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Solovyov, L. A.
Complete crystal structure of decafluorocyclohex-1-ene at 4.2 K from original neutron diffraction data / L. A. Solovyov, A. S. Fedorov, A. A. Kuzubov // Acta Crystallogr. B. - 2014. - Vol. 70. - P. 395-397, DOI 10.1107/S2052520613031028. - Cited References: 20 . - ISSN 0108-7681. - ISSN 1600-5740

РУБ Crystallography
Рубрики:
AUGMENTED-WAVE METHOD
   POWDER DIFFRACTION
   NORMAL-BUTANE
   REFINEMENT
   DISORDER
Аннотация: The crystal structure model of decafluorocyclohex-1-ene at 4.2 K derived from simulated powder diffraction data and solid-state energy minimization [Smrcok et al. (2013). Acta Cryst. B69, 395-404] is found to be incomplete. In this study it is completed by an additional alternative molecular orientation revealed from the difference density analysis and direct space search. The structure is refined by the derivative difference method in the rigid-body approximation leading to perfect agreement between observed and calculated neutron powder patterns.

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Держатели документа:
Inst Chem & Chem Technol, Krasnoyarsk 660036, Russia
LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Krasnoyarsk Railway Transport Inst, Krasnoyarsk 660028, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia;ИХХТ СО РАН

Доп.точки доступа:
Fedorov, A. S.; Федоров, Александр Семенович; Kuzubov, A. A.; Кузубов, Александр Александрович; Соловьев, Леонид Александрович
}
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Effect of cation substitution in fluorine-oxygen molybdates (NH4)(2-x) A (x) MoO2F4 / E. V. Bogdanov [et al.] // Phys. Solid State. - 2011. - Vol. 53, Is. 2. - P. 303-308, DOI 10.1134/S1063783411020065. - Cited References: 11. - This study was supported by the Russian Foundation for Basic Research (project no. 09-02-00062) and the Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools of the Russian Federation (project no. NSh-1011.2008.2). . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
PHASE-TRANSITIONS
   CRYSTALS
   (NH4)(2)WO2F4
   DIFFRACTION
   OXYFLUORIDE
   MECHANISM
   DISORDER
Аннотация: Thermophysical and structural studies of (NH4)(2 - x) A (x) MoO2F4 (A = Cs, Rb, K) solid solutions of oxyfluorides have been performed. The character of the influence of cation substitutions on the stability of the initial phase (space group Cmcm) and on the mechanism of phase transitions has been elucidated.

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Держатели документа:
[Bogdanov, E. V.
Vasil'ev, A. D.
Flerov, I. N.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Vasil'ev, A. D.
Flerov, I. N.] Siberian Fed Univ, Inst Engn Phys & Radioelect, Krasnoyarsk 660074, Russia
[Laptash, N. M.] Russian Acad Sci, Inst Chem, Far Eastern Branch, Vladivostok 690022, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Institute of Engineering Physics and Radioelectronics, Siberian Federal University, ul. Kirenskogo 28, Krasnoyarsk 660074, Russian Federation
Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok 690022, Russian Federation

Доп.точки доступа:
Bogdanov, E. V.; Богданов, Евгений Витальевич; Vasil'ev, A. D.; Васильев, Александр Дмитриевич; Flerov, I. N.; Флёров, Игорь Николаевич; Laptash, N. M.
}
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Ignatchenko, V. A.
Effect of the correlation properties of one- and three-dimensional inhomogeneities on the high-frequency magnetic susceptibility of sinusoidal superlattices / V. A. Ignatchenko, Y. I. Mankov // Phys. Solid State. - 2005. - Vol. 47, Is. 3. - P. 587-594, DOI 10.1134/1.1884725. - Cited References: 29 . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
PERIODIC MULTILAYERS
   WAVE SPECTRUM
   SPIN-WAVES
   LOCALIZATION
   SYSTEMS
   DISORDER
Аннотация: The effect of one-(1D) and three-dimensional (3D) inhomogeneities on the high-frequency magnetic susceptibility at the boundary of the first Brillouin zone of a ferromagnetic superlattice is studied. The study is performed with an earlier developed method of random spatial modulation (RSM) of the superlattice period. In this method, structural inhomogeneities are described in terms of the random-phase model, in which the phase depends on three coordinates in the general case. The frequency spacing Delta v(m) between two peaks in the imaginary part of the averaged Green's function, which characterizes the gap width in the frequency spectrum at the boundary of the Brillouin zone, is calculated as a function of both the root-mean-square fluctuations gamma(i) and the correlation wavenumbers eta(i) of phase inhomogeneities (i = 1 and 3 for 1D and 3D inhomogeneities, respectively). The function Delta v(m)(gamma(1), eta(1)) for 1D inhomogeneities is shown to be symmetric with respect to inter- changing the variables gamma(1)(2) and eta(1), whereas the function Delta v(m)(gamma(3), eta(3)) for 3D inhomogeneities is strongly asym- metric with respect to interchanging gamma(3)(2) eta(3). This effect is associated with the difference in form between the correlation functions of 1D and 3D inhomogeneities and can be used to determine the dimensionality of inhomogeneities from the results of spectral studies of such superlattices. (c) 2005 Pleiades Publishing, Inc.

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Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Siberian Div, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, Akademgorodok, 660036, Russian Federation

Доп.точки доступа:
Mankov, Y. I.; Игнатченко, Вальтер Алексеевич
}
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Ignatchenko, V. A.
Effects of cross correlations between 1D and 3D inhomogeneities on the high-frequency susceptibility of superlattices / V. A. Ignatchenko, Y. I. Mankov // J. Exp. Theor. Phys. - 2006. - Vol. 102, Is. 4. - P. 625-635, DOI 10.1134/S106377610604011X. - Cited References: 29 . - ISSN 1063-7761

РУБ Physics, Multidisciplinary
Рубрики:
ELASTIC MEDIUM THEORY
   3-DIMENSIONAL INHOMOGENEITIES
   PERIODIC MULTILAYERS
   SPIN-WAVES
   LOCALIZATION
   SPECTRUM
   SYSTEMS
   MEDIA
   DISORDER
Кл.слова (ненормированные):
Correlation methods -- Damping -- Function evaluation -- Wave equations -- Brillouin zone -- Distribution function -- Random variables -- Superlattices
Аннотация: Cross Correlations between components of a mixture of one-dimensional (I D) and three-diniensional (3D) inhomogenetics are described by introducing a distribution function taking into account correlations between absolute values of two random variables in the absence of correlations between the variables themselves. This distribution function is used for derivation and analysis of the superlattice correlation function containing a mixture of cross-correlated 1D and 3D in homogeneitics. The effect of such inhomogeneities on the high-frequency susceptibility at the edge of the first Brillouin zone of the superlattice is investigated. It is shown that positive cross correlations partly suppress the effect of a mixture of 1D and 3D inhomogeneities on the wave spectrum: the gap at the boundary of the Brillouin zone increases, and wave damping decreases as compared to the effect produced by a mixture of 1D and 3D inhomogeneities in the absence of cross correlations. Negative cross correlations lead to the opposite effect: the gap decreases and wave damping increases. Cross correlations also lead to the emergence of new resonance effects: a narrow dip or a narrow peak at the center of the band gap (depending on the sign of the correlation factor).

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Держатели документа:
Russian Acad Sci, Kirenskii Inst Phys, Siberian Div, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirenskii Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Mankov, Y. I.; Игнатченко, Вальтер Алексеевич
}
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Ignatchenko, V. A.
Effects of one- and three-dimensional inhomogeneities on the wave spectrum of multilayers with finite interface thicknesses / V. A. Ignatchenko, Y. I. Mankov, A. A. Maradudin // Phys. Rev. B. - 2002. - Vol. 65, Is. 2. - Ст. 24207, DOI 10.1103/PhysRevB.65.024207. - Cited References: 24 . - ISSN 1098-0121

РУБ Physics, Condensed Matter
Рубрики:
PERIODIC MULTILAYERS
   SPIN-WAVES
   LOCALIZATION
   SUPERLATTICES
   SYSTEMS
   DISORDER
   AVERAGE
   MEDIA
Аннотация: To describe a partially randomized multilayer structure with arbitrary thicknesses of the interfaces between layers, we introduce a model in which the dependence of a material parameter along the axis of such a Superlattice is described by a Jacobian elliptic sine function with a random spatial modulation of its period. Both one- and three-dimensional inhomogeneities of the period are considered. We develop the correlation function for this model, and investigate the dispersion law and damping of averaged waves in this superlattice. The dependencies of the widths of the gaps in the spectrum and the damping at the boundaries of all odd Brillouin zones, on the thicknesses of the interfaces, and on the dimensionality, intensity, and correlation wave number of the inhomogeneities are found. It is shown that experimental investigations of the widths of the gaps and damping for several Brillouin zones could permit, in principle, determining all parameters of the superlattice as well as the parameters of the inhomogeneities from these spectral characteristics.

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Держатели документа:
LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Univ Calif Irvine, Dept Phys & Astron, Irvine, CA 92697 USA
ИФ СО РАН

Доп.точки доступа:
Mankov, Y. I.; Maradudin, A. A.; Игнатченко, Вальтер Алексеевич
}
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Ignatchenko, V. A.
Effects of the dimensionality of inhomogeneities on the wave spectrum of superlattices / V. A. Ignatchenko, Y. I. Mankov, A. A. Maradudin // Phys. Rev. B. - 2003. - Vol. 68, Is. 2. - Ст. 24209, DOI 10.1103/PhysRevB.68.024209. - Cited References: 26 . - ISSN 1098-0121

РУБ Physics, Condensed Matter
Рубрики:
ELASTIC MEDIUM THEORY
   PERIODIC MULTILAYERS
   SPIN-WAVES
   LOCALIZATION
   SYSTEMS
   MEDIA
   DISORDER
Аннотация: Dependences of the dispersion laws and damping of waves in an initially sinusoidal superlattice on the dimensionality of inhomogeneities modulating the period of the superlattice are studied. The cases of one- and three-dimensional modulations, as well as modulation by a mixture of inhomogeneities of both of these dimensionalities, are considered. The correlation function of the superlattice K(r) has the form of a product of the same periodic function and a decreasing function that is significantly different for these different cases. For r -- infinity the decreasing function goes to zero for the one-dimensional inhomogeneities and to a nonzero asymptote for the three-dimensional ones. Consequently, the transition from the disordered to ordered states is accompanied in the three-dimensional case not only by an increase of the correlation radius as in the one-dimensional case, but also by a change in the relationship between the volumes of the superlattices with finite and infinite correlation radii. The decreasing part of the correlation function for the mixture of inhomogeneities of different dimensionalities has the form of a product of the decreasing parts of the correlation functions of the components of the mixture. This leads to the nonadditivity of the contributions of the components of different dimensionalities to the resulting modification of the parameters of the wave spectrum that are due to the inhomogeneities (the damping of waves for the mixture of these components is smaller than the sum of the dampings of the components, the maximum gap in the spectrum corresponds to the simultaneous presence of both components, and so on).

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Держатели документа:
LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Univ Calif Irvine, Dept Phys & Astron, Irvine, CA 92697 USA
ИФ СО РАН

Доп.точки доступа:
Mankov, Y. I.; Maradudin, A. A.; Игнатченко, Вальтер Алексеевич
}
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Ignatchenko, V. A.
Effects of the mixture of one- and three-dimensional inhomogeneities on the wave spectrum of superlattices / V. A. Ignatchenko, Y. I. Mankov, A. A. Maradudin // JETP Letters. - 2003. - Vol. 77, Is. 6. - P. 285-290, DOI 10.1134/1.1577758. - Cited References: 24 . - ISSN 0021-3640

РУБ Physics, Multidisciplinary
Рубрики:
PERIODIC MULTILAYERS
   SPIN-WAVES
   LOCALIZATION
   SYSTEMS
   THICKNESSES
   DISORDER
   AVERAGE
   MEDIA
Аннотация: Dependences of the dispersion laws and damping of waves in an initially sinusoidal superlattice on the dimensionality of inhomogeneities modulating the period of the superlattice are studied. The cases of one- and three-dimensional modulations, as well as modulation by a mixture of inhomogeneities of both of these dimensionalities, are considered. The correlation function of the superlattice K(r) has the form of a product of the same periodic function and a decreasing function that is significantly different for these different cases. The decreasing part of the correlation function for the mixture of inhomogeneities of different dimensionalities has the form of a product of the decreasing parts of the correlation functions of the components of the mixture. This leads to the nonadditivity of the contributions of the components of different dimensionalities to the resulting modification of the parameters of the wave spectrum that are due to the inhomogeneities (the damping of waves for the mixture of these components is smaller than the sum of the dampings of the components, the maximum gap in the spectrum corresponds to the simultaneous presence of both components of the mixture, not only of the three-dimensional inhomogeneities). (C) 2003 MAIK "Nauka / Interperiodica".

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Держатели документа:
LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Univ Calif Irvine, Dept Phys & Astron, Irvine, CA 92697 USA
ИФ СО РАН
Kirensky Institute of Physics, Krasnoyarsk, 660036, Russian Federation
Department of Physics and Astronomy, University of California, Irvine, CA 92697, United States

Доп.точки доступа:
Mankov, Y. I.; Maradudin, A. A.; Игнатченко, Вальтер Алексеевич
}
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Ignatchenko, V. A.
High-Frequency Susceptibility of a Superlattice with 2D Inhomogeneities / V. A. Ignatchenko, Y. I. Mankov, D. S. Tsikalov // J. Exp. Theor. Phys. - 2008. - Vol. 107, Is. 4. - P. 603-611, DOI 10.1134/S1063776108100075. - Cited References: 26. - This work was supported in part by grant no. 3818.2008.3 from the President of Russia in accordance with the program supporting leading scientific schools. . - ISSN 1063-7761

РУБ Physics, Multidisciplinary
Рубрики:
SPIN-WAVE SUSCEPTIBILITY
   PERIODIC MULTILAYERS
   LOCALIZATION
   SYSTEMS
   SPECTRUM
   DISORDER
   MEDIA
Кл.слова (ненормированные):
Energy conservation -- Energy gap -- Energy management -- Frequency bands -- Gallium alloys -- Green's function -- Probability density function -- Three dimensional -- Band gaps -- Energy conservation laws -- Green functions -- High frequencies -- Imaginary parts -- Magnon crystals -- Scattered waves -- Superlattice layers -- Wave spectrums -- Phase interfaces
Аннотация: We investigate the high-frequency susceptibility (Green function) of an initially sinusoidal 1D superlattice with 2D phase inhomogeneities that model the deformations of the interfaces between the superlattice layers. For waves propagating along the superlattice axis ( the geometry of a photon or magnon crystal), we have found a peculiar behavior of the imaginary part of the Green function that consists in a significant difference between the peaks corresponding to the edges of the band gap in the wave spectrum. The peak corresponding to the lower-frequency band edge remains essentially unchanged as the root-mean-square fluctuation of the 2D inhomogeneities. 2 increases, while the peak corresponding to the higher-frequency band edge broaden and decreases sharply in height until its complete disappearance with increasing gamma(2). This behavior of the peaks corresponds to a band gap closure mechanism that differs from the traditional one characteristic of 1D and 3D inhomogeneities. These effects can be explained by a peculiarity of the energy conservation laws for the incident and scattered waves for 2D inhomogeneities in a 1D superlattice.

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Держатели документа:
[Ignatchenko, V. A.
Mankov, Yu. I.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Mankov, Yu. I.
Tsikalov, D. S.] Siberian Fed Univ, Krasnoyarsk 660062, Russia
ИФ СО РАН
L.V. Kirenskii Institute of Physics, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk 660036, Russian Federation
Siberian Federal University, Krasnoyarsk 660062, Russian Federation

Доп.точки доступа:
Mankov, Y. I.; Tsikalov, D. S.; Цикалов, Денис Сергеевич; Игнатченко, Вальтер Алексеевич
}
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Martynov, S. N.
Incommensurate magnetic structures in rhombohedral Heisenberg antiferromagnet / S. N. Martynov // JETP Letters. - 2013. - Vol. 98, Is. 1. - P. 19-23, DOI 10.1134/S0021364013140099. - Cited References: 31 . - 5. - ISSN 0021-3640
Рубрики:
DISORDER
Аннотация: The phase diagram of the ground state has been calculated for a rhombohedral antiferromagnet of the R3m symmetry with frustrated exchange in the base plane and competition of exchanges between the nearest and next-nearest planes. The diagram contains phases of collinear antiferromagnetic ordering of various types separated by five incommensurate magnetic states of the helicoidal type, differing in the ordering type and in the direction of the modulation vector. The commensurate and incommensurate phases converge at multi-critical points lying on a line corresponding to an antiferromagnet with an undistorted simple cubic lattice.

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Публикация на русском языке Несоизмеримые магнитные структуры ромбоэдрического гейзенберговского антиферромагнетика. - [S. l. : s. n.]

Доп.точки доступа:
Мартынов, Сергей Николаевич
}
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10.

Influence of the molecular groups ordering on structural phase transitions in (NH4)2WO2F4 crystal / A. S. Krylov [et al.] // Cryst. Growth Des. - 2014. - Vol. 14, Is. 1. - P. 374-380, DOI 10.1021/cg400899m. - Cited References: 27. - This work was partly supported by the Russian Foundation for the Basic Research project no. 12-02-00056, no. 13-02-00825, and integration project SB RAS no. 28, SS-4828.2012.2. - Published as part of the Crystal Growth & Design virtual special issue Anion-controlled New Inorganic Materials. . - ISSN 1528-7483. - ISSN 1528-7505

РУБ Chemistry, Multidisciplinary + Crystallography + Materials Science, Multidisciplinary
Рубрики:
RAMAN-SCATTERING
   NEUTRON-SCATTERING
   SOLID-STATE
   OXYFLUORIDES
   DISORDER
   POLAR
   ANION
Аннотация: Phase transitions of the (NH4)2WO2F 4 crystal were studied by Raman spectroscopy in the range from 10 to 350 K. The mechanism of two phase transitions at T1 = 201 and T 2 = 160 K was proposed. The significant spectra changes occur in the range corresponding to the W-O vibrations. The first temperature phase transition is due to the ordering of the quasi-octahedral groups [WO 2F4]2- and partial ordering of ammonium groups. Experimental data allow for attributing the first (T1 = 201 K) phase transition to the first order close to the tricritical point. The noticeable changes of the Raman spectrum have been found in the range corresponding to the ammonium vibrations below the temperature T2. The second phase transition is associated with the further ordering of ammonium groups. Room temperature (296 K) experiments have been carried out under high hydrostatic pressure up to 10 GPa. Above 2 GPa, new spectral features appear, allowing for the assumption of the existence of a new high-pressure phase of (NH 4)2WO2F4, which is mainly connected with ordering of the [WO2F4]2- quasi-octahedral groups.

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Держатели документа:
Kirensky Inst Phys SB RAS, Krasnoyarsk 660036, Russia
Inst Geol & Mineral SB RAS, Novosibirsk 630090, Russia
Inst Chem FEB RAS, Vladivostok 690022, Russia

Доп.точки доступа:
Krylov, A. S.; Крылов, Александр Сергеевич; Goryainov, S. V.; Laptash, N. M.; Vtyurin, A. N.; Втюрин, Александр Николаевич; Mel'nikova, S. V.; Мельникова, Светлана Владимировна; Krylova, S. N.; Крылова, Светлана Николаевна
}
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11.

Zhandun, V. S.
Lattice dynamics and the ferroelectric phase transition in ordered Pb-2 B'BaEuro(3)O(6) (B' = Ga, In, Lu; BaEuro(3) = Nb, Ta) solid solutions / V. S. Zhandun, N. G. Zamkova, V. I. Zinenko // Phys. Solid State. - 2010. - Vol. 52, Is. 2. - P. 357-363, DOI 10.1134/S1063783410020228. - Cited References: 19. - This study is supported by the Russian Foundation for Basic Research (project no. 09-02-00067) and the Council on Grants from the President of the Russian Federation for Support of the Leading Scientific Schools (grant no. NSh-4137.2006.2). . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
PEROVSKITES
   CRYSTALS
   DISORDER
   RELAXOR
   BATIO3
   PBTIO3
Аннотация: The lattice vibration spectrum, rf permittivity, and dynamic Born charges have been calculated for ordered Pb-2 B'BaEuro(3)O(3) (B'=Ga, In, Lu; BaEuro(3)=Nb, Ta) solid solutions in terms of the generalized Gordon-Kim model. It has been shown that all compounds exhibit a ferroelectric instability and that the frequencies of "soft" ferroelectric modes are close in magnitude. The ferroelectric phase-transition temperatures and the spontaneous polarization in the ferroelectric phase of the solid solutions under consideration have been calculated by the Monte Carlo method using the model Hamiltonian in the local mode approximation. The transition temperature is found to increase with increasing atomic number of the B' ion.

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Держатели документа:
[Zhandun, V. S.
Zamkova, N. G.
Zinenko, V. I.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Zamkova, N. G.; Замкова, Наталья Геннадьевна; Zinenko, V. I.; Зиненко, Виктор Иванович; Жандун, Вячеслав Сергеевич
}
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12.

Lattice dynamics of oxyfluoride Rb2KMoO3F3 / A. S. Krylov [et al.] // Ferroelectrics. - 2012. - Vol. 441. - P. 52-60, DOI 10.1080/00150193.2012.743791. - Cited References: 23 . - ISSN 0015-0193

РУБ Materials Science, Multidisciplinary + Physics, Condensed Matter
Рубрики:
PHASE-TRANSITIONS
   RAMAN-SCATTERING
   ELPASOLITE
   CRYSTALS
   DISORDER
   SPECTRA
   CS
Кл.слова (ненормированные):
Oxyfluorides -- lattice dynamics -- Ramam measurements
Аннотация: The complete Raman spectra of oxyfluoride Rb2KMoO 3F3 were obtained. At T ≈ 185 K phase transitions were found. Lattice dynamics of disordered structures of the investigated compound was simulated, and "soft" vibrational modes were found in the calculated spectrum. Copyright © Taylor & Francis Group, LLC.

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Доп.точки доступа:
Krylov, A. S.; Крылов, Александр Сергеевич; Sofronova, S. N.; Софронова, Светлана Николаевна; Kolesnikova, E. M.; Колесникова, Евгения Михайловна; Vtyurin, A. N.; Втюрин, Александр Николаевич; Isaenko, L. I.; International Symposium on Ferroic Domains and Micro- to Nanoscopic Structures(11th ; 20-24 Aug. 2012 ; Ekaterinburg, Russia); Russia/CIS/Baltic/Japan Symposium on Ferroelectricity(11 ; 2012 ; Aug. ; 20-24 ; Ekaterinburg)
}
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13.

Optical and X-ray Diffraction Studies of the Symmetry of Distorted Phases of the (NH4)(3)ZrF7 Crystal / S. V. Misyul [et al.] // Phys. Solid State. - 2008. - Vol. 50, Is. 10. - P. 1951-1956, DOI 10.1134/S1063783408100272. - Cited References: 12. - This work was supported by the Council on Grants from the President of the Russian Federation (project NSh-4137.2006.2). . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
AMMONIUM HEPTAFLUOROZIRCONATE
   DISORDER
   TRANSITION
   K3ZRF7
Аннотация: (NH4)(3)ZrF7 single crystals were grown, and polarization-optical and x-ray diffraction studies were performed on powders and crystalline plates of various cuts over a wide temperature range. Phase transitions are revealed at temperatures T-1 up arrow = 280 K, T-2 up arrow = 279.6 K, T-3 up arrow = 260-265 K, and T-4 up arrow = 238 K on heating and at T-1 down arrow = 280 K, T-2 down arrow = 269-270 K, T-3 down arrow = 246 K, and T-4 down arrow = 235 K on cooling. The sequence of changes in symmetry is established to be as follows: O-h(5) (Z = 4)↔ D-2h(25) (Z = 2) ↔ C-2h(3) (Z = 2)↔ C-i(1) (Z = 108)↔ monoclinic(2) (Z = 216).

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Держатели документа:
[Misyul, S. V.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
[Mel'nikova, S. V.
Bovina, A. F.] Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Laptash, N. M.] Russian Acad Sci, Inst Chem, Far E Div, Vladivostok 690022, Russia
ИФ СО РАН
Siberian Federal University, Svobodnyi pr. 59, Krasnoyarsk 660041, Russian Federation
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok 690022, Russian Federation

Доп.точки доступа:
Misyul, S. V.; Мисюль, Сергей Валентинович; Mel'nikova, S. V.; Мельникова, Светлана Владимировна; Bovina, A. F.; Бовина, Ася Федоровна; Laptash, N. M.
}
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14.

Optical studies of phase transitions in the (NH4)(3)Ti(O-2)F-5 crystal / S. V. Mel'nikova [et al.] // Phys. Solid State. - 2009. - Vol. 51, Is. 4. - P. 817-822, DOI 10.1134/S1063783409040301. - Cited References: 13. - This work was supported by the Council on Grants from the President of the Russian Federation (project no. NSh-1011.2008.2), the Russian Foundation for Basic Research (project no. 06-02-16102), and RFBR Enisei (project no. 07-02-096800). . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
(NH4)(3)WO3F3 OXYFLUORIDE
RAMAN-SCATTERING
DISORDER
Аннотация: Polarization-optical study of twinning and measurements of the Raman spectra and birefringence in oxyfluoride (NH4)(3)Ti(O-2)F-5 were carried out over the temperature range 90-350 K. Phase transitions were detected at temperatures T (01) = 266 K (second-order transition) and T (02) = 225 K (first order). It is assumed that the crystal symmetry is changed as follows: Fm3m a dagger" I4/mmm a dagger" I4/m. Anomalies of the spectral parameters are established in the frequency range of internal vibrations of ammonium ions and Ti(O-2)F-5 complexes. An analysis of the results shows that the transition at T (01) is likely due to small shifts of the tetrahedral groups from their position on the triad axis and that the transition at T (02) is due to fluorine-oxygen ordering of Ti(O-2)F-5 complexes.

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Держатели документа:
[Mel'nikova, S. V.
Krylov, A. S.
Zhogal', A. L.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Laptash, N. M.] Russian Acad Sci, Inst Chem, Far E Div, Vladivostok 690022, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok 690022, Russian Federation

Доп.точки доступа:
Mel'nikova, S. V.; Мельникова, Светлана Владимировна; Krylov, A. S.; Крылов, Александр Сергеевич; Zhogal', A. L.; Laptash, N. M.; Russian Federation [NSh-1011.2008.2]; Russian Foundation for Basic Research [06-02-16102]; RFBR Enisei [07-02-096800]
}
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15.

Mel'nikova, S. V.
Optical studies of the (T-x) phase diagram of oxyfluoride (NH4)2MoO2F4-Rb2MoO2F4 solid solutions / S. V. Mel'nikova, N. M. Laptash // Phys. Solid State. - 2015. - Vol. 57, Is. 6. - P. 1201-1205, DOI 10.1134/S1063783415060256. - Cited References:8. - This study was supported by the Council on Grants from the President of the Russian Federation for Supporting of Leading Scientific Schools of the Russian Federation (grant NSh-924.2014.2). . - ISSN 1063. - ISSN 1090-6460. -

РУБ Physics, Condensed Matter
Рубрики:
TRANSITIONS
   (NH4)2WO2F4
   CRYSTALS
   DISORDER
Аннотация: Single crystals of solid solutions (NH4)2 − x Rb x MoO2F4 (including individual complex Rb2MoO2F4) have been grown and studied using polarization-optical methods. The birefringence Δn(T) has been measured in the temperature range of 100–400 K. The complete (T-x) phase diagram has been constructed.

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Публикация на русском языке Мельникова, Светлана Владимировна. Оптические исследования фазовой (T-x)-диаграммы твердых растворов оксифторидов (NH4)2MoO2F4-Rb2MoO2F4 [Текст] / С. В. Мельникова, Н. М. Лапташ // Физ. тверд. тела : Физико-технический институт им. А. Ф. Иоффе РАН, 2015. - Т. 57 Вып. 6. - С. 1180-1184

Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Far Eastern Branch, Inst Chem, Vladivostok 690022, Russia.

Доп.точки доступа:
Laptash, N. M.; Мельникова, Светлана Владимировна; Russian Federation [NSh-924.2014.2]
}
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16.

Ignatchenko, V. A.
Partial restoration of the wave spectrum of a superlattice due to cross correlations between one- and three-dimensional inhomogeneities / V. A. Ignatchenko, Y. I. Mankov // Phys. Rev. B. - 2007. - Vol. 75, Is. 23. - Ст. 235422, DOI 10.1103/PhysRevB.75.235422. - Cited References: 32 . - ISSN 1098-0121

РУБ Physics, Condensed Matter
Рубрики:
ELASTIC MEDIUM THEORY
   PERIODIC MULTILAYERS
   SPIN-WAVES
   LOCALIZATION
   SYSTEMS
   SUSCEPTIBILITY
   DISORDER
   MEDIA
Аннотация: Effects of cross correlations between one-dimensional (1D) and three-dimensional (3D) random inhomogeneities on the wave spectrum in sinusoidal superlattices are studied theoretically. The situation when the gap in the spectrum (the forbidden zone) at the first Brillouin zone boundary of the superlattice is closed under the action of the 1D inhomogeneities is considered. The phenomenon of the partial opening of this gap is found when the 3D inhomogeneities cross correlated with the 1D inhomogeneities add to the superlattice. The appearance of the logarithmic resonance in the center of the forbidden zone under the action of the cross correlations is shown. The physical nature of the effects in the wave spectrum of the superlattice that are caused by the cross correlations and the relation of these effects with the asymptotic properties of the correlation function of inhomogeneities are discussed.

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Держатели документа:
SB RAS, LV Kirensky Inst Phys, Krasnoyarsk 660036, Russia
ИФ СО РАН
L. V. Kirensky Institute of Physics, SB RAS, 660036 Krasnoyarsk, Russian Federation

Доп.точки доступа:
Mankov, Y. I.; Игнатченко, Вальтер Алексеевич
}
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17.

18.

    Phase transitions in (NH4)2MoO2F4 crystal / A. Krylov [et al.] // J. Mol. Struct. - 2016. - Vol. 1124, Special Issue : Novel developments and applications of two-dimensional correlation spectroscopy — A festschrift in honor of professor Isao Noda. - P. 125-130, DOI 10.1016/j.molstruc.2016.03.009. - Cited References:17 . - ISSN 0022-2860. - ISSN 1872-8014
   Перевод заглавия: Фазовые переходы в кристалле (NH4)2MoO2F4

РУБ Chemistry, Physical
Рубрики:
OXYFLUORIDE
   (NH4)2WO2F4
   DISORDER
   DIAGRAMS
Кл.слова (ненормированные):
Phase transitions -- Raman high-pressure -- Two-dimensional correlations -- Oxyfluorides
Аннотация: The mechanisms of temperature and high pressure phase transitions have been studied by Raman spectroscopy. Room temperature (295 K) experiments under high hydrostatic pressure up to 3.6 GPa for (NH4)(2) MoO2 F-4 have been carried out. Experimental data indicates a phase transition into a new high-pressure phase for (NH4)(2) MoO2 F-4 at 1.2 GPa. This phase transition is related to the ordering anion octahedron groups [MoO2 F-4](2) and is not associated with ammonium group. Raman spectra of small non-oriented crystals ranging from 10 to 350 K have been observed. The experiment shows anion groups [MoO2 F-4](2-) and ammonium in high temperature phase are disordered. The phase transition at T-1 = 269.8 K is of the first-order, close to the tricritical point. The first temperature phase transition is related to the ordering anion octahedron groups [MoO2 F-4](2-). Second phase transitions T-2 = 180 K are associated with the ordering of ammonium. The data presented within this study demonstrate that 2D correlation analysis combined with traditional Raman spectroscopy are powerful tool to study phase transitions in the crystals. (C) 2016 Elsevier B.V. All rights reserved.

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Доп.точки доступа:
Krylov, A. S.; Крылов, Александр Сергеевич; Laptash, N. M.; Vtyurin, A. N.; Втюрин, Александр Николаевич; Krylova, S. N.; Крылова, Светлана Николаевна; International Symposium on Two-Dimensional Correlation Spectroscopy(8th ; JUL 08-11, 2015 ; Vienna, Austria)
}
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19.

Phase transitions in the (NH4)(2)NbOF5 oxyfluoride / V. D. Fokina [et al.] // Phys. Solid State. - 2010. - Vol. 52, Is. 4. - P. 781-788, DOI 10.1134/S1063783410040189. - Cited References: 13. - We would like to thank A. A. Udovenko (Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, Vladivostok, Russia) for kindly supplied detailed data on the atomic coordinates in the structure of the (NHINF4/INF)INF2/INFNbOFINF5/INF oxyfluoride.This study was supported by the Russian Foundation for Basic Research (project no. 09-02-00062) and the Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools of the Russian Federation (grant no. NSh-1011.2008.2). . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
CRYSTAL-STRUCTURE
   (NH4)(2)WO2F4
   MECHANISM
   DISORDER
Аннотация: The thermal and dielectric properties of the (NH4)(2)NbOF5 oxyfluoride have been investigated. It has been established that the structural phase transitions Cmc2(1) - C2 - Ia observed at the temperatures T (1) = 258.0 K and T (2) = 218.9 K exhibit a nonferroelectric nature. The hydrostatic pressure, which stabilizes the initial phase and destabilizes the low-temperature phase, hardly affects the temperature range of stability of the intermediate phase. The model of sequential ordering of the structural elements due to phase transitions has been analyzed using experimental data on the entropies of the phase transitions.

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Держатели документа:
[Fokina, V. D.
Bogdanov, E. V.
Gorev, M. V.
Molokeev, M. S.
Flerov, I. N.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Fokina, V. D.
Gorev, M. V.
Pogorel'tsev, E. I.
Flerov, I. N.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
[Laptash, N. M.] Russian Acad Sci, Far Eastern Branch, Inst Chem, Vladivostok 690022, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk 660036, Russian Federation
Siberian Federal University, pr. Svobodny 79, Krasnoyarsk 660041, Russian Federation
Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok 690022, Russian Federation

Доп.точки доступа:
Fokina, V. D.; Фокина, Валентина Дмитриевна; Bogdanov, E. V.; Богданов, Евгений Витальевич; Gorev, M. V.; Горев, Михаил Васильевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Pogorel'tsev, E. I.; Flerov, I. N.; Флёров, Игорь Николаевич; Laptash, N. M.
}
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20.

Mel'nikova, S. V.
Phase transitions in the oxyfluoride (NH4)(3)NbOF6 / S. V. Mel'nikova, N. M. Laptash, A. L. Zhogal' // Phys. Solid State. - 2007. - Vol. 49, Is. 5. - P. 958-962, DOI 10.1134/S1063783407050253. - Cited References: 11 . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
RAY-DIFFRACTION INVESTIGATIONS
   DISTORTED PHASES
   SYMMETRY
   DISORDER
   CRYSTAL
Аннотация: (NH4)(3)NbOF6 single crystals were grown, polarization-optical studies were performed, and birefringence was measured over the temperature range 90-500 K. A sequence of first-order structural phase transitions was found at temperatures T (1 down arrow) = 259.7 K and T (2 down arrow) = 257.7 K with temperature hysteresis delta T-1 = 0.9 K and delta T-2 = 1.9 K. The transitions are accompanied by twinning and the following change in the crystal symmetry: cubic paired left right arrows tetragonal paired left right arrows monoclinic. Optical second harmonic generation is found to occur at room temperature, which indicates that the cubic phase is not centrosymmetric. It is assumed that the phase transitions are ferroelastic and ferroelectric in nature.

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
Russian Acad Sci, Inst Chem, Far E Div, Vladivostok 690022, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russian Federation

Доп.точки доступа:
Laptash, N. M.; Zhogal', A. L.; Мельникова, Светлана Владимировна
}
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