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A hybrid quantum–classical theory for predicting terahertz charge-transfer plasmons in metal nanoparticles on graphene / A. S. Fedorov, E. V. Eremkin, P. O. Krasnov [et al.] // J. Chem. Phys. - 2024. - Vol. 160, Is. 4. - Ст. 044117, DOI 10.1063/5.0178247. - Cited References: 61. - This study was funded by the Ministry of Science and High Education of Russian Federation, Project No. FSRZ-2023-0006. The calculations of CTPs in specific NP–graphene complexes were performed within the RSF Grant No. 23-12-20007 and the Krasnoyarsk Territorial Foundation for Support of Scientific and R & D Activities, Agreement No. 256. H. Ågren was supported by the Swedish Science Research Council on Contract No. 2022-03405 . - ISSN 0021-9606. - ISSN 1089-7690
Аннотация: Metal nanoparticle (NP) complexes lying on a single-layer graphene surface are studied with a developed original hybrid quantum–classical theory using the Finite Element Method (FEM) that is computationally cheap. Our theory is based on the motivated assumption that the carrier charge density in the doped graphene does not vary significantly during the plasmon oscillations. Charge transfer plasmon (CTP) frequencies, eigenvectors, quality factors, energy loss in the NPs and in graphene, and the absorption power are aspects that are theoretically studied and numerically calculated. It is shown the CTP frequencies reside in the terahertz range and can be represented as a product of two factors: the Fermi level of graphene and the geometry of the NP complex. The energy losses in the NPs are predicted to be inversely dependent on the radius R of the nanoparticle, while the loss in graphene is proportional to R and the interparticle distance. The CTP quality factors are predicted to be in the range ~ 10 – 100. The absorption power under CTP excitation is proportional to the scalar product of the CTP dipole moment and the external electromagnetic field. The developed theory makes it possible to simulate different properties of CTPs 3–4 orders of magnitude faster compared to the original FEM or the finite-difference time domain method, providing possibilities for predicting the plasmonic properties of very large systems for different applications.

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Держатели документа:
International Research Center of Spectroscopy and Quantum Chemistry, Siberian Federal University, 660041 Krasnoyarsk, Russia
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia
Institute of Computational Modeling SB RAS, 660036 Krasnoyarsk, Russia
Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala, Sweden

Доп.точки доступа:
Fedorov, A. S.; Федоров, Александр Семенович; Eremkin, E. V.; Krasnov, P. O.; Gerasimov, V. S.; Agren, H.; Polyutov, S. P.
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Charge transfer plasmons in the arrays of nanoparticles connected by conductive linkers / A. S. Fedorov, M. A. Visotin, V. S. Gerasimov [et al.] // J. Chem. Phys. - 2021. - Vol. 154, Is. 8. - Ст. 012009, DOI 10.1063/5.0040128. - Cited References: 41. - This study was supported by the Russian Science Foundation, Project No. 18-13-00363 . - ISSN 0021-9606
Кл.слова (ненормированные):
Analytical expressions -- Carrier scattering -- Charge displacement -- External electromagnetic field -- Finite difference time domain simulations -- Metallic nanoparticles -- Numerical solution -- Plasmon oscillations
Аннотация: Charge transfer plasmons (CTPs) that occur in different topology and dimensionality arrays of metallic nanoparticles (NPs) linked by narrow molecular bridges are studied. The occurrence of CTPs in such arrays is related to the ballistic motion of electrons in thin linkers with the conductivity that is purely imaginary, in contrast to the case of conventional CTPs, where metallic NPs are linked by thick bridges with the real optical conductivity caused by carrier scattering. An original hybrid model for describing the CTPs with such linkers has been further developed. For different NP arrays, either a general analytical expression or a numerical solution has been obtained for the CTP frequencies. It has been shown that the CTP frequencies lie in the IR spectral range and depend on both the linker conductivity and the system geometry. It is found that the electron currents of plasmon oscillations correspond to minor charge displacements of only few electrons. It has been established that the interaction of the CTPs with an external electromagnetic field strongly depends on the symmetry of the electron currents in the linkers, which, in turn, are fully governed by the symmetry of the investigated system. The extended model and the analytical expressions for the CTPs frequencies have been compared with the conventional finite difference time domain simulations. It is argued that applications of this novel type of plasmon may have wide ramifications in the area of chemical sensing.

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Держатели документа:
International Research Center of Spectroscopy and Quantum Chemistry - IRC SQC, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
National Research Tomsk State University, Tomsk, 634050, Russian Federation
Institute of Computational Modelling, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Federal Siberian Research Clinical Centre, FMBA of Russia, Krasnoyarsk, 660037, Russian Federation
Kyungpook National University, Daegu, 41566, South Korea

Доп.точки доступа:
Fedorov, A. S.; Федоров, Александр Семенович; Visotin, M. A.; Высотин, Максим Александрович; Gerasimov, V. S.; Polyutov, S. P.; Avramov, P. A.
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Collective resonances in hybrid photonic-plasmonic nanostructures / A. E. Ershov [et al.] // International Conference on Metamaterials and Nanophotonics (METANANO 2019). - St. Petersburg, 2019

Материалы конференции,
Материалы конференции

Доп.точки доступа:
Ershov, A. E.; Ершов, Александр Андреевич; Bikbaev, R. G.; Бикбаев, Рашид Гельмединович; Rasskazov, I. L.; Рассказов, Илья Леонидович; Gerasimov, V. S.; Герасимов, Валерий Сергеевич; Timofeev, I. V.; Тимофеев, Иван Владимирович; Polyutov, S. P.; Karpov, S. V.; Карпов, Сергей Васильевич; International Conference on Metamaterials and Nanophotonics(4 ; 2019 ; July ; 15-19 ; Saint Peresburg); Санкт-Петербургский национальный исследовательский университет информационных технологий, механики и оптики
}
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Collective lattice resonances in all-dielectric nanostructures under oblique incidence / A. D. Utyushev, V. I. Zakomirnyi, A. E. Ershov [et al.] // Photonics. - 2020. - Vol. 7, Is. 2. - Ст. 24, DOI 10.3390/PHOTONICS7020024. - Cited References: 70. - This research was funded by the RF Ministry of Science and Higher Education, the State contract with Siberian Federal University for scientific research and Russian Science Foundation project 19-72-00066 (investigation of finite size effects) . - ISSN 2304-6732
Кл.слова (ненормированные):
Collective lattice resonance -- Nanoparticle -- All-dielectric nanophotonics -- Mie resonance
Аннотация: Collective lattice resonances (CLRs) emerging under oblique incidence in 2D finite-size arrays of Si nanospheres have been studied with the coupled dipole model. We show that hybridization between the Mie resonances localized on a single nanoparticle and angle-dependent grating Wood-Rayleigh anomalies allows for the efficient tuning of CLRs across the visible spectrum. Complex nature of CLRs in arrays of dielectric particles with both electric dipole (ED) and magnetic dipole (MD) resonances paves a way for a selective and flexible tuning of either ED or MD CLR by an appropriate variation of the angle of incidence. The importance of the finite-size effects, which are especially pronounced for CLRs emerging for high diffraction orders under an oblique incidence has been also discussed.

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Держатели документа:
Department of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Department of Space Materials and Technology, Siberian State University of Science and Technology, Krasnoyarsk, 660014, Russian Federation
Institute of Computational Modeling SB RAS, Krasnoyarsk, 660036, Russian Federation
L. V. Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
The Institute of Optics, University of Rochester, Rochester, NY 14627, United States

Доп.точки доступа:
Utyushev, A. D.; Zakomirnyi, V. I.; Ershov, A. E.; Gerasimov, V. S.; Karpov, S. V.; Карпов, Сергей Васильевич; Rasskazov, I. L.
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Collective lattice resonances in arrays of dielectric nanoparticles: a matter of size / V. I. Zakomirnyi [et al.] // Opt. Lett. - 2019. - Vol. 44, Is. 23. - P. 5743-5746, DOI 10.1364/OL.44.005743. - Cited References: 66. - Russian Science Foundation (19-72-00066). . - ISSN 0146-9592. - ISSN 1539-4794
Аннотация: Collective lattice resonances (CLRs) in finite-sized 2D arrays of dielectric nanospheres have been studied via the coupled dipole approximation. We show that even for sufficiently large arrays, up to 100×100 nanoparticles (NPs), electric or magnetic dipole CLRs may differ significantly from the ones calculated for infinite arrays with the same NP sizes and interparticle distances. The discrepancy is explained by the existence of a sufficiently strong cross-interaction between electric and magnetic dipoles induced at NPs in finite-sized lattices, which is ignored for infinite arrays. We support this claim numerically and propose an analytic model to estimate a spectral width of CLRs for finite-sized arrays. Given that most of the current theoretical and numerical researches on collective effects in arrays of dielectric NPs rely on modeling infinite structures, the reported findings may contribute to thoughtful and optimal design of inherently finite-sized photonic devices.

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Держатели документа:
Department of Theoretical Chemistry and Biology, School of Engineering Sciences in Chemistry, Biotechnology and Health, Royal Institute of Technology, Stockholm SE-10691, Sweden
Federal Siberian Research Clinical Centre under FMBA of Russia, Krasnoyarsk 660037, Russia
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia
Institute of Computational Modeling SB RAS, Krasnoyarsk 660036, Russia
Siberian Federal University, Krasnoyarsk 660041, Russia
Siberian State University of Science and Technology, Krasnoyarsk 660014, Russia
The Institute of Optics, University of Rochester, Rochester, New York 14627, USA

Доп.точки доступа:
Zakomirnyi, V. I.; Закомирный, Вадим Игоревич; Ershov, A. E.; Ершов, Александр Евгеньевич; Gerasimov, V. S.; Герасимов, Валерий Сергеевич; Karpov, S. V.; Карпов, Сергей Васильевич; Ågren, H.; Rasskazov, I. L.
}
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Collective resonances in hybrid photonic-plasmonic nanostructures / A. E. Ershov, R. G. Bikbaev, I. L. Rasskazov [et al.] // J. Phys.: Conf. Ser. - 2020. - Vol. 1461, Is. 1. - Ст. 012046DOI 10.1088/1742-6596/1461/1/012046. - Cited References: 11. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science (Grant No. 18-42-240013); A.E. thanks the grant of the President of Russian Federation (agreement 075-15-2019-676)
Кл.слова (ненормированные):
Hybrid systems -- Plasmonics -- Time domain analysis -- 1-D photonic crystal -- Defect layers -- Nanodisks -- Periodic arrays -- Plasmonic nanostructures -- Rayleigh anomalies -- Spectral position -- Theoretical modeling -- Finite difference time domain method
Аннотация: We present the theoretical model to predict the spectral position of Rayleigh anomalies emerged in hybrid system consisting of periodic array of plasmonic nanodisks embeded into the middle of defect layer of 1D photonic crystal (PhC). The spectral positions of these new emerged Rayleigh anomalies agree well with the results of exact simulations with Finite-Difference Time-Domain (FDTD) method.

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Держатели документа:
Institute of Computational Modeling SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Siberian State University of Science and Technology, Krasnoyarsk, 660014, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Institute of Optics, University of Rochester, Rochester, NY 14627, United States

Доп.точки доступа:
Ershov, A. E.; Bikbaev, R. G.; Бикбаев, Рашид Гельмединович; Rasskazov, I. L.; Gerasimov, V. S.; Timofeev, I. V.; Тимофеев, Иван Владимирович; Polyutov, S. P.; Karpov, S. V.; Карпов, Сергей Васильевич; International Conference on Metamaterials and Nanophotonics(4th ; 15 - 19 July 2019 ; St. Petersburg, Russian Federation)
}
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Cинтез плазмонно-резонансных нановолноводов оптического излучения на диэлектрической подложке в условиях ее электростатической функционализации / С. В. Карпов, И. Л. Исаев [и др.] // Ультрадисперсные порошки, наноструктуры, материалы: получение, свойства, применение. V Ставеровские чтения : труды Всерос. науч.-технич. конф. с междунар. участием, 15-16 октября 2009 г., Красноярск. - Красноярск : СФУ, 2009. - С. 210-211

Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Карпов, Сергей Васильевич; Karpov, S. V.; Исаев, Иван Леонидович; Isaev, I. L.; Герасимов, Валерий Сергеевич; Gerasimov V. S.; Грачев, Александр Сергеевич; Рассказов, И. С; Ципотан, Алексей Сергеевич; "Ультрадисперсные порошки, наноструктуры, материалы", Всероссийская научно-техническая конференция(5 ; 2009 ; сент. ; Красноярск); Ставеровские чтения(5 ; 2009 ; сент. ; Красноярск)
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Cпонтанная кристаллизация наноструктурированных золей металлов и ее кинетика / С. В. Карпов, И. Л. Исаев, А. П. Гаврилюк [и др.] // Моделирование неравновесных систем - 2008 : материалы Одиннадцатого Всероссийского семинара : 26-28 сентября 2008 г. - 2011. - С. 114-116

Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Карпов, Сергей Васильевич; Karpov, S.V.; Исаев, Иван Леонидович; Isaev, I. L.; Гаврилюк, Анатолий Петрович; Gavrilyuk A.P.; Герасимов, Валерий Сергеевич; Gerasimov V. S.; Грачев, Александр Сергеевич; "Моделирование неравновесных систем", всероссийский семинар(11 ; 2008 ; сент. ; Красноярск); Институт вычислительного моделирования Сибирского отделения РАН; Сибирский федеральный университет; Институт систем энергетики им. Л. А. Мелентьева СО РАН; Институт физики им. Л.В. Киренского Сибирского отделения РАН
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Electromagnetic density of states and absorption of radiation by aggregates of nanospheres with multipole interactions / V. A. Markel [et al.] // Phys. Rev. B. - 2004. - Vol. 70, Is. 5. - Ст. 54202, DOI 10.1103/PhysRevB.70.054202. - Cited References: 81 . - ISSN 1098-0121

РУБ Physics, Condensed Matter
Рубрики:
DISCRETE-DIPOLE APPROXIMATION
   ENHANCED RAMAN-SCATTERING
   METAL FRACTAL CLUSTERS
   OPTICAL-PROPERTIES
   SELECTIVE PHOTOMODIFICATION
   DISORDERED CLUSTERS
   NUMERICAL-SIMULATION
   SPECTRAL DEPENDENCE
   PARTICULATE MATTER
   LIGHT-SCATTERING
Кл.слова (ненормированные):
carbon -- iron -- palladium -- silver -- article -- dipole -- electromagnetic field -- geometry -- mathematical analysis -- molecular interaction -- nanoparticle -- radiation absorption
Аннотация: We calculate the quasistatic electromagnetic density of states for aggregates of touching spheres, in particular, linear chains and computer-generated random fractal aggregates. Multipole moments with orders of up to L=64 are taken into account for random aggregates with the number of particles of up to N=100 and up to L=8000 for linear chains. Extensive comparisons with the dipole approximation and geometrical cluster renormalization method are performed. Extinction spectra are calculated for several metals and black carbon. Long wavelength electromagnetic properties of fractal aggregates are considered in details.

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Держатели документа:
Univ Penn, Dept Radiol, Philadelphia, PA 19104 USA
Jackson State Univ, Dept Phys, Jackson, MS 39217 USA
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
Moscow Inst Phys & Technol, Dolgoprudnyi 141700, Russia
Krasnoyarsk State Tech Univ, Dept Phys & Engn, Krasnoyarsk 660028, Russia
Natl Acad Sci Ukraine, Inst Surface Chem, UA-03164 Kiev, Ukraine
ИФ СО РАН
Department of Radiology, University of Pennsylvania, Philadelphia, PA 19104, United States
Department of Physics, Jackson State University, Jackson, MS 39217, United States
L. V. Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk 660036, Russian Federation
Moscow Inst. of Phys. and Technology, Dolgoprudny, Moscow Region 141700, Russian Federation
Dept. of Physics, and Engineering, Krasnoyarsk State Tech. University, Krasnoyarsk 660028, Russian Federation
Institute of Surface Chemistry, Natl. Academy of Sciences of Ukraine, 17 General Naumov St., 03164 Kiev, Ukraine

Доп.точки доступа:
Markel, V. A.; Pustovit, V. N.; Karpov, S. V.; Карпов, Сергей Васильевич; Obuschenko, A. V.; Gerasimov, V. S.; Герасимов, Валерий Сергеевич; Isaev, I. L.; Исаев, Иван Леонидович
}
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10.

    Engineering mode hybridization in regular arrays of plasmonic nanoparticles embedded in 1D photonic crystal / V. S. Gerasimov [et al.] // J. Quant. Spectrosc. Radiat. Transf. - 2019. - Vol. 224. - P. 303-308, DOI 10.1016/j.jqsrt.2018.11.028. - Cited References: 49. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science (Grant No.18-42-240013); by the RF Ministry of Science and Higher Education, the State contract with Siberian Federal University for scientific research in 2017–2019 (Grant No.3.8896.2017); by the Russian Science Foundation (Project No. 18-13-00363 ) (numerical calculations of Rayleigh anomalies in planar structures and corresponding research). . - ISSN 0022-4073
   Перевод заглавия: Управляемая гибридизация мод двумерной решетки внедренной в одномерный фотонный кристалл
Кл.слова (ненормированные):
Surface lattice resonance -- Photonic crystal -- Optical cavity
Аннотация: We analytically and numerically study coupling mechanisms between 1D photonic crystal (PhC) and 2D array of plasmonic nanoparticles (NPs) embedded in its defect layer. We introduce general formalism to explain and predict the emergence of PhC-mediated Wood–Rayleigh anomalies, which spectral positions agree well with the results of exact simulations with Finite-Difference Time-Domain (FDTD) method. Electromagnetic coupling between localized surface plasmon resonance (LSPR) and PhC-mediated Wood–Rayleigh anomalies makes it possible to efficiently tailor PhC modes. The understanding of coupling mechanisms in such hybrid system paves a way for optimal design of sensors, light absorbers, modulators and other types of modern photonic devices with controllable optical properties.

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Держатели документа:
Institute of Computational Modeling SB RAS, Krasnoyarsk, 660036, Russian Federation
Institute of Nanotechnology, Spectroscopy and Quantum Chemistry, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Federal Siberian Research Clinical Centre under FMBA of Russia, Krasnoyarsk, 660037, Russian Federation
Polytechnic Institute, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
The Institute of Optics, University of Rochester, Rochester, NY 14627, United States
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian State University of Science and Technology, Krasnoyarsk, 660014, Russian Federation

Доп.точки доступа:
Gerasimov, V. S.; Герасимов, Валерий Сергеевич; Ershov, A. E.; Ершов, Александр Евгеньевич; Bikbaev, R. G.; Rasskazov, I. L.; Timofeev, I. V.; Тимофеев, Иван Владимирович; Polyutov, S. P.; Karpov, S. V.; Карпов, Сергей Васильевич
}
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11.

Engineering novel tunable optical high-Q nanoparticle array filters for a wide range of wavelengths / A. D. Utyushev, I. L. Isaev, V. S. Gerasimov [et al.] // Opt. Express. - 2020. - Vol. 28, Is. 2. - P. 1426-1438, DOI 10.1364/OE.28.001426. - Cited References: 62. - The reported study was funded by the Russian Science Foundation, project No. 18-13-00363; the grant of the President of Russian Federation for young scientists No. 075-15-2019-676 (calculations of the electromagnetic field configurations in NPs array) . - ISSN 1094-4087
Рубрики:
Nanophotonics, Metamaterials, and Photonic Crystals
Аннотация: The interaction of non-monochromatic radiation with arrays comprising plasmonic and dielectric nanoparticles has been studied using the finite-difference time-domain electrodynamics method. It is shown that LiNbO3, TiO2, GaAs, Si, and Ge all-dielectric nanoparticle arrays can provide a complete selective reflection of an incident plane wave within a narrow spectral line of collective lattice resonance with a Q-factor of 103 or larger at various spectral ranges, while plasmonic refractory TiN and chemically stable Au nanoparticle arrays provide high-Q resonances with moderate reflectivity. Arrays with fixed dimensional parameters make it possible to fine-tune the position of a selected resonant spectral line by tilting the array relative to the direction of the incident radiation. These effects provide grounds for engineering novel selective tunable optical high-Q filters in a wide range of wavelengths, from visible to middle-IR.

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Держатели документа:
Siberian Federal University, Krasnoyarsk 660041, Russia
Siberian State University of Science and Technology, 660014 Krasnoyarsk, Russia
Institute of Computational Modeling, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia
Federal Siberian Research Clinical Center under FMBA of Russia, Krasnoyarsk 660037, Russia
Division of Theoretical Chemistry and Biology, Royal Institute of Technology, SE-100 44 Stockholm, Sweden
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia
The Institute of Optics, University of Rochester, Rochester, NY 14627, USA

Доп.точки доступа:
Utyushev, A. D.; Isaev, I. L.; Gerasimov, V. S.; Ershov, A. E.; Zakomirnyi, V. I.; Закомирный, Вадим Игоревич; Rasskazov, I. L.; Polyutov, S. P.; Полютов, Сергей Петрович; Ågren, H.; Karpov, S. V.; Карпов, Сергей Васильевич
}
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12.

Enhanced sensitivity of an all-dielectric refractive index sensor with an optical bound state in the continuum / D. N. Maksimov, V. S. Gerasimov, A. A. Bogdanov, S. P. Polyutov // Phys. Rev. A. - 2022. - Vol. 105, Is. 3. - Ст. 033518, DOI 10.1103/PhysRevA.105.033518. - Cited References: 49. - The theoretical part of the research was supported by the Ministry of Science and High Education of Russian Federation, Project No. FSRZ-2020-0008, by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science (Grant No. 20-42-240003). The numerical part is supported by the Russian Science Foundation (21-72-30018) . - ISSN 2469-9926
Кл.слова (ненормированные):
Dielectric devices -- Dielectric materials -- Perturbation techniques -- Refractive index
Аннотация: The sensitivity of a refractive index sensor based on an optical bound state in the continuum is considered. Applying Zel'dovich perturbation theory we derived an analytic expression for bulk sensitivity of an all-dielectric sensor utilizing symmetry protected in-Γ optical bound states in a dielectric grating. The upper sensitivity limit is obtained. A recipe is proposed for obtaining the upper sensitivity limit by optimizing the design of the grating. It is shown that the maximal sensitivity can be achieved regardless to the permittivity of the constituent dielectric of the system. The results are confirmed through direct numerical simulations.

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Держатели документа:
IRC SQC, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Institute of Computational Modeling SB RAS, Krasnoyarsk, 660036, Russian Federation
Department of Physics and Engineering, ITMO University, St. Petersburg, 191002, Russian Federation

Доп.точки доступа:
Maksimov, D. N.; Максимов, Дмитрий Николаевич; Gerasimov, V. S.; Bogdanov, A. A.; Polyutov, S. P.
}
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13.

    Infrared bound states in the continuum: random forest method / M. S. Molokeev, A. S. Kostyukov, A. E. Ershov [et al.] // Opt. Lett. - 2023. - Vol. 48, Is. 17. - P. 4460-4463, DOI 10.1364/OL.494629. - Cited References: 42. - Ministry of Science and Higher Education of the Russian Federation (FSRZ-2023-0006) . - ISSN 0146-9592. - ISSN 1539-4794
   Перевод заглавия: Инфракрасные связанные состояния в континууме: метод случайного леса
Кл.слова (ненормированные):
Field enhancement -- Infrared radiation -- Neural networks -- Refractive index -- Second harmonic generation -- Subwavelength gratings
Аннотация: In this Letter, we consider optical bound states in the continuum (BICs) in the infrared range supported by an all-dielectric metasurface in the form of subwavelength dielectric grating. We apply the random forest machine learning method to predict the frequency of the BICs as dependent on the optical and geometric parameters of the metasurface. It is found that the machine learning approach outperforms the standard least square method at the size of the dataset of ≈4000 specimens. It is shown that the random forest approach can be applied for predicting the subband in the infrared spectrum into which the BIC falls. The important feature parameters that affect the BIC wavelength are identified.

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Держатели документа:
IRC SQC, Siberian Federal University, Krasnoyarsk, 660041, Russia
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
Laboratory of Theory and Optimization of Chemical and Technological Processes, University of Tyumen, Tyumen, 625003, Russia
Institute of Computational Modelling SB RAS, Krasnoyarsk, 660036, Russia

Доп.точки доступа:
Molokeev, M. S.; Молокеев, Максим Сергеевич; Kostyukov, A. S.; Ershov, A. E.; Maksimov, D. N.; Максимов, Дмитрий Николаевич; Gerasimov, V. S.; Polyutov, S. P.
}
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14.

Intense charge transfer plasmons in golden nanoparticle dimers connected by conductive molecular linkers / A. S. Fedorov, M. A. Visotin, A. V. Lukyanenko [et al.] // J. Chem. Phys. - 2024. - Vol. 160, Is. 8. - Ст. 084110, DOI 10.1063/5.0183334. - Cited References: 52. - This study was supported by the Russian Science Foundation, Agreement No. 23-12-20007, and the Government of the Krasnoyarsk Territory and the Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activities, Agreement No. 256 . - ISSN 0021-9606. - ISSN 1089-7690
Аннотация: Golden nanoparticle dimers connected by conjugated molecular linkers 1,2-bis(2-pyridyl)ethylene are produced. The formation of stable dimers with 22 nm diameter nanoparticles is confirmed by transmission electron microphotography. The possibility of charge transfer through the linkers between the particles in the dimers is shown by the density functional theory calculations. In addition to localized plasmon resonance of solitary nanoparticles with a wavelength of 530 nm, the optical spectra exhibit a new intense absorption peak in the near-infrared range with a wavelength of ∼780 nm. The emergent absorption peak is attributed to the charge-transfer plasmon (CTP) mode; the spectra simulated within the CTP developed model agree with the experimental ones. This resonant absorption may be of interest to biomedical applications due to its position in the so-called transmission window of biological tissues. The in vitro heating of CTP dimer solution by a laser diode with a wavelength of 792 nm proved the efficiency of CTP dimers for achieving a temperature increase of ΔT = 6 °C, which is sufficient for hyperthermia treatment of malignant tumors. This indicates the possibility of using hyperthermia to treat malignant tumors using the material we synthesized.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia
International Research Center of Spectroscopy and Quantum Chemistry – IRC SQC, Siberian Federal University, 660041 Krasnoyarsk, Russia
Siberian Federal University, 660041 Krasnoyarsk, Russia
Institute of Computational Modeling, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia

Доп.точки доступа:
Fedorov, A. S.; Федоров, Александр Семенович; Visotin, M. A.; Высотин, Максим Александрович; Lukyanenko, A. V.; Лукьяненко, Анна Витальевна; Gerasimov, V. S.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич
}
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15.

Local anisotropy and giant enhancement of local electromagnetic fields in fractal aggregates of metal nanoparticles / S. V. Karpov [et al.] // Phys. Rev. B. - 2005. - Vol. 72, Is. 20. - Ст. 205425, DOI 10.1103/PhysRevB.72.205425. - Cited References: 56 . - ISSN 1098-0121

РУБ Physics, Condensed Matter
Рубрики:
SMALL-PARTICLE COMPOSITES
   DIFFUSION-LIMITED AGGREGATION
   OPTICAL-PROPERTIES
   SELECTIVE PHOTOMODIFICATION
   NUMERICAL-SIMULATION
   DISORDERED CLUSTERS
   ABSORPTION-SPECTRUM
   PARTICULATE MATTER
   NONLINEAR OPTICS
   LIGHT-SCATTERING
Аннотация: We have shown within quasistatic approximation that the giant fluctuations of a local electromagnetic field in random fractal aggregates of silver nanospheres are strongly correlated with a local anisotropy factor S which is defined in this paper. The latter is a purely geometrical parameter which characterizes the deviation of local environment of a given nanosphere in an aggregate from spherical symmetry. Therefore, it is possible to predict the sites with anomalously large local fields in an aggregate without explicitly solving the electromagnetic problem. We have also demonstrated that the average (over nanospheres) value of S does not depend noticeably on the fractal dimension D, except when D approaches the trivial limit D=3. In this case, as one can expect, the average local environment becomes spherically symmetrical and S approaches zero. This corresponds to the well-known fact that in trivial aggregates, fluctuations of local electromagnetic fields are much weaker than in fractal aggregates. Thus, we find that, within the quasistatics, the large-scale geometry does not have a significant impact on local electromagnetic responses in nanoaggregates in a wide range of fractal dimensions. However, this prediction is expected not to be correct in aggregates which are sufficiently large for the intermediate- and radiation-zone interaction of individual nanospheres to become important.

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
Krasnoyarsk State Tech Univ, Dept Phys & Engn, Krasnoyarsk 660028, Russia
Univ Penn, Dept Radiol, Philadelphia, PA 19104 USA
Univ Penn, Dept Bioengn, Philadelphia, PA 19104 USA
ИФ СО РАН
L. V. Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk 660036, Russian Federation
Department of Physics and Engineering, Krasnoyarsk State Technical University, Krasnoyarsk 660028, Russian Federation
Departments of Radiology and Bioengineering, University of Pennsylvania, Philadelphia, PA 19104, United States

Доп.точки доступа:
Karpov, S. V.; Карпов, Сергей Васильевич; Gerasimov, V. S.; Герасимов, Валерий Сергеевич; Isaev, I. L.; Исаев, Иван Леонидович; Markel, V. A.
}
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16.

    Medium dependent optical response in ultra-fine plasmonic nanoparticles / L. K. Sorensen, D. E. Khrennikov, V. S. Gerasimov [et al.] // Phys. Chem. Chem. Phys. - 2022. - Vol. 24, Is. 39. - P. 24062-24075, DOI 10.1039/d2cp02929d. - Cited References: 52. - DEK, VSG, SVK acknowledge the support of the Russian Science Foundation (project no. 18-13-00363). L. K. S. acknowledges the support of Carl Tryggers Stiftelse, project CTS 18-441. We also acknowledge the Swedish National Infrastructure for Computing (SNIC) at the High Performance Computing Center North (HPC2N) partially funded by the Swedish Research Council through grant agreement no. 2021/3-22 . - ISSN 1463-9084
   Перевод заглавия: Зависимость оптического отклика сверхмалых плазмонных наночастиц от окружающей среды
Аннотация: We study the influence of media on the interaction of ultra-fine plasmonic nanoparticles (≤ 8 nm) with radiation. The important role of the surface layer of the nanoparticles, with properties that differ from the ones in the inner part, is established. Using an atomistic representation of the nanoparticle material and its interaction with light, we find a highly inhomogeneous distribution of the electric field inside and around the particles. It is predicted that with an increase in the refractive index of the ambient medium, the extension of the surface layer of atoms increases, something that also is accompanied by an enhanced red shift of the plasmon resonance band compared to large particles in which the influence of this layer and its relative volume is reduced. It is shown that the physical origin for the formation of a surface layer of atoms near the nanoparticle boundary is related to the anisotropy of the local environment of atoms in this layer which changes the conditions for the interaction of neighboring atoms with each other and with the incident radiation. It is shown that a growth of the refractive index of the ambient medium results in an increase in the local field in the dielectric cavity in which a plasmonic nanoparticle is embedded and which is accompanied by a growth of the amplitude of the plasmon resonance. We predict that in the ultra-fine regime the refractive index sensitivity shows a decreasing trend with respect to size which is opposite to that for larger particles. With the applied atomistic model this work demonstrates close relations between field distributions and properties of ultra-fine nanoparticles.

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Держатели документа:
Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala, Sweden. lasse.kragh.soerensen@gmail.com
Department of Theoretical Chemistry and Biology, School of Engineering Sciences in Chemistry, Biotechnology and Health, Royal Institute of Technology, Stockholm, SE-10691, Sweden
University Library, University of Southern Denmark, DK-5230 Odense M, Denmark
International Research Center of Spectroscopy and Quantum Chemistry, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Institute of Computational Modelling, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Federal Siberian Research Clinical Centre under FMBA of Russia, 660037, Kolomenskaya, 26 Krasnoyarsk, Russia
L. V. Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Sorensen, L. K.; Khrennikov, D. E.; Gerasimov, V. S.; Ershov, A. E.; Polyutov, S. P.; Karpov, S. V.; Карпов, Сергей Васильевич; Agren, H.
}
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17.

Mode coupling in arrays of Al nanoparticles / A. E. Ershov, V. S. Gerasimov, R. G. Bikbaev [et al.] // J. Quant. Spectrosc. Radiat. Transf. - 2020. - Vol. 248. - Ст. 106961, DOI 10.1016/j.jqsrt.2020.106961. - Cited References: 81. - The reported study was funded by the grant of the President of Russian Federation (agreement 075-15-2019-676 ); the Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science (Grant No.18-42-240013); the State contract with Siberian Federal University for scientific research; Russian Science Foundation project number 19-72-00066 (investigation of finite size effects) . - ISSN 0022-4073
Кл.слова (ненормированные):
Plasmonics -- Aluminum -- Surface lattice resonances
Аннотация: The mechanisms of coupling between the lattice modes of a two-dimensional (2D) array consisting of Al nanoparticles and the localized modes of individual Al nanoparticles have been studied in detail. The results were obtained employing the finite-difference time-domain method (FDTD) and the generalized Mie theory. It was shown that interactions of single particles with 2D lattice modes significantly change the extinction spectra depending on the particle radius and the lattice period. The Rayleigh anomalies of higher orders contribute to formation of hybrid modes resulting in increase of the extinction efficiency in short wavelength range of the spectrum. It was shown that high intensity magnetic modes are excited in aluminum nanoparticles arrays. The patterns of spatial electromagnetic field distribution at the frequencies of hybrid modes have been studied. We note that comprehensive understanding the mode coupling mechanisms in arrays paves the way for engineering different types of modern photonic devices with controllable optical properties.

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Держатели документа:
Institute of Computational Modeling SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
L.V. Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian State University of Science and Technology, Krasnoyarsk, 660014, Russian Federation

Доп.точки доступа:
Ershov, A. E.; Gerasimov, V. S.; Bikbaev, R. G.; Бикбаев, Рашид Гельмединович; Polyutov, S. P.; Karpov, S. V.; Карпов, Сергей Васильевич
}
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18.

Mode coupling in arrays of Al nanoparticles [Preprint] / A. E. Ershov, V. S. Gerasimov, R. G. Bikbaev [et al.]. - Electronic text data // ArXiv. - 2020. - Ст. 1912.12830. - Cited References: 78. - The reported study was funded by the Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science (Grant No.18-42-240013); A.E. thanks the grant of the President of Russian Federation (agreement 075-15-2019-676)
Кл.слова (ненормированные):
plasmonics -- aluminum -- surface lattice resonances
Аннотация: The mechanisms of coupling between the lattice modes of a two-dimensional (2D) array consisting of Al nanoparticles and the localized modes of individual Al nanoparticles have been studied in detail. The results have been obtained employing the finite time difference method (FDTD) and the generalized Mie theory. It was shown that interactions of single particles with 2D lattice modes significantly change the extinction spectra depending on the particle radius and the lattice period. The Rayleigh anomalies of higher orders contribute to formation of hybrid modes resulting in increase of the extinction efficiency in short wavelength range of the spectrum. The patterns of spatial electromagnetic field distribution at the frequencies of hybrid modes have been studied. We note that comprehensive understanding the mode coupling mechanisms in arrays paves the way for engineering different types of modern photonic devices with controllable optical properties.

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Держатели документа:
Institute of Computational Modeling SB RAS, Krasnoyarsk 660036, Russia
Siberian Federal University, Krasnoyarsk, 660041, Russia
L.V. Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036, Krasnoyarsk, Russia
Siberian State University of Science and Technology, 660014, Krasnoyarsk, Russia

Доп.точки доступа:
Ershov, A. E.; Gerasimov, V. S.; Bikbaev, R. G.; Бикбаев, Рашид Гельмединович; Polyutov, S. P.; Полютов, Сергей Петрович; Karpov, S. V.; Карпов, Сергей Васильевич
}
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19.

Multilayered gold nanoshells with ideal absorption for plasmonic photothermal therapy / V. I. Zakomirnyi [et al.] // Журнал прикладной спектроскопии. - 2016. - Т. 83, Вып. 6-16. - P. 177-178 . - ISSN 0514-7506
Аннотация: We study multilayered spherical nanoparticles with ideal absorption [1] for biomedical applications. The core of such particles consists of Si, SiO2 or alternative plasmonic materials [2], such as zinc oxide doped with aluminum, gallium and indium tin oxide whereas the outer shell consists of gold. We develop the algorithm for finding optimal geometry of ideally absorbing Au nanoparticles taking into account the quantum size effect that in multilayered metallic nanoshells plays a significant role.

РИНЦ

Доп.точки доступа:
Zakomirnyi, V .I.; Rasskazov, I. L.; Gerasimov, V. S.; Герасимов, Валерий Сергеевич; Ershov, A. E.; Ершов, Александр Евгеньевич; Karpov, S. V.; Карпов, Сергей Васильевич; Polyutov, S. P.; International Conference on Coherent and Nonlinear Optics(2016 ; Sept. ; 26-30 ; Minsk, Belarus); International Conference on Lasers, Applications, and Technologies(2016 ; Sept. ; 26-30 ; Minsk, Belarus)
}
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20.

    Nature of the anomalous size dependence of resonance red shifts in ultrafine plasmonic nanoparticles / L. K. Sorensen, D. E. Khrennikov, V. S. Gerasimov [et al.] // J. Phys. Chem. C. - 2022. - Vol. 126, Is. 39. - P. 16804-16814, DOI 10.1021/acs.jpcc.2c03738. - Cited References: 61. - D.K., V.G., A.E., S.P., and S.K. acknowledge the support by the Russian Science Foundation (project no. 18-13-00363). L.K.S acknowledges the support of Carl Tryggers Stifetelse, project CTS 18-441. The authors also acknowledge the Swedish National Infrastructure for Computing (SNIC) at the High Performance Computing Center North (HPC2N) partially funded by the Swedish Research Council through grant agreement no. 2020/3-29 . - ISSN 1932-7447
   Перевод заглавия: Природа аномальной размерной зависимости резонансных длинноволновых сдвигов в сверхмалых плазмонных наночастицах
Аннотация: Plasmonic red shifts of nanoparticles are commonly used in imaging technologies to probe the character of local environments, and the understanding of their dependence on size, shape, and surrounding media has therefore become an important target for research. The red shift of plasmon resonances changes character at about 8-10 nm of size for spherical gold nanoparticles above this value, the red shift progresses linearly with particle size, while below this size, the red shift changes nonlinearly and more strongly with size. Using an atomistic discrete interaction model, we have studied the special properties of the nanoparticle surface layers and discovered its importance for ultrafine plasmonic nanoparticles and their red shifts. We find that the physical origin for the specific properties inherent to the surface layer of atoms near the nanoparticle boundary is related to the anisotropy of the local environment of atoms in this layer by other atoms. The anisotropy changes the conditions for light-induced nonlocal interactions of neighboring atoms with each other and with the incident radiation compared to the atoms located in the particle core with isotropic nearest surroundings by other atoms. The local anisotropy of the nanoparticle crystal lattice is a geometric factor that increases toward its boundary and that is the most fundamental factor underlying the physical differences between the nanoparticle surface layer and the core material. It is shown that the inflexion point at 8-10 nm is due to a change in the dominant physical origin of the red shift from chaotization of atomically light-induced dipoles within the surface layer in the case of ultrafine nanoparticles to retardation effects for large nanoparticles in which the relative volume of the surface layer decreases rapidly to a negligible value with increasing nanoparticle size. The patterns revealed are the basis for predicting the manifestation of surface layer effects in ultrafine plasmonic nanoparticles of different shapes and composed of different plasmonic materials.

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Держатели документа:
Department of Physics and Astronomy, Uppsala University, Box 516, Uppsala, SE-751 20, Sweden
Department of Theoretical Chemistry and Biology, School of Engineering Sciences in Chemistry, Biotechnology and Health, Royal Institute of Technology, Stockholm, SE-10691, Sweden
University Library, University of Southern Denmark, Odense M, DK-5230, Denmark
International Research Center of Spectroscopy and Quantum Chemistry, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Federal Research Center KSC SB RAS, Institute of Computational Modelling, Krasnoyarsk, 660036, Russian Federation
Federal Siberian Research Clinical Centre under FMBA of Russia, 26 Krasnoyarsk, Kolomenskaya660037, Russian Federation
Federal Research Center KSC SB RAS, L. V. Kirensky Institute of Physics, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Sorensen, L. K.; Khrennikov, D. E.; Gerasimov, V. S.; Ershov, A. E.; Polyutov, S. P.; Karpov, S. V.; Карпов, Сергей Васильевич; Agren, H.
}
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