metric with respect to interchanging gamma(3)(2) eta(3). This effect is associated with the difference in form between the correlation functions of 1D and 3D inhomogeneities and can be used to determine the dimensionality of inhomogeneities from the results of spectral studies of such superlattices. (c) 2005 Pleiades Publishing, Inc.

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Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Siberian Div, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, Akademgorodok, 660036, Russian Federation

Доп.точки доступа:
Mankov, Y. I.; Игнатченко, Вальтер Алексеевич
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2.


    Mel'nikova, S. V.
    Phase transitions in the oxyfluoride (NH4)(3)NbOF6 / S. V. Mel'nikova, N. M. Laptash, A. L. Zhogal' // Phys. Solid State. - 2007. - Vol. 49, Is. 5. - P. 958-962, DOI 10.1134/S1063783407050253. - Cited References: 11 . - ISSN 1063-7834
РУБ Physics, Condensed Matter
Рубрики:
RAY-DIFFRACTION INVESTIGATIONS
   DISTORTED PHASES

   SYMMETRY

   DISORDER

   CRYSTAL

Аннотация: (NH4)(3)NbOF6 single crystals were grown, polarization-optical studies were performed, and birefringence was measured over the temperature range 90-500 K. A sequence of first-order structural phase transitions was found at temperatures T (1 down arrow) = 259.7 K and T (2 down arrow) = 257.7 K with temperature hysteresis delta T-1 = 0.9 K and delta T-2 = 1.9 K. The transitions are accompanied by twinning and the following change in the crystal symmetry: cubic paired left right arrows tetragonal paired left right arrows monoclinic. Optical second harmonic generation is found to occur at room temperature, which indicates that the cubic phase is not centrosymmetric. It is assumed that the phase transitions are ferroelastic and ferroelectric in nature.

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
Russian Acad Sci, Inst Chem, Far E Div, Vladivostok 690022, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russian Federation

Доп.точки доступа:
Laptash, N. M.; Zhogal', A. L.; Мельникова, Светлана Владимировна
}
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3.


    Ignatchenko, V. A.
    Effects of the dimensionality of inhomogeneities on the wave spectrum of superlattices / V. A. Ignatchenko, Y. I. Mankov, A. A. Maradudin // Phys. Rev. B. - 2003. - Vol. 68, Is. 2. - Ст. 24209, DOI 10.1103/PhysRevB.68.024209. - Cited References: 26 . - ISSN 1098-0121
РУБ Physics, Condensed Matter
Рубрики:
ELASTIC MEDIUM THEORY
   PERIODIC MULTILAYERS

   SPIN-WAVES

   LOCALIZATION

   SYSTEMS

   MEDIA

   DISORDER

Аннотация: Dependences of the dispersion laws and damping of waves in an initially sinusoidal superlattice on the dimensionality of inhomogeneities modulating the period of the superlattice are studied. The cases of one- and three-dimensional modulations, as well as modulation by a mixture of inhomogeneities of both of these dimensionalities, are considered. The correlation function of the superlattice K(r) has the form of a product of the same periodic function and a decreasing function that is significantly different for these different cases. For r -- infinity the decreasing function goes to zero for the one-dimensional inhomogeneities and to a nonzero asymptote for the three-dimensional ones. Consequently, the transition from the disordered to ordered states is accompanied in the three-dimensional case not only by an increase of the correlation radius as in the one-dimensional case, but also by a change in the relationship between the volumes of the superlattices with finite and infinite correlation radii. The decreasing part of the correlation function for the mixture of inhomogeneities of different dimensionalities has the form of a product of the decreasing parts of the correlation functions of the components of the mixture. This leads to the nonadditivity of the contributions of the components of different dimensionalities to the resulting modification of the parameters of the wave spectrum that are due to the inhomogeneities (the damping of waves for the mixture of these components is smaller than the sum of the dampings of the components, the maximum gap in the spectrum corresponds to the simultaneous presence of both components, and so on).

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Держатели документа:
LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Univ Calif Irvine, Dept Phys & Astron, Irvine, CA 92697 USA
ИФ СО РАН

Доп.точки доступа:
Mankov, Y. I.; Maradudin, A. A.; Игнатченко, Вальтер Алексеевич
}
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4.


    Zinenko, V. I.
    Statistical mechanics of cation ordering in PbSc1/2Ta1/2O3 and PbSc1/2Nb1/2O3 solid solutions / V. I. Zinenko, S. N. Sofronova // Phys. Solid State. - 2005. - Vol. 47, Is. 12. - P. 2309-2314, DOI 10.1134/1.2142896. - Cited References: 17 . - ISSN 1063-7834
РУБ Physics, Condensed Matter
Рубрики:
PHASE-TRANSITION
   PEROVSKITE

   DISORDER

   FERROELECTRICS

   CRYSTALS

   MODEL

Аннотация: A model Hamiltonian for B cation ordering (Sc-Nb(Ta)) in PbSc1/2Nb1/2O3 and PbSc1/2Ta1/2O3 solid solutions is constructed. The parameters of the model Hamiltonian are determined from the ab initio calculation within the ionic crystal model with allowance made for the deformability and the dipole and quadrupole polarizabilities of the ions. The temperatures of the phase transition due to the ordering of the B cations are calculated by the Monte Carlo method in the mean-field and cluster approximations. The phase transition temperatures calculated by the Monte Carlo method (1920 K for PbSc1/2Ta1/2O3 and 1810 K for PbSc1/2Nb1/2O3) are consistent with the experimental data (1770 and 1450 K, respectively). The thermodynamic properties of the cation ordering are investigated using the Monte Carlo method. (c) 2005 Pleiades Publishing, Inc.

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Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Siberian Div, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Sofronova, S. N.; Софронова, Светлана Николаевна; Зиненко, Виктор Иванович
}
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5.


   
    Optical and X-ray Diffraction Studies of the Symmetry of Distorted Phases of the (NH4)(3)ZrF7 Crystal / S. V. Misyul [et al.] // Phys. Solid State. - 2008. - Vol. 50, Is. 10. - P. 1951-1956, DOI 10.1134/S1063783408100272. - Cited References: 12. - This work was supported by the Council on Grants from the President of the Russian Federation (project NSh-4137.2006.2). . - ISSN 1063-7834
РУБ Physics, Condensed Matter
Рубрики:
AMMONIUM HEPTAFLUOROZIRCONATE
   DISORDER

   TRANSITION

   K3ZRF7

Аннотация: (NH4)(3)ZrF7 single crystals were grown, and polarization-optical and x-ray diffraction studies were performed on powders and crystalline plates of various cuts over a wide temperature range. Phase transitions are revealed at temperatures T-1 up arrow = 280 K, T-2 up arrow = 279.6 K, T-3 up arrow = 260-265 K, and T-4 up arrow = 238 K on heating and at T-1 down arrow = 280 K, T-2 down arrow = 269-270 K, T-3 down arrow = 246 K, and T-4 down arrow = 235 K on cooling. The sequence of changes in symmetry is established to be as follows: O-h(5) (Z = 4)↔ D-2h(25) (Z = 2) ↔ C-2h(3) (Z = 2)↔ C-i(1) (Z = 108)↔ monoclinic(2) (Z = 216).

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Держатели документа:
[Misyul, S. V.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
[Mel'nikova, S. V.
Bovina, A. F.] Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Laptash, N. M.] Russian Acad Sci, Inst Chem, Far E Div, Vladivostok 690022, Russia
ИФ СО РАН
Siberian Federal University, Svobodnyi pr. 59, Krasnoyarsk 660041, Russian Federation
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok 690022, Russian Federation

Доп.точки доступа:
Misyul, S. V.; Мисюль, Сергей Валентинович; Mel'nikova, S. V.; Мельникова, Светлана Владимировна; Bovina, A. F.; Бовина, Ася Федоровна; Laptash, N. M.
}
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6.


    Ignatchenko, V. A.
    High-Frequency Susceptibility of a Superlattice with 2D Inhomogeneities / V. A. Ignatchenko, Y. I. Mankov, D. S. Tsikalov // J. Exp. Theor. Phys. - 2008. - Vol. 107, Is. 4. - P. 603-611, DOI 10.1134/S1063776108100075. - Cited References: 26. - This work was supported in part by grant no. 3818.2008.3 from the President of Russia in accordance with the program supporting leading scientific schools. . - ISSN 1063-7761
РУБ Physics, Multidisciplinary
Рубрики:
SPIN-WAVE SUSCEPTIBILITY
   PERIODIC MULTILAYERS

   LOCALIZATION

   SYSTEMS

   SPECTRUM

   DISORDER

   MEDIA

Кл.слова (ненормированные):
Energy conservation -- Energy gap -- Energy management -- Frequency bands -- Gallium alloys -- Green's function -- Probability density function -- Three dimensional -- Band gaps -- Energy conservation laws -- Green functions -- High frequencies -- Imaginary parts -- Magnon crystals -- Scattered waves -- Superlattice layers -- Wave spectrums -- Phase interfaces
Аннотация: We investigate the high-frequency susceptibility (Green function) of an initially sinusoidal 1D superlattice with 2D phase inhomogeneities that model the deformations of the interfaces between the superlattice layers. For waves propagating along the superlattice axis ( the geometry of a photon or magnon crystal), we have found a peculiar behavior of the imaginary part of the Green function that consists in a significant difference between the peaks corresponding to the edges of the band gap in the wave spectrum. The peak corresponding to the lower-frequency band edge remains essentially unchanged as the root-mean-square fluctuation of the 2D inhomogeneities. 2 increases, while the peak corresponding to the higher-frequency band edge broaden and decreases sharply in height until its complete disappearance with increasing gamma(2). This behavior of the peaks corresponds to a band gap closure mechanism that differs from the traditional one characteristic of 1D and 3D inhomogeneities. These effects can be explained by a peculiarity of the energy conservation laws for the incident and scattered waves for 2D inhomogeneities in a 1D superlattice.

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Держатели документа:
[Ignatchenko, V. A.
Mankov, Yu. I.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Mankov, Yu. I.
Tsikalov, D. S.] Siberian Fed Univ, Krasnoyarsk 660062, Russia
ИФ СО РАН
L.V. Kirenskii Institute of Physics, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk 660036, Russian Federation
Siberian Federal University, Krasnoyarsk 660062, Russian Federation

Доп.точки доступа:
Mankov, Y. I.; Tsikalov, D. S.; Цикалов, Денис Сергеевич; Игнатченко, Вальтер Алексеевич
}
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7.


    Ignatchenko, V. A.
    Partial restoration of the wave spectrum of a superlattice due to cross correlations between one- and three-dimensional inhomogeneities / V. A. Ignatchenko, Y. I. Mankov // Phys. Rev. B. - 2007. - Vol. 75, Is. 23. - Ст. 235422, DOI 10.1103/PhysRevB.75.235422. - Cited References: 32 . - ISSN 1098-0121
РУБ Physics, Condensed Matter
Рубрики:
ELASTIC MEDIUM THEORY
   PERIODIC MULTILAYERS

   SPIN-WAVES

   LOCALIZATION

   SYSTEMS

   SUSCEPTIBILITY

   DISORDER

   MEDIA

Аннотация: Effects of cross correlations between one-dimensional (1D) and three-dimensional (3D) random inhomogeneities on the wave spectrum in sinusoidal superlattices are studied theoretically. The situation when the gap in the spectrum (the forbidden zone) at the first Brillouin zone boundary of the superlattice is closed under the action of the 1D inhomogeneities is considered. The phenomenon of the partial opening of this gap is found when the 3D inhomogeneities cross correlated with the 1D inhomogeneities add to the superlattice. The appearance of the logarithmic resonance in the center of the forbidden zone under the action of the cross correlations is shown. The physical nature of the effects in the wave spectrum of the superlattice that are caused by the cross correlations and the relation of these effects with the asymptotic properties of the correlation function of inhomogeneities are discussed.

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Держатели документа:
SB RAS, LV Kirensky Inst Phys, Krasnoyarsk 660036, Russia
ИФ СО РАН
L. V. Kirensky Institute of Physics, SB RAS, 660036 Krasnoyarsk, Russian Federation

Доп.точки доступа:
Mankov, Y. I.; Игнатченко, Вальтер Алексеевич
}
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8.


   
    Thermophysical studies of the phase transitions in (NH4)(3)NbOF6 crystals / V. D. Fokina [et al.] // Phys. Solid State. - 2007. - Vol. 49, Is. 8. - P. 1548-1553, DOI 10.1134/S1063783407080240. - This work was supported by the Russian Foundation for Basic Research (project no. 06-02-16102), Krasnoyarsk Regional Science Foundation (project no.16G098), and the Council on Grants from President of the Russian Federation for the Support of Leading Scientific Schools of the Russian Federation (project NSh-4137.2006.2). - Cited References: 17 . - ISSN 1063-7834
РУБ Physics, Condensed Matter
Рубрики:
OXYFLUORIDES
   DISORDER

   RB

   CS

Аннотация: The thermophysical properties of oxyfluoride (NH4)(3)NbOF6 were studied in detail over wide ranges of temperatures and pressures. At atmospheric pressure, a sequence of four structural phase transitions was established with the following changes in entropy: Delta S (1) = Rln 2.7, delta S (2) = Rln38.3, Delta S (3) = 0.08R, and Delta S (4) = 0.17R. An external hydrostatic pressure was found to narrow the region of existence of the initial cubic phase. A triple point was detected in the p-T diagram; at a pressure above 0.07 GPa, the transition between the tetragonal and monoclinic phases occurs through a distorted high-pressure phase.

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Публикация на русском языке Теплофизические исследования фазовых переходов в кристалле (NH4)3NBOF6 [Текст] / Н. Б. Иванова [и др.] // Физ. тверд. тела. - 2007. - Т. 49 Вып. 8. - С. 1475-1479

Держатели документа:
Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Russian Acad Sci, Far E Div, Inst Chem, Vladivostok 690022, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok 690022, Russian Federation

Доп.точки доступа:
Fokina, V. D.; Фокина, Валентина Дмитриевна; Flerov, I. N.; Флёров, Игорь Николаевич; Gorev, M. V.; Горев, Михаил Васильевич; Bogdanov, E. V.; Богданов, Евгений Витальевич; Bovina, A. F.; Бовина, Ася Федоровна; Laptash, N. M.
}
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9.


   
    Phase transitions in (NH4)2MoO2F4 crystal / A. Krylov [et al.] // J. Mol. Struct. - 2016. - Vol. 1124, Special Issue : Novel developments and applications of two-dimensional correlation spectroscopy — A festschrift in honor of professor Isao Noda. - P. 125-130, DOI 10.1016/j.molstruc.2016.03.009. - Cited References:17 . - ISSN 0022-2860. - ISSN 1872-8014
   Перевод заглавия: Фазовые переходы в кристалле (NH4)2MoO2F4
РУБ Chemistry, Physical
Рубрики:
OXYFLUORIDE
   (NH4)2WO2F4

   DISORDER

   DIAGRAMS

Кл.слова (ненормированные):
Phase transitions -- Raman high-pressure -- Two-dimensional correlations -- Oxyfluorides
Аннотация: The mechanisms of temperature and high pressure phase transitions have been studied by Raman spectroscopy. Room temperature (295 K) experiments under high hydrostatic pressure up to 3.6 GPa for (NH4)(2) MoO2 F-4 have been carried out. Experimental data indicates a phase transition into a new high-pressure phase for (NH4)(2) MoO2 F-4 at 1.2 GPa. This phase transition is related to the ordering anion octahedron groups [MoO2 F-4](2) and is not associated with ammonium group. Raman spectra of small non-oriented crystals ranging from 10 to 350 K have been observed. The experiment shows anion groups [MoO2 F-4](2-) and ammonium in high temperature phase are disordered. The phase transition at T-1 = 269.8 K is of the first-order, close to the tricritical point. The first temperature phase transition is related to the ordering anion octahedron groups [MoO2 F-4](2-). Second phase transitions T-2 = 180 K are associated with the ordering of ammonium. The data presented within this study demonstrate that 2D correlation analysis combined with traditional Raman spectroscopy are powerful tool to study phase transitions in the crystals. (C) 2016 Elsevier B.V. All rights reserved.

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Доп.точки доступа:
Krylov, A. S.; Крылов, Александр Сергеевич; Laptash, N. M.; Vtyurin, A. N.; Втюрин, Александр Николаевич; Krylova, S. N.; Крылова, Светлана Николаевна; International Symposium on Two-Dimensional Correlation Spectroscopy(8th ; JUL 08-11, 2015 ; Vienna, Austria)
}
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10.


   
    Optical studies of phase transitions in the (NH4)(3)Ti(O-2)F-5 crystal / S. V. Mel'nikova [et al.] // Phys. Solid State. - 2009. - Vol. 51, Is. 4. - P. 817-822, DOI 10.1134/S1063783409040301. - Cited References: 13. - This work was supported by the Council on Grants from the President of the Russian Federation (project no. NSh-1011.2008.2), the Russian Foundation for Basic Research (project no. 06-02-16102), and RFBR Enisei (project no. 07-02-096800). . - ISSN 1063-7834
РУБ Physics, Condensed Matter
Рубрики:
(NH4)(3)WO3F3 OXYFLUORIDE
   RAMAN-SCATTERING

   DISORDER

Аннотация: Polarization-optical study of twinning and measurements of the Raman spectra and birefringence in oxyfluoride (NH4)(3)Ti(O-2)F-5 were carried out over the temperature range 90-350 K. Phase transitions were detected at temperatures T (01) = 266 K (second-order transition) and T (02) = 225 K (first order). It is assumed that the crystal symmetry is changed as follows: Fm3m a dagger" I4/mmm a dagger" I4/m. Anomalies of the spectral parameters are established in the frequency range of internal vibrations of ammonium ions and Ti(O-2)F-5 complexes. An analysis of the results shows that the transition at T (01) is likely due to small shifts of the tetrahedral groups from their position on the triad axis and that the transition at T (02) is due to fluorine-oxygen ordering of Ti(O-2)F-5 complexes.

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Держатели документа:
[Mel'nikova, S. V.
Krylov, A. S.
Zhogal', A. L.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Laptash, N. M.] Russian Acad Sci, Inst Chem, Far E Div, Vladivostok 690022, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok 690022, Russian Federation

Доп.точки доступа:
Mel'nikova, S. V.; Мельникова, Светлана Владимировна; Krylov, A. S.; Крылов, Александр Сергеевич; Zhogal', A. L.; Laptash, N. M.; Russian Federation [NSh-1011.2008.2]; Russian Foundation for Basic Research [06-02-16102]; RFBR Enisei [07-02-096800]
}
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11.


    Ignatchenko, V. A.
    Partial restoration of the wave spectrum of a superlattice due to cross correlations between one- and three-dimensional inhomogeneities / V. A. Ignatchenko, Y. I. Mankov // Phys. Rev. B. - 2007. - Vol. 75, Is. 23. - Ст. 235422, DOI 10.1103/PhysRevB.75.235422. - Cited References: 32 . - ISSN 1098-0121
РУБ Physics, Condensed Matter
Рубрики:
ELASTIC MEDIUM THEORY
   PERIODIC MULTILAYERS

   SPIN-WAVES

   LOCALIZATION

   SYSTEMS

   SUSCEPTIBILITY

   DISORDER

   MEDIA

Аннотация: Effects of cross correlations between one-dimensional (1D) and three-dimensional (3D) random inhomogeneities on the wave spectrum in sinusoidal superlattices are studied theoretically. The situation when the gap in the spectrum (the forbidden zone) at the first Brillouin zone boundary of the superlattice is closed under the action of the 1D inhomogeneities is considered. The phenomenon of the partial opening of this gap is found when the 3D inhomogeneities cross correlated with the 1D inhomogeneities add to the superlattice. The appearance of the logarithmic resonance in the center of the forbidden zone under the action of the cross correlations is shown. The physical nature of the effects in the wave spectrum of the superlattice that are caused by the cross correlations and the relation of these effects with the asymptotic properties of the correlation function of inhomogeneities are discussed.

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Держатели документа:
SB RAS, LV Kirensky Inst Phys, Krasnoyarsk 660036, Russia
ИФ СО РАН
L. V. Kirensky Institute of Physics, SB RAS, 660036 Krasnoyarsk, Russian Federation

Доп.точки доступа:
Mankov, Y. I.; Игнатченко, Вальтер Алексеевич
}
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12.


   
    Thermal, optical, and dielectric properties of Fluoride Rb2TaF7 / E. I. Pogorel'tsev [et al.] // Phys. Solid State. - 2017. - Vol. 59, Is. 5. - P. 986-991, DOI 10.1134/S1063783417050250. - Cited References:21. - The reported study was funded by the Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research project no. 16-42-243001. . - ISSN 1063-7834. - ISSN 1090-6460
РУБ Physics, Condensed Matter
Рубрики:
PHASE-TRANSITIONS
   X-RAY

   DISORDER

   NMR

   DIFFRACTION

   OXYFLUORIDE

Аннотация: The thermal, optical, and dielectric properties of fluoride Rb2TaF7 were investigated. It was observed that the variation in chemical pressure in fluorides A2+TaF7 caused by the cation substitution of rubidium for ammonium does not affect the ferroelastic nature of structural distortions, but leads to stabilization of the high- and low-temperature phases and enhancement of birefringence. The entropy of the phase transition P4/nmm ↔ Cmma is typical of the shift transformations, which is consistent with a model of the initial and distorted phase structures. The anisotropy of chemical pressure causes the change of signs of the anomalous strain and baric coefficient dT/dp of Rb2TaF7 as compared with the values for its ammonium analog.

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Публикация на русском языке Тепловые, оптические и диэлектрические свойства Rb2TaF7 [Текст] / Е. И. Погорельцев [и др.] // Физ. тверд. тела : Наука, 2017. - Т. 59 Вып. 5. - С. 959-964

Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Fed Res Ctr, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Krasnoyarsk State Pedag Univ, Krasnoyarsk 660060, Russia.
Russian Acad Sci, Inst Chem, Far East Branch, Vladivostok 690022, Russia.

Доп.точки доступа:
Pogorel'tsev, E. I.; Погорельцев, Евгений Ильич; Mel'nikova, S. V.; Мельникова, Светлана Владимировна; Kartashev, A. V.; Карташев, Андрей Васильевич; Gorev, M. V.; Горев, Михаил Васильевич; Flerov, I. N.; Флёров, Игорь Николаевич; Laptash, N. M.; Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund [16-42-243001]
}
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13.


    Ignatchenko, V. A.
    Effects of the mixture of one- and three-dimensional inhomogeneities on the wave spectrum of superlattices / V. A. Ignatchenko, Y. I. Mankov, A. A. Maradudin // JETP Letters. - 2003. - Vol. 77, Is. 6. - P. 285-290, DOI 10.1134/1.1577758. - Cited References: 24 . - ISSN 0021-3640
РУБ Physics, Multidisciplinary
Рубрики:
PERIODIC MULTILAYERS
   SPIN-WAVES

   LOCALIZATION

   SYSTEMS

   THICKNESSES

   DISORDER

   AVERAGE

   MEDIA

Аннотация: Dependences of the dispersion laws and damping of waves in an initially sinusoidal superlattice on the dimensionality of inhomogeneities modulating the period of the superlattice are studied. The cases of one- and three-dimensional modulations, as well as modulation by a mixture of inhomogeneities of both of these dimensionalities, are considered. The correlation function of the superlattice K(r) has the form of a product of the same periodic function and a decreasing function that is significantly different for these different cases. The decreasing part of the correlation function for the mixture of inhomogeneities of different dimensionalities has the form of a product of the decreasing parts of the correlation functions of the components of the mixture. This leads to the nonadditivity of the contributions of the components of different dimensionalities to the resulting modification of the parameters of the wave spectrum that are due to the inhomogeneities (the damping of waves for the mixture of these components is smaller than the sum of the dampings of the components, the maximum gap in the spectrum corresponds to the simultaneous presence of both components of the mixture, not only of the three-dimensional inhomogeneities). (C) 2003 MAIK "Nauka / Interperiodica".

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Держатели документа:
LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Univ Calif Irvine, Dept Phys & Astron, Irvine, CA 92697 USA
ИФ СО РАН
Kirensky Institute of Physics, Krasnoyarsk, 660036, Russian Federation
Department of Physics and Astronomy, University of California, Irvine, CA 92697, United States

Доп.точки доступа:
Mankov, Y. I.; Maradudin, A. A.; Игнатченко, Вальтер Алексеевич
}
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14.


    Ignatchenko, V. A.
    Waves in a superlattice with anisotropic inhomogeneities / V. A. Ignatchenko, A. A. Maradudin, A. V. Poszdnyakov // JETP Letters. - 2003. - Vol. 78, Is. 9. - P. 592-596, DOI 10.1134/1.1641491. - Cited References: 28 . - ISSN 0021-3640
РУБ Physics, Multidisciplinary
Рубрики:
PERIODIC MULTILAYERS
   SPIN-WAVES

   SPECTRUM

   LOCALIZATION

   SYSTEMS

   MEDIA

   DISORDER

   AVERAGE

Аннотация: Dependences of the dispersion laws and damping of waves in an initially sinusoidal superlattice on inhomogeneities with anisotropic correlation properties are studied for the first time. The period of the superlattice is modulated by the random function described by the anisotropic correlation function K-phi(r) that has different correlation radii, k(parallel toparallel to)(-1) and k(perpendicular to)(-1), along the axis of the superlattice z and in the plane xy, respectively. The anisotropy of the correlation is characterized by the parameter lambda = 1 - k(perpendicular to)/k(parallel toparallel to) that can change from lambda = 0 to lambda = 1 when the correlation wave number k(perpendicular to) changes from k(perpendicular to) = k(parallel toparallel to) (isotropic 3D inhomogeneities) to k(perpendicular to) = 0 (1D inhomogeneities). The correlation function of the superlattice K(r) is developed. Its decreasing part goes to the asymptote L that divides the correlation volume into two parts, characterized by finite and infinite correlation radii. The dependences of the width of the gap in the spectrum at the boundary of the Brillouin zone Deltanu and the damping of waves xi on the value of lambda are studied. It is shown that decreasing L leads to the decrease of Deltanu, and increase of xi, with the increase of lambda. (C) 2003 MAIK "Nauka / Interperiodica".

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
Univ Calif Irvine, Dept Phys & Astron, Irvine, CA 92697 USA
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Department of Physics and Astronomy, University of California, Irvine, CA, United States

Доп.точки доступа:
Maradudin, A. A.; Poszdnyakov, A. V.; Игнатченко, Вальтер Алексеевич
}
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15.


    Ignatchenko, V. A.
    Effects of cross correlations between 1D and 3D inhomogeneities on the high-frequency susceptibility of superlattices / V. A. Ignatchenko, Y. I. Mankov // J. Exp. Theor. Phys. - 2006. - Vol. 102, Is. 4. - P. 625-635, DOI 10.1134/S106377610604011X. - Cited References: 29 . - ISSN 1063-7761
РУБ Physics, Multidisciplinary
Рубрики:
ELASTIC MEDIUM THEORY
   3-DIMENSIONAL INHOMOGENEITIES

   PERIODIC MULTILAYERS

   SPIN-WAVES

   LOCALIZATION

   SPECTRUM

   SYSTEMS

   MEDIA

   DISORDER

Кл.слова (ненормированные):
Correlation methods -- Damping -- Function evaluation -- Wave equations -- Brillouin zone -- Distribution function -- Random variables -- Superlattices
Аннотация: Cross Correlations between components of a mixture of one-dimensional (I D) and three-diniensional (3D) inhomogenetics are described by introducing a distribution function taking into account correlations between absolute values of two random variables in the absence of correlations between the variables themselves. This distribution function is used for derivation and analysis of the superlattice correlation function containing a mixture of cross-correlated 1D and 3D in homogeneitics. The effect of such inhomogeneities on the high-frequency susceptibility at the edge of the first Brillouin zone of the superlattice is investigated. It is shown that positive cross correlations partly suppress the effect of a mixture of 1D and 3D inhomogeneities on the wave spectrum: the gap at the boundary of the Brillouin zone increases, and wave damping decreases as compared to the effect produced by a mixture of 1D and 3D inhomogeneities in the absence of cross correlations. Negative cross correlations lead to the opposite effect: the gap decreases and wave damping increases. Cross correlations also lead to the emergence of new resonance effects: a narrow dip or a narrow peak at the center of the band gap (depending on the sign of the correlation factor).

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Держатели документа:
Russian Acad Sci, Kirenskii Inst Phys, Siberian Div, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirenskii Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Mankov, Y. I.; Игнатченко, Вальтер Алексеевич
}
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16.


    Ignatchenko, V. A.
    Effects of one- and three-dimensional inhomogeneities on the wave spectrum of multilayers with finite interface thicknesses / V. A. Ignatchenko, Y. I. Mankov, A. A. Maradudin // Phys. Rev. B. - 2002. - Vol. 65, Is. 2. - Ст. 24207, DOI 10.1103/PhysRevB.65.024207. - Cited References: 24 . - ISSN 1098-0121
РУБ Physics, Condensed Matter
Рубрики:
PERIODIC MULTILAYERS
   SPIN-WAVES

   LOCALIZATION

   SUPERLATTICES

   SYSTEMS

   DISORDER

   AVERAGE

   MEDIA

Аннотация: To describe a partially randomized multilayer structure with arbitrary thicknesses of the interfaces between layers, we introduce a model in which the dependence of a material parameter along the axis of such a Superlattice is described by a Jacobian elliptic sine function with a random spatial modulation of its period. Both one- and three-dimensional inhomogeneities of the period are considered. We develop the correlation function for this model, and investigate the dispersion law and damping of averaged waves in this superlattice. The dependencies of the widths of the gaps in the spectrum and the damping at the boundaries of all odd Brillouin zones, on the thicknesses of the interfaces, and on the dimensionality, intensity, and correlation wave number of the inhomogeneities are found. It is shown that experimental investigations of the widths of the gaps and damping for several Brillouin zones could permit, in principle, determining all parameters of the superlattice as well as the parameters of the inhomogeneities from these spectral characteristics.

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Держатели документа:
LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Univ Calif Irvine, Dept Phys & Astron, Irvine, CA 92697 USA
ИФ СО РАН

Доп.точки доступа:
Mankov, Y. I.; Maradudin, A. A.; Игнатченко, Вальтер Алексеевич
}
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17.


    Zhandun, V. S.
    Lattice dynamics and the ferroelectric phase transition in ordered Pb-2 B'BaEuro(3)O(6) (B' = Ga, In, Lu; BaEuro(3) = Nb, Ta) solid solutions / V. S. Zhandun, N. G. Zamkova, V. I. Zinenko // Phys. Solid State. - 2010. - Vol. 52, Is. 2. - P. 357-363, DOI 10.1134/S1063783410020228. - Cited References: 19. - This study is supported by the Russian Foundation for Basic Research (project no. 09-02-00067) and the Council on Grants from the President of the Russian Federation for Support of the Leading Scientific Schools (grant no. NSh-4137.2006.2). . - ISSN 1063-7834
РУБ Physics, Condensed Matter
Рубрики:
PEROVSKITES
   CRYSTALS

   DISORDER

   RELAXOR

   BATIO3

   PBTIO3

Аннотация: The lattice vibration spectrum, rf permittivity, and dynamic Born charges have been calculated for ordered Pb-2 B'BaEuro(3)O(3) (B'=Ga, In, Lu; BaEuro(3)=Nb, Ta) solid solutions in terms of the generalized Gordon-Kim model. It has been shown that all compounds exhibit a ferroelectric instability and that the frequencies of "soft" ferroelectric modes are close in magnitude. The ferroelectric phase-transition temperatures and the spontaneous polarization in the ferroelectric phase of the solid solutions under consideration have been calculated by the Monte Carlo method using the model Hamiltonian in the local mode approximation. The transition temperature is found to increase with increasing atomic number of the B' ion.

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Держатели документа:
[Zhandun, V. S.
Zamkova, N. G.
Zinenko, V. I.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Zamkova, N. G.; Замкова, Наталья Геннадьевна; Zinenko, V. I.; Зиненко, Виктор Иванович; Жандун, Вячеслав Сергеевич
}
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18.


    Molokeev, M. S.
    Processes of ordering of structural elements, critical and noncritical parameters of phase transitions in the (NH4)3WO3F3 crystal / M. S. Molokeev, S. V. Misyul' // Phys. Solid State. - 2012. - Vol. 54, Is. 1. - P. 155-165, DOI 10.1134/S1063783412010222. - Cited References: 18. - This study was supported by the Russian Foundation for Basic Research (project no. 09-02-00062) and the Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools of the Russian Federation (grant no. NSh-4645.2010.2). . - ISSN 1063-7834. - ISSN 1090-6460
РУБ Physics, Condensed Matter
Рубрики:
OXYFLUORIDE
   TRANSFORMATIONS

   (NH4)3TiOF5

   DISORDER

Аннотация: The structure of the low-temperature triclinic phase of the (NH4)3WO3F3 crystal has been determined and the structure of the cubic phase of this crystal has been refined from data of an X-ray diffraction experiment performed for a powder sample. The profile and structural parameters have been refined according to the procedure implemented in the DDM program. The results obtained have been discussed with invoking the group-theoretical analysis of the complete order parameter condensate, which takes into account the critical and noncritical atomic orderings and allows one to interpret the obtained experimental data. It has been found that the symmetry transformation in the crystal can be schematically represented in the following form: Fm3¯m(Z=4)→P1¯(Z=1)→P1¯(Z=6)Fm\bar 3m(Z = 4) \to P\bar 1(Z = 1) \to P\bar 1(Z = 6) . This transformation is accompanied by the complete ordering of WO3F3 polyhedra and the displacement of NH4 ions.

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Публикация на русском языке Молокеев, Максим Сергеевич. Процессы упорядочения структурных элементов, критические и некритические параметры переходов в кристалле (NH4)3WO3F3 [Текст] / М. С. Молокеев, С. В. Мисюль // Физ. тверд. тела : Физико-технический институт им. А.Ф.Иоффе РАН, 2012. - Т. 54 Вып. 1. - С. 144-153

Держатели документа:
[Molokeev, M. S.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Misyul', S. V.] Siberian Fed Univ, Krasnoyarsk 660041, Russia

Доп.точки доступа:
Misyul', S. V.; Мисюль, Сергей Валентинович; Молокеев, Максим Сергеевич
}
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19.


   
    Raman scattering study of temperature induced phase transitions in crystalline ammonium heptafluorozirconate, (NH4)3ZrF7 / A. S. Krylov [et al.] // Vib. Spectrosc. - 2012. - Vol. 62. - P. 258-263, DOI 10.1016/j.vibspec.2012.07.003. - Cited References: 31. - This work was partly supported by integration project SB RAS No 28, Russian Foundation for Basic Research project No 11-02-98002-r_siberia, No 12-02-00056, SS-4828.2012.2. The authors are grateful to Dr. I.N. Flerov for helpful discussions. The assistance of Dr. S. Skokov is sincerely appreciated. . - ISSN 0924-2031
РУБ Chemistry, Analytical + Chemistry, Physical + Spectroscopy
Рубрики:
VIBRATIONAL-SPECTRA
   X-RAY

   DISORDER

   DIFFRACTION

   ELPASOLITE

   SYMMETRY

   RB2KSCF6

   IF7

Кл.слова (ненормированные):
Raman spectroscopy -- Phase transition -- Ammonium heptafluorozirconate -- Low temperature
Аннотация: This paper reports on a Raman spectroscopy investigation of phase transitions in (NH4)3ZrF7 crystal. Raman spectra were obtained and analyzed in a wavenumber range from 3800 to 15 cm−1 and in the temperature range from 7 to 360 K. The anomalies caused by a series of subsequent structural phase transitions have been analyzed. A soft phonon mode restoring in the distorted phase was found. The spectral changes observed in the current study are similar to those typically found in phase transitions near a tricritical point. The spectral changes in the middle wavenumber range, 700–150 cm−1, indicate that the phase transitions are due to structural ordering of pentagonal ZrF73− bipyramids. Spectral data also show that a phase transition near 225 K is accompanied by an increase of the unit cell volume. In addition, spectral changes in the range of internal vibrations of ammonium ions indicate that the ion's motion slows down with decrease of temperature.

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Держатели документа:
[Krylov, A. S.
Krylova, S. N.
Vtyurin, A. N.] LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
[Laptash, N. M.] Russian Acad Sci, Inst Chem, Vladivostok 690022, Russia

Доп.точки доступа:
Krylov, A. S.; Крылов, Александр Сергеевич; Krylova, S. N.; Крылова, Светлана Николаевна; Laptash, N. M.; Vtyurin, A. N.; Втюрин, Александр Николаевич
}
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20.


   
    Reconstructive phase transition in (NH4)3TiF7 accompanied by the ordering of TiF6 octahedra / M. S. Molokeev [et al.] // Acta Crystallogr. B. - 2014. - Vol. 70. - P. 924-931, DOI 10.1107/S2052520614021192. - This study was supported by Russian Fund of Basic Research, project No. 12-02-00056 a . - ISSN 0108-7681. - ISSN 1600-5740
   Перевод заглавия: Реконструктивный фазовый переход в (NH4)3TiF7, сопровождающийся упорядочением октаэдров TiF6
РУБ Crystallography
Рубрики:
CRYSTAL-STRUCTURE
   NEUTRON-DIFFRACTION

   POWDER DIFFRACTION

   FLUORIDES

   DISORDER

   MECHANISM

   PATHWAYS

   COMPLEX

   LI3THF7

   ALPHA

Кл.слова (ненормированные):
reconstructive phase transition -- ammonium heptafluorotitanate -- order-disorder transition
Аннотация: An unusual phase transition P4/mnc →Pa3 has been detected after cooling the (NH4)3TiF7 compound. Some TiF6 octahedra, which are disordered in the room-temperature tetragonal structure, become ordered in the low-temperature cubic phase due to the disappearance of the fourfold axis. Other TiF6 octahedra undergo large rotations resulting in huge displacements of the F atoms by 1.5-1.8 Å that implies a reconstructive phase transition. It was supposed that phases P4/mbm and Pm3m could be a high-temperature phase and a parent phase, respectively, in (NH4)3TiF7. Therefore, the sequence of phase transitions can be written as Pm3m → P4/bm → P4/mnc → Pa3. The interrelation between (NH4)3TiF7, (NH4)3GeF7 and (NH4)3PbF7 is found, which allows us to suppose phase transitions in relative compounds.

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Держатели документа:
LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Siberian State Univ, Inst Engn Phys & Radioelect, Krasnoyarsk 660074, Russia
Inst Chem, Vladivostok 660022, Russia

Доп.точки доступа:
Molokeev, M. S.; Молокеев, Максим Сергеевич; Misjul, S. V.; Мисюль, Сергей Валентинович; Flerov, I. N.; Флёров, Игорь Николаевич; Laptash, N. M.
}
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